File name: Pandora77s1_Singapore-NUS_20230621_L2Fit_fout2c3d20230113p1-8.txt File generation date: 20251122T210022.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora77_OF_v1d20220405.txt Instrument calibration file used: Pandora77s1_CF_v3d20230113.txt Level 1 file used: Pandora77s1_Singapore-NUS_20230621_L1_smca1c3d20230113p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20230621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0008 305.1420 305.2832 305.4244 305.5656 305.7068 305.8480 305.9891 306.1303 306.2714 306.4126 306.5537 306.6948 306.8359 306.9770 307.1181 307.2591 307.4002 307.5412 307.6822 307.8233 307.9643 308.1053 308.2463 308.3872 308.5282 308.6691 308.8101 308.9510 309.0919 309.2328 309.3737 309.5146 309.6555 309.7964 309.9372 310.0780 310.2189 310.3597 310.5005 310.6413 310.7821 310.9228 311.0636 311.2043 311.3451 311.4858 311.6265 311.7672 311.9079 312.0486 312.1893 312.3299 312.4706 312.6112 312.7518 312.8924 313.0331 313.1736 313.3142 313.4548 313.5953 313.7359 313.8764 314.0169 314.1574 314.2979 314.4384 314.5789 314.7194 314.8598 315.0003 315.1407 315.2811 315.4215 315.5619 315.7023 315.8427 315.9830 316.1234 316.2637 316.4040 316.5444 316.6847 316.8250 316.9652 317.1055 317.2458 317.3860 317.5262 317.6665 317.8067 317.9469 318.0871 318.2272 318.3674 318.5076 318.6477 318.7878 318.9279 319.0680 319.2081 319.3482 319.4883 319.6284 319.7684 319.9084 320.0485 320.1885 320.3285 320.4685 320.6085 320.7484 320.8884 321.0283 321.1683 321.3082 321.4481 321.5880 321.7279 321.8678 322.0076 322.1475 322.2873 322.4271 322.5670 322.7068 322.8466 322.9863 323.1261 323.2659 323.4056 323.5454 323.6851 323.8248 323.9645 324.1042 324.2439 324.3835 324.5232 324.6628 324.8025 324.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230620T234129.6Z 8571.987148 49 1 49.93 2 81.48 66.49 113.82 62.15 0.00 1 0.00 1 0 17 4.851e-01 1.434e-02 3.113e-01 9.455e-03 6.268847e-01 5.192541e-03 6.674360e-03 -6.000000e+00 2.794918e-01 227.41 -2.00 3.05 -2.00 321.64 0.00e+00 9.285904e-04 2.924276e-03 6.574043e-03 -6.000000e+00 1.307866e-02 293.85 -2.00 20.00 -2.00 320.98 0.00e+00 6.351 0.000 302.00 328.00 3 2.0724e+00 2.0541e-02 7.7887e-02 -6.0000e+00 6.9096e-01 2.5454e-01 2.8034e-02 5.7622e-02 -6.0000e+00 7.4849e-01 -3.6878e-01 2.4534e-02 1.9639e-02 -6.0000e+00 4.4964e-01 1.3817e-01 1.1468e-02 5.6949e-03 -6.0000e+00 1.9297e-01 7.3955e-05 -2.8616e-04 2.9038e-04 7.6936e-05 -6.0000e+00 1.3404e-02 1.8717e-03 1.0036e-06 12 9 8 11 16 0 98.69 24.41 0.59 0.00187 -0.00028 42 8 1 5 0 1188.680 26.83 20.00 24.41 33.57 5.7 1035.95 -198294 -177118 900000 -165385 -130263 -169170 -86905 -109661 -133043 -113583 -50565 -127307 -105244 -68057 -95426 156238 83878 23445 -9563 -40414 -53141 -15987 -62790 -14787 -27361 41705 56610 -25170 6363 -66961 -43296 -14343 -16311 58011 103232 81151 -18981 27348 -5053 12341 -8914 20720 21607 14261 26001 2743 13869 13656 6596 -8682 9916 9236 3935 8939 6054 10446 9649 19799 4613 955 740 15231 9603 6027 7336 2996 6876 843 5962 1841 14835 2106 2542 789 -1878 3884 -5370 -5077 -6043 -4588 586 114 -3763 -2210 375 -1719 1279 915 1601 -170 -169 -4257 156 -4349 -2285 -870 -608 -499 -807 -963 -996 686 -2081 -2443 -1886 -1503 -1031 -1339 1274 193 2015 511 193 -1114 -409 527 -139 103 219 1592 1380 -281 75 1380 392 784 343 235 544 -292 340 -1176 -22 -483 -28 162 306 671 -276 90 -496 163 -785 -4113 -3538 900000 -3176 -1601 -2859 -801 -1179 -2044 -1571 -466 -2250 -1779 -993 -2273 1440 773 252 -168 -1016 -1559 -322 -2052 -322 -734 594 712 -696 123 -2750 -1597 -469 -629 1167 1298 1224 -827 871 -271 672 -687 1285 1394 1016 1656 223 1023 1030 553 -895 931 975 482 1244 926 1599 1539 2866 757 158 125 2401 1806 1322 1698 715 1540 204 1489 550 4349 742 893 269 -606 1064 -1485 -1390 -1827 -1607 229 51 -1953 -1206 214 -1070 816 607 1060 -111 -104 -2543 86 -2530 -1438 -623 -503 -474 -843 -1023 -1004 618 -1769 -2077 -1709 -1446 -1045 -1459 1479 253 2879 789 301 -1713 -592 725 -193 150 336 2532 2203 -443 113 2005 553 1065 454 323 834 -509 648 -2431 -48 -1109 -69 418 811 1806 -750 236 -1236 381 -1802 SS 20230620T235400.3Z 8571.995837 54 1 50.42 2 78.62 66.34 111.16 62.80 0.00 1 0.00 1 0 17 1.859e-01 7.436e-03 3.927e-02 1.508e-03 5.171943e-01 7.835714e-04 5.399400e-03 -6.000000e+00 1.071080e-01 227.41 -2.00 3.05 -2.00 320.18 0.00e+00 1.708525e-03 2.864774e-04 1.906403e-03 -6.000000e+00 4.955035e-03 293.85 -2.00 20.00 -2.00 319.35 0.00e+00 4.892 0.000 302.00 328.00 3 1.5479e+00 2.4007e-03 5.3832e-02 -6.0000e+00 2.6479e-01 3.4772e-03 2.9922e-03 2.5899e-02 -6.0000e+00 2.8684e-01 -4.0983e-02 2.5327e-03 1.2249e-02 -6.0000e+00 1.7221e-01 6.3259e-03 1.2980e-03 3.2089e-03 -6.0000e+00 7.3663e-02 5.5761e-04 -3.9095e-04 4.3620e-05 4.6636e-05 -6.0000e+00 5.1362e-03 1.4776e-03 -1.2971e-05 11 8 0 10 0 0 60.28 24.42 0.45 0.00148 -0.00146 158 30 1 5 0 319.090 26.73 20.00 24.42 34.48 5.8 1042.10 -63873 -66052 -58411 -66369 -36380 -83442 -77942 -22392 -64663 -66371 -38929 -51269 -27084 -30571 -8490 -12384 -3459 -21038 1276 -4299 5 -582 -5788 -6713 -9136 -3764 -7081 -6403 -4507 -9693 -4586 -6020 -791 -5505 -4789 -7241 -6811 -5711 -1393 -2367 3984 840 1566 1361 -218 1476 2482 -71 -1697 -932 692 -845 421 1714 1119 1762 655 -381 1124 -1633 1418 2242 2699 2933 2814 1219 -735 -147 1227 1259 