File name: Pandora77s1_Singapore-NUS_20260125_L2Fit_fout2c4d20240329p1-8.txt File generation date: 20260128T105741.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v4d20240329.txt Level 1 file used: Pandora77s1_Singapore-NUS_20260125_L1_smca1c4d20240329p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20260125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 for fieldcal from 202403 First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1364 305.2776 305.4188 305.5600 305.7012 305.8423 305.9835 306.1246 306.2657 306.4068 306.5479 306.6890 306.8301 306.9712 307.1123 307.2533 307.3943 307.5354 307.6764 307.8174 307.9584 308.0994 308.2403 308.3813 308.5222 308.6632 308.8041 308.9450 309.0859 309.2268 309.3677 309.5086 309.6494 309.7903 309.9311 310.0719 310.2128 310.3536 310.4944 310.6351 310.7759 310.9167 311.0574 311.1981 311.3389 311.4796 311.6203 311.7610 311.9017 312.0423 312.1830 312.3236 312.4643 312.6049 312.7455 312.8861 313.0267 313.1673 313.3078 313.4484 313.5889 313.7295 313.8700 314.0105 314.1510 314.2915 314.4320 314.5724 314.7129 314.8533 314.9937 315.1342 315.2746 315.4150 315.5554 315.6957 315.8361 315.9764 316.1168 316.2571 316.3974 316.5377 316.6780 316.8183 316.9586 317.0988 317.2391 317.3793 317.5195 317.6598 317.8000 317.9401 318.0803 318.2205 318.3607 318.5008 318.6409 318.7811 318.9212 319.0613 319.2014 319.3414 319.4815 319.6215 319.7616 319.9016 320.0416 320.1816 320.3216 320.4616 320.6016 320.7416 320.8815 321.0215 321.1614 321.3013 321.4412 321.5811 321.7210 321.8608 322.0007 322.1405 322.2804 322.4202 322.5600 322.6998 322.8396 322.9794 323.1192 323.2589 323.3986 323.5384 323.6781 323.8178 323.9575 324.0972 324.2369 324.3765 324.5162 324.6558 324.7954 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260125T000741.0Z 9521.005335 52 1 49.56 2 78.50 109.70 145.41 69.02 0.00 1 0.00 1 0 17 4.423e-01 1.157e-02 2.401e-01 8.366e-03 4.763498e-01 4.466088e-03 4.907430e-03 -6.000000e+00 2.545710e-01 225.23 -2.00 3.05 -2.00 320.78 0.00e+00 2.093588e-03 1.909772e-03 1.408864e-03 -6.000000e+00 1.224112e-02 293.93 -2.00 20.00 -2.00 320.00 0.00e+00 4.847 0.000 302.00 328.00 3 3.9093e+00 1.4829e-02 5.2193e-02 -6.0000e+00 6.2762e-01 5.0000e-02 1.9113e-02 2.2922e-02 -6.0000e+00 6.8156e-01 -6.4171e-02 1.6545e-02 1.1740e-02 -6.0000e+00 4.0810e-01 1.9271e-02 8.2356e-03 3.5572e-03 -6.0000e+00 1.7774e-01 5.6984e-05 -5.3139e-04 2.6320e-04 5.0159e-05 -6.0000e+00 1.2516e-02 -3.0244e-03 0.0000e+00 12 9 8 11 16 0 80.77 25.77 0.54 -0.00302 -0.00702 18 3 1 5 0 2752.970 27.99 20.00 25.77 30.00 16.2 972.04 4068 900000 900000 -77885 -127098 222207 -96640 900000 76395 -98532 24645 -101482 -68956 -5420 43417 -11294 -10857 365640 -15841 3950 26314 51730 -16730 33355 -4773 -17930 14193 -25706 34034 -11241 -19126 19571 -16888 -3589 -20891 11431 6138 10856 2905 6756 10212 2853 12522 -4279 8820 -5580 -2802 7647 5276 1501 -153 3434 841 6209 1469 5246 -1734 2594 -3962 566 3263 3878 6342 1094 -3310 -274 167 -5001 -986 -2281 1877 2506 4770 433 304 -2236 -1478 -4351 -1038 -1960 -1754 -3200 -2071 1884 -632 -529 1887 639 1369 -1018 -603 1001 -1687 -213 -616 3452 -463 407 195 -504 -549 117 -461 -2097 -1139 -1788 610 -827 904 -494 716 972 14 -1218 -621 -354 325 874 300 166 337 393 643 652 -227 770 -998 -292 109 105 215 -439 452 -148 -114 769 -319 -55 -1005 362 -262 372 33 900000 900000 -1111 -2763 1812 -1773 900000 623 -2410 201 -3385 -2044 -104 611 -310 -322 2981 -564 120 644 997 -682 890 -198 -877 494 -1276 933 -533 -1134 899 -1227 -226 -1502 627 409 837 293 751 1188 376 