File name: Pandora279s1_Sapporo_20260718_L2Fit_fout2c2d20231207p1-8.txt File generation date: 20260718T144939.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v2d20231207.txt Level 1 file used: Pandora279s1_Sapporo_20260718_L1_smca1c2d20231207p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1196 305.2603 305.4009 305.5416 305.6822 305.8229 305.9635 306.1041 306.2447 306.3853 306.5259 306.6665 306.8070 306.9476 307.0881 307.2287 307.3692 307.5097 307.6502 307.7907 307.9311 308.0716 308.2120 308.3525 308.4929 308.6333 308.7737 308.9141 309.0545 309.1949 309.3353 309.4756 309.6160 309.7563 309.8966 310.0369 310.1772 310.3175 310.4578 310.5980 310.7383 310.8785 311.0188 311.1590 311.2992 311.4394 311.5796 311.7198 311.8599 312.0001 312.1402 312.2804 312.4205 312.5606 312.7007 312.8408 312.9809 313.1209 313.2610 313.4010 313.5411 313.6811 313.8211 313.9611 314.1011 314.2410 314.3810 314.5210 314.6609 314.8008 314.9408 315.0807 315.2206 315.3605 315.5003 315.6402 315.7801 315.9199 316.0597 316.1996 316.3394 316.4792 316.6189 316.7587 316.8985 317.0382 317.1780 317.3177 317.4574 317.5971 317.7368 317.8765 318.0162 318.1559 318.2955 318.4352 318.5748 318.7144 318.8540 318.9936 319.1332 319.2728 319.4123 319.5519 319.6914 319.8309 319.9705 320.1100 320.2495 320.3889 320.5284 320.6679 320.8073 320.9468 321.0862 321.2256 321.3650 321.5044 321.6438 321.7832 321.9225 322.0619 322.2012 322.3405 322.4798 322.6191 322.7584 322.8977 323.0370 323.1762 323.3155 323.4547 323.5939 323.7331 323.8723 324.0115 324.1507 324.2899 324.4290 324.5682 324.7073 324.8464 324.9855 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260717T233221.4Z 9694.980804 210 1 1.70 2 44.84 104.05 90.33 83.25 0.00 1 0.00 1 0 17 8.659e-03 6.375e-03 3.955e-03 2.893e-03 1.878297e-01 1.482035e-03 2.255991e-03 -6.000000e+00 4.919420e-03 233.01 -2.00 3.56 -2.00 314.68 0.00e+00 3.639705e-04 1.200943e-04 2.521538e-05 -6.000000e+00 2.187728e-04 288.03 -2.00 20.00 -2.00 314.02 0.00e+00 1.408 0.000 302.00 328.00 3 3.2810e+00 3.8273e-03 1.7244e-02 -6.0000e+00 1.2363e-02 2.1225e-02 4.2434e-03 9.8717e-03 -6.0000e+00 1.3390e-02 -1.6733e-03 2.4247e-03 4.7502e-03 -6.0000e+00 7.9629e-03 -3.6678e-03 1.0527e-03 1.3169e-03 -6.0000e+00 3.3651e-03 4.0236e-03 1.0113e-03 7.6864e-05 1.5799e-05 -6.0000e+00 2.2075e-04 -2.8351e-03 2.0244e-04 12 1 1 12 1 1 -432.57 29.30 0.33 -0.00284 0.00476 3 12 1 5 0 423.150 37.00 20.00 29.30 31.55 0.0 991.38 -48 355 5 -1352 -3622 -2838 -1658 1315 1245 126 -1791 -446 -174 -280 206 733 577 -176 764 1786 176 670 1748 792 266 1199 -123 -951 -1041 1382 1056 1038 1038 -342 -2290 -2491 -580 -1063 -220 -159 -1262 -641 -454 -1075 -377 -38 -305 -341 -800 5 860 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-322 294 356 177 -633 -178 -332 -1097 SS 20260717T233627.6Z 9694.983653 213 1 49.17 2 44.11 104.94 89.62 83.94 0.00 1 0.00 1 0 17 1.641e-02 8.870e-03 2.897e-03 1.765e-03 1.890017e-01 8.959397e-04 2.284336e-03 -6.000000e+00 9.315943e-03 233.01 -2.00 3.56 -2.00 315.46 0.00e+00 4.719815e-04 8.428735e-05 2.423170e-05 -6.000000e+00 4.146910e-04 288.03 -2.00 20.00 -2.00 314.71 0.00e+00 1.391 0.000 302.00 328.00 3 5.6730e+00 2.3350e-03 1.7187e-02 -6.0000e+00 2.3412e-02 4.2841e-02 2.5973e-03 1.0012e-02 -6.0000e+00 2.5365e-02 1.7795e-03 1.4813e-03 4.8202e-03 -6.0000e+00 1.5083e-02 -5.0363e-03 6.6372e-04 1.3422e-03 -6.0000e+00 6.3687e-03 3.6901e-04 8.9948e-05 4.7388e-05 1.5421e-05 -6.0000e+00 4.1859e-04 6.8478e-04 9.7524e-05 12 9 1 12 41 1 100.00 29.27 0.73 0.00068 0.00136 31 3 1 5 0 1536.490 36.75 20.00 29.27 31.69 0.0 992.42 -3062 -290 4923 4130 -5168 -4891 -2033 6944 352 93 -6755 -1683 2452 2273 5201 37 709 -2373 -175 580 242 -1326 1899 608 -1376 3799 -1393 -1344 -384 1439 660 -708 820 -2043 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-899 -1640 -282 -105 753 1905 856 115 3 -670 26 -1021 252 80 145 -99 510 -228 344 448 329 1241 386 -170 437 853 -731 -771 573 -234 -188 1181 566 -420 200 142 -704 -1515 SS 20260718T044320.5Z 9695.196765 421 1 47.61 2 33.72 238.91 43.17 151.56 0.00 1 0.00 1 0 17 2.224e-02 3.080e-02 1.773e-03 1.280e-03 1.659590e-01 6.560434e-04 1.970191e-03 -6.000000e+00 1.262673e-02 233.00 -2.00 3.56 -2.00 314.70 0.00e+00 1.444126e-04 5.345699e-05 2.578358e-04 -6.000000e+00 5.619564e-04 288.03 -2.00 20.00 -2.00 314.05 0.00e+00 1.201 0.000 302.00 328.00 3 5.3399e+00 1.6970e-03 1.4652e-02 -6.0000e+00 3.1731e-02 2.6756e-02 1.8791e-03 8.2584e-03 -6.0000e+00 3.4376e-02 -1.0986e-02 1.0727e-03 3.9929e-03 -6.0000e+00 2.0442e-02 1.2379e-02 4.6726e-04 1.2658e-03 -6.0000e+00 8.6333e-03 6.5478e-04 4.1507e-04 3.4243e-05 1.7744e-05 -6.0000e+00 5.6714e-04 2.8453e-04 1.5139e-04 12 9 9 12 9 1 99.99 29.27 0.25 0.00028 0.00340 23 3 1 5 0 1983.490 36.75 20.00 29.27 32.14 0.0 995.33 105 4250 2781 256 -3910 -3324 -787 4178 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