1705 1758 1053 1037 -695 -959 -1889 -3962 -2047 -2481 -1436 -1624 -1604 -1411 -651 67 651 1215 1087 1348 1103 132 -729 -654 -858 -298 773 630 546 -558 -721 -1495 -1138 -1198 -1261 -973 -794 -424 5 1022 673 650 359 273 -395 -147 -311 272 202 168 471 468 545 374 394 -99 -136 356 -12 -293 -380 -215 -313 -217 -177 198 370 472 390 -258 -139 -327 -416 -632 -803 -726 -905 -340 -1182 -1094 -204 -1028 -1189 -557 -884 -434 -697 -192 -350 -101 -804 42 -161 0 -22 -237 -300 -455 -190 -382 -337 -224 -517 -261 -406 -58 -467 -399 -598 -599 -579 -165 -344 622 147 287 258 -43 289 488 -15 -363 -207 164 -226 122 531 337 551 214 -127 363 -533 505 779 1047 1266 1287 554 -328 -66 579 679 1024 1119 680 644 -408 -510 -928 -1945 -1059 -1495 -913 -1178 -1280 -1196 -586 59 607 1167 1054 1268 1055 118 -622 -557 -795 -288 848 731 691 -721 -885 -1819 -1275 -1345 -1522 -1159 -995 -563 7 1487 1075 1023 565 441 -602 -213 -450 409 323 283 800 777 875 582 587 -143 -203 505 -19 -479 -676 -405 -578 -422 -368 410 786 1022 847 -547 -298 -668 -828 SS 20230620T235957.0Z 8571.999965 57 1 50.54 2 77.25 66.25 109.89 63.07 0.00 1 0.00 1 0 17 1.185e-01 7.226e-03 1.834e-02 1.033e-03 4.717176e-01 5.293001e-04 4.876317e-03 -6.000000e+00 6.826590e-02 227.41 -2.00 3.05 -2.00 319.66 0.00e+00 1.582453e-03 1.626769e-04 1.317342e-03 -6.000000e+00 3.157925e-03 293.85 -2.00 20.00 -2.00 318.80 0.00e+00 4.408 0.000 302.00 328.00 3 1.3832e+00 1.5444e-03 4.8328e-02 -6.0000e+00 1.6876e-01 -2.9050e-03 1.8667e-03 2.2459e-02 -6.0000e+00 1.8282e-01 -3.1596e-02 1.4713e-03 1.0925e-02 -6.0000e+00 1.0976e-01 3.7852e-03 7.6928e-04 2.9930e-03 -6.0000e+00 4.6951e-02 1.0833e-03 -3.0850e-04 2.9958e-05 3.7246e-05 -6.0000e+00 3.2734e-03 1.3650e-03 4.5899e-08 11 8 0 10 0 0 92.73 24.42 0.38 0.00137 -0.00095 230 43 1 5 0 219.700 26.83 19.99 24.42 34.95 5.7 1046.06 -33129 -47157 -17814 -53418 -20806 -52666 -42377 -28510 -32755 -44888 -32148 -30496 -26401 -18421 -8700 -7193 -6225 -9219 -1969 -3556 -1730 1671 282 -5220 1415 -3066 -1522 -6659 -2748 -8745 -4642 -1467 -231 -1906 -4489 -5952 -7341 -3389 -731 -668 2009 694 1552 137 819 376 998 -643 -709 -432 464 913 1102 2279 1603 1743 751 689 262 -487 438 1488 2432 2614 2136 611 -203 -697 712 766 1503 1241 808 817 -364 -847 -2219 -2845 -2379 -1822 -1573 -1771 -1650 -1630 -566 -78 620 1044 1312 1209 663 -8 -619 -545 -802 -274 466 672 526 -395 -713 -1245 -1024 -1023 -1229 -1113 -630 -581 156 980 817 674 309 39 -361 60 -259 263 206 166 358 483 638 424 265 -32 -17 222 36 -128 -330 -284 -360 -137 -112 132 390 426 186 -44 -204 -334 -488 -434 -846 -261 -1125 -292 -955 -722 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