File name: Pandora279s1_Sapporo_20260715_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260722T152646.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260715_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260714T215059.1Z 9691.910406 137 1 8.21 2 62.85 85.07 68.75 78.84 0.00 1 0.00 1 0 17 1.110e-02 5.894e-03 3.428e-03 1.704e-03 2.708479e-01 8.627137e-04 3.249776e-03 -6.000000e+00 6.300725e-03 233.08 -2.00 3.56 -2.00 316.24 0.00e+00 1.140481e-04 9.614915e-05 4.192360e-05 -6.000000e+00 2.801907e-04 287.89 -2.00 20.00 -2.00 315.44 0.00e+00 2.179 0.000 302.00 328.00 3 3.2776e+00 2.2657e-03 2.6102e-02 -6.0000e+00 1.5838e-02 2.1360e-02 2.5311e-03 1.4343e-02 -6.0000e+00 1.7158e-02 -5.8316e-03 1.4542e-03 6.8877e-03 -6.0000e+00 1.0202e-02 -1.1811e-03 6.7198e-04 1.8585e-03 -6.0000e+00 4.3055e-03 1.6531e-03 1.3195e-04 4.5865e-05 2.0656e-05 -6.0000e+00 2.8295e-04 -1.3801e-03 0.0000e+00 12 1 1 12 1 1 83.38 29.30 0.35 -0.00138 -0.00039 14 9 1 5 0 546.840 37.00 20.00 29.30 31.06 0.0 989.42 -1092 1770 141 -1037 -5606 -5598 -2501 1366 -165 -3375 -2287 -1905 -151 652 1947 -368 -632 -266 550 1273 1109 898 991 201 546 1846 189 -1137 375 1275 1019 1303 1122 -911 -2230 -1871 -1091 -1769 -149 -278 -612 -863 -632 -251 -280 158 -838 -98 -790 -296 679 427 750 789 1068 1039 782 258 550 434 1128 884 1427 1440 -287 -182 -456 -287 397 469 598 62 221 267 99 -452 -487 -1042 -428 -1208 -609 -1184 -2088 -1532 -1028 -437 3 459 518 569 387 -28 31 -56 -86 105 640 795 190 -262 -316 -401 -789 129 -669 -750 -453 -364 44 329 52 406 149 176 -76 -162 -158 278 65 -31 -122 92 300 304 559 211 554 756 571 258 214 23 -350 268 100 -109 152 111 29 -130 -536 -299 -707 -219 368 30 -199 -1003 -1008 -479 285 -36 -775 -505 -447 -40 183 615 -120 -213 -93 200 476 418 335 387 79 224 775 79 -443 144 494 402 553 522 -403 -969 -828 -509 -928 -89 -181 -406 -595 -447 -177 -197 111 -577 -66 -522 -198 486 313 553 613 847 843 620 203 441 349 902 738 1291 1326 -260 -155 -383 -238 347 450 595 61 216 258 92 -388 -399 -866 -368 -1101 -594 -1236 -2237 -1655 -1158 -523 3 568 638 685 441 -30 32 -57 -92 121 762 1018 248 -339 -393 -472 -920 154 -827 -968 -593 -485 62 465 77 601 211 242 -99 -207 -205 368 91 -44 -177 130 426 411 735 274 702 953 758 356 301 33 -516 400 156 -173 239 180 48 -208 -833 -459 -1071 SS 20260714T215456.6Z 9691.913156 140 1 54.89 2 62.13 85.72 68.08 79.45 0.00 1 0.00 1 0 17 1.142e-02 5.942e-03 1.729e-03 7.780e-04 2.642510e-01 3.930397e-04 3.174297e-03 -6.000000e+00 6.481783e-03 233.08 -2.00 3.56 -2.00 316.48 0.00e+00 3.703766e-04 4.617869e-05 5.544994e-05 -6.000000e+00 2.882613e-04 287.89 -2.00 20.00 -2.00 315.67 0.00e+00 2.128 0.000 302.00 328.00 3 3.6641e+00 1.0350e-03 2.5503e-02 -6.0000e+00 1.6293e-02 2.6014e-02 1.1572e-03 1.4044e-02 -6.0000e+00 1.7651e-02 -4.0400e-03 6.6990e-04 6.7480e-03 -6.0000e+00 1.0495e-02 -3.0699e-03 3.1393e-04 1.8362e-03 -6.0000e+00 4.4290e-03 1.1891e-03 1.6661e-04 2.0985e-05 1.9703e-05 -6.0000e+00 2.9111e-04 -9.2166e-04 0.0000e+00 10 0 0 10 0 0 99.99 29.30 0.28 -0.00092 0.00033 237 22 1 5 0 231.600 36.75 19.99 29.30 31.24 0.0 990.20 -2523 2330 1963 -209 -3985 -5984 -3028 1697 -1200 -838 -4539 -1347 1003 347 2363 18 -456 -608 582 1091 1069 392 1527 452 -150 1860 -489 -775 -823 77 821 241 1243 -1282 -2370 -2112 -1203 -1447 -536 -68 -321 -642 -574 67 -72 -291 -886 116 -687 82 893 493 549 1023 840 810 743 448 277 562 659 819 1589 1592 -2 -270 -694 -762 707 813 475 258 299 456 250 -317 -759 -1141 -819 -896 -744 -1101 -2045 -1524 -878 -190 -137 365 648 457 469 83 -76 180 -135 -15 585 498 157 -210 -413 -819 -698 -165 -716 -680 -704 -430 -20 280 1170 415 121 80 -266 25 -158 239 165 50 -195 156 195 275 578 103 452 843 284 280 135 -19 -274 95 192 -212 187 182 -88 -160 -169 -517 -523 -441 415 351 -34 -603 -928 -499 302 -243 -173 -946 -289 222 89 675 6 -149 -192 189 365 360 131 529 168 -59 739 -195 -285 -283 27 306 98 544 -529 -970 -882 -521 -743 -308 -42 -212 -415 -381 44 -48 -192 -608 77 -451 54 597 353 414 765 644 634 592 353 214 434 532 679 1422 1431 -2 -227 -584 -635 606 756 478 255 291 444 236 -267 -620 -905 -703 -831 -731 -1140 -2147 -1669 -989 -228 -165 448 789 551 541 87 -77 180 -147 -18 718 650 205 -275 -506 -963 -820 -197 -899 -891 -929 -593 -28 400 1740 620 173 109 -347 32 -207 316 227 73 -289 225 274 382 759 136 561 1072 378 396 192 -28 -409 143 297 -344 297 297 -144 -261 -267 -788 -814 SS 20260714T215853.9Z 9691.915902 143 1 3.82 2 61.41 86.37 67.40 80.05 0.00 1 0.00 1 0 17 9.702e-03 6.238e-03 2.583e-03 1.459e-03 2.587239e-01 7.390227e-04 3.112071e-03 -6.000000e+00 5.509336e-03 233.08 -2.00 3.56 -2.00 315.86 0.00e+00 3.502194e-04 7.575643e-05 3.453620e-05 -6.000000e+00 2.449898e-04 287.89 -2.00 20.00 -2.00 315.09 0.00e+00 2.079 0.000 302.00 328.00 3 2.3632e+00 1.9319e-03 2.4908e-02 -6.0000e+00 1.3848e-02 2.0805e-02 2.1552e-03 1.3687e-02 -6.0000e+00 1.5003e-02 -8.1035e-03 1.2306e-03 6.5778e-03 -6.0000e+00 8.9203e-03 3.6252e-05 5.5679e-04 1.7941e-03 -6.0000e+00 3.7648e-03 4.6359e-03 1.7740e-04 3.9034e-05 2.0112e-05 -6.0000e+00 2.4740e-04 -1.6155e-03 0.0000e+00 12 1 1 12 1 1 82.91 29.30 0.40 -0.00162 -0.00028 18 26 1 5 0 200.820 36.75 19.99 29.30 31.40 0.0 990.97 -1013 254 -66 -2784 -4224 -3467 -645 384 186 -1441 -2817 -1627 -306 -201 902 1075 -114 721 867 1502 880 642 1158 1180 59 1000 423 -476 -511 427 1055 817 1649 -1471 -2700 -2265 -1631 -1449 -61 -341 -674 -194 -307 -438 6 -323 -692 -403 -509 92 1019 731 1253 936 981 902 706 112 264 597 964 901 1754 1761 121 -239 -770 -767 81 270 336 269 -72 597 34 -119 -869 -1004 -665 -1231 -988 -1371 -2011 -1392 -1010 -460 -64 414 671 316 380 -26 -210 -116 89 206 533 720 159 -172 -302 -584 -912 85 -521 -562 -628 -397 69 235 737 554 265 187 -339 -44 176 250 -69 47 -255 -76 435 323 644 211 455 821 342 258 159 8 -263 -42 147 -26 175 249 -74 -223 -154 -704 -622 -242 64 -17 -647 -952 -778 -143 95 51 -384 -739 -448 -95 -67 320 410 -45 280 349 623 369 266 499 512 27 470 196 -204 -217 182 458 383 794 -724 -1288 -1100 -842 -802 -37 -228 -465 -138 -225 -321 4 -235 -493 -279 -360 63 747 552 957 756 782 734 586 92 212 479 808 792 1608 1654 111 -213 -649 -640 71 255 332 274 -73 588 31 -106 -736 -823 -569 -1131 -982 -1420 -2144 -1547 -1147 -540 -77 507 816 374 433 -28 -220 -120 97 235 640 909 205 -219 -368 -688 -1059 101 -650 -715 -818 -527 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