1550 -698 1280 -946 -466 1166 852 270 -31 731 198 1473 380 1347 -482 679 -1089 151 913 1201 2130 410 -1268 -97 59 -1957 -421 -1106 929 1246 2240 198 126 -866 -548 -1756 -465 -1029 -1044 -2126 -1447 1350 -498 -442 1600 554 1151 -822 -449 688 -1173 -156 -513 3152 -498 475 232 -574 -572 112 -441 -2185 -1255 -2088 739 -1091 1284 -776 1169 1578 22 -1816 -871 -491 465 1324 484 272 543 613 969 941 -317 1023 -1368 -433 179 186 402 -859 921 -324 -264 1814 -777 -134 -2418 820 -569 781 SS 20260125T001356.6Z 9521.009683 55 1 49.82 2 77.03 109.85 144.00 69.75 0.00 1 0.00 1 0 17 4.026e-01 1.083e-02 1.445e-01 3.061e-03 4.390626e-01 1.578874e-03 4.512294e-03 -6.000000e+00 2.322400e-01 225.23 -2.00 3.05 -2.00 319.76 0.00e+00 -2.699068e-04 5.078035e-04 1.024474e-03 -6.000000e+00 1.125028e-02 293.93 -2.00 20.00 -2.00 318.91 0.00e+00 4.336 0.000 302.00 328.00 3 3.8275e+00 4.6536e-03 4.6895e-02 -6.0000e+00 5.7198e-01 -7.4267e-02 5.6937e-03 2.1067e-02 -6.0000e+00 6.2117e-01 7.7121e-02 4.6983e-03 9.8204e-03 -6.0000e+00 3.7144e-01 -3.8376e-02 2.4516e-03 2.8848e-03 -6.0000e+00 1.6067e-01 1.0701e-04 -2.4307e-04 9.1101e-05 3.0347e-05 -6.0000e+00 1.1414e-02 -2.5034e-03 0.0000e+00 12 9 8 11 32 0 90.46 25.77 0.62 -0.00250 -0.00433 26 5 1 5 0 1915.980 27.99 20.00 25.77 30.12 16.1 972.83 353916 168985 -88033 32147 -16694 -89743 900000 18382 -65468 22961 900000 6109 -69357 150414 38181 46061 8549 21034 15858 44778 50109 3335 -8988 4506 649 -4581 6952 43375 5498 4103 8975 7122 4537 1094 15277 -3334 4420 -4350 -7139 13214 -2433 3855 547 -7243 2406 2389 -5997 -1484 -5424 -1384 -4756 -471 1623 3023 2278 -1663 -1606 2696 -7025 2415 1358 4758 1359 6019 -1343 -675 82 2763 471 1212 1279 2082 -1078 2059 733 -638 -4153 -1230 105 -817 -3234 -1867 -3595 -617 34 -121 772 876 897 703 -46 299 17 869 256 616 315 376 71 -302 -929 -436 -1113 -847 -1027 -1058 188 351 1355 67 436 934 130 -462 196 -707 359 71 153 242 -17 620 131 512 -1192 69 -203 -67 -373 -301 -157 -340 -302 196 159 495 465 -213 -142 -80 -290 173 1056 504 -2221 227 -181 -2118 900000 194 -1793 274 900000 104 -3066 987 911 1141 334 784 662 1470 1585 173 -571 274 44 -342 454 1876 346 285 680 625 448 111 1299 -363 518 -680 -1395 2425 -567 889 135 -1949 596 597 -1639 -393 -1542 -406 -1592 -150 546 1068 846 -666 -651 1032 -2921 931 568 2136 698 3110 -727 -345 41 1432 284 814 838 1371 -710 1342 439 -352 -2284 -690 67 -552 -2537 -1586 -3302 -588 32 -120 794 909 909 669 -44 267 15 809 249 677 392 473 90 -368 -1126 -487 -1250 -1020 -1323 -1331 247 494 2056 105 706 1495 200 -717 285 -1028 538 106 241 389 -26 948 209 776 -1765 96 -288 -104 -593 -515 -283 -595 -555 381 327 985 947 -439 -285 -164 -568 328 SS 20260125T002448.0Z 9521.017222 61 1 51.36 2 74.48 110.14 141.55 70.88 0.00 1 0.00 1 0 17 2.269e-01 2.037e-02 2.257e-01 1.632e-02 3.742313e-01 8.484629e-03 3.916755e-03 -6.000000e+00 1.310699e-01 225.23 -2.00 3.05 -2.00 319.77 0.00e+00 -2.204595e-03 2.595831e-03 1.059572e-03 -6.000000e+00 6.472019e-03 293.93 -2.00 20.00 -2.00 318.89 0.00e+00 3.667 0.000 302.00 328.00 3 5.7063e+00 2.4869e-02 4.0073e-02 -6.0000e+00 3.2331e-01 9.2167e-02 3.0082e-02 1.9755e-02 -6.0000e+00 3.5143e-01 -5.4118e-02 2.2141e-02 8.3067e-03 -6.0000e+00 2.0930e-01 2.1988e-02 1.1469e-02 3.9589e-03 -6.0000e+00 9.0413e-02 3.1337e-05 -6.1279e-04 5.0898e-04 3.2901e-05 -6.0000e+00 6.4130e-03 -4.8046e-04 0.0000e+00 12 9 8 11 16 0 99.99 25.76 0.69 -0.00048 -0.00509 23 4 1 5 0 2232.640 27.99 20.00 25.76 30.46 16.1 975.03 27407 -6558 48373 -81654 900000 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