File name: Pandora77s1_Singapore-NUS_20260211_L2Fit_fout2c4d20240329p1-8.txt File generation date: 20260211T173231.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Santo V. Salinas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 77 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora77_OF_v2d20220405.txt Instrument calibration file used: Pandora77s1_CF_v4d20240329.txt Level 1 file used: Pandora77s1_Singapore-NUS_20260211_L1_smca1c4d20240329p1-8.txt Full location name: Centre for Remote Imaging Sensing and Processing (CRISP), National University of Short location name: Singapore-NUS Country of location: Singapore Location latitude [deg]: 1.2990 Location longitude [deg]: 103.7710 Location altitude [m]: 77 Local noon date: 20260211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 for fieldcal from 202403 First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1364 305.2776 305.4188 305.5600 305.7012 305.8423 305.9835 306.1246 306.2657 306.4068 306.5479 306.6890 306.8301 306.9712 307.1123 307.2533 307.3943 307.5354 307.6764 307.8174 307.9584 308.0994 308.2403 308.3813 308.5222 308.6632 308.8041 308.9450 309.0859 309.2268 309.3677 309.5086 309.6494 309.7903 309.9311 310.0719 310.2128 310.3536 310.4944 310.6351 310.7759 310.9167 311.0574 311.1981 311.3389 311.4796 311.6203 311.7610 311.9017 312.0423 312.1830 312.3236 312.4643 312.6049 312.7455 312.8861 313.0267 313.1673 313.3078 313.4484 313.5889 313.7295 313.8700 314.0105 314.1510 314.2915 314.4320 314.5724 314.7129 314.8533 314.9937 315.1342 315.2746 315.4150 315.5554 315.6957 315.8361 315.9764 316.1168 316.2571 316.3974 316.5377 316.6780 316.8183 316.9586 317.0988 317.2391 317.3793 317.5195 317.6598 317.8000 317.9401 318.0803 318.2205 318.3607 318.5008 318.6409 318.7811 318.9212 319.0613 319.2014 319.3414 319.4815 319.6215 319.7616 319.9016 320.0416 320.1816 320.3216 320.4616 320.6016 320.7416 320.8815 321.0215 321.1614 321.3013 321.4412 321.5811 321.7210 321.8608 322.0007 322.1405 322.2804 322.4202 322.5600 322.6998 322.8396 322.9794 323.1192 323.2589 323.3986 323.5384 323.6781 323.8178 323.9575 324.0972 324.2369 324.3765 324.5162 324.6558 324.7954 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260210T234459.2Z 9537.989574 211 1 50.34 2 84.05 104.31 28.87 171.86 0.00 1 0.00 1 0 17 7.693e-01 2.515e-02 3.228e-01 6.921e-03 7.474159e-01 4.243794e-03 7.757516e-03 -6.000000e+00 4.652017e-01 225.62 -2.00 3.05 -2.00 322.01 0.00e+00 3.035604e-03 2.868428e-03 7.253793e-03 -6.000000e+00 2.810307e-02 294.02 -2.00 20.00 -2.00 321.46 0.00e+00 8.583 0.001 302.00 328.00 3 7.2633e-01 1.9247e-02 9.8471e-02 -6.0000e+00 1.1622e+00 4.2721e-01 2.8755e-02 6.1576e-02 -6.0000e+00 1.2823e+00 -6.4053e-01 2.6953e-02 2.5251e-02 -6.0000e+00 7.5480e-01 2.6232e-01 1.1847e-02 5.6678e-03 -6.0000e+00 3.2206e-01 3.2586e-05 -2.1119e-04 2.1868e-04 1.3978e-04 -6.0000e+00 2.4162e-02 4.1245e-04 0.0000e+00 12 8 8 10 0 0 59.55 25.42 0.77 0.00041 -0.00117 52 10 1 5 0 968.000 27.67 19.99 25.42 30.18 16.3 973.59 900000 900000 -262051 900000 -30507 -248850 900000 900000 -227790 70461 900000 900000 -236723 900000 900000 900000 -48996 900000 900000 900000 900000 900000 140582 900000 900000 36944 900000 900000 900000 29257 118328 900000 900000 156926 900000 30022 256221 900000 40492 900000 121863 292868 295694 25597 196689 105464 24601 15396 36627 21381 20157 26360 81578 74010 45204 16895 11647 86402 18497 30968 20934 36324 8897 63099 14427 20449 8520 23769 12617 15323 18528 18959 3003 10642 2457 8530 -31640 11995 -4776 -2339 -2578 1140 -2894 826 -1737 -819 171 -2638 3749 -294 4605 -2765 -597 -2134 -3262 1404 -3915 -247 -2010 36 -1979 -1692 -4500 -2463 -907 -3109 785 -2805 2879 -15 600 -1054 195 -2108 210 -1509 -186 -1133 -39 2376 1144 3067 1195 1195 2955 812 -528 -339 251 -251 -109 -352 340 344 955 697 561 627 -1042 -886 -1736 -387 900000 900000 -7181 900000 -205 -5010 900000 900000 -4841 473 900000 900000 -10542 900000 900000 900000 -658 900000 900000 900000 900000 900000 943 900000 900000 293 900000 900000 900000 286 794 900000 900000 1053 900000 458 1719 900000 939 900000 1717 1965 1984 1031 1452 1982 1073 775 1598 1205 1299 1769 3449 3626 3094 1587 1157 3943 1614 2411 1953 3315 1224 5505 2062 2731 1327 3477 2379 3157 3917 3995 705 2121 477 1443 -8068 2206 -1244 -709 -912 435 -1237 364 -842 -415 89 -1423 1849 -142 1996 -1252 -274 -1120 -2034 983 -3059 -207 -1762 29 -1503 -1280 -3446 -1974 -765 -2589 680 -2795 3084 -19 807 -1479 267 -2828 266 -1957 -249 -1631 -58 3439 1617 4103 1583 1532 3616 992 -684 -499 421 -434 -203 -702 721 785 2293 1727 1415 1583 -2576 -2056 -3815 -810 SS 20260210T235720.2Z 9537.998150 214 1 50.52 2 81.06 104.48 28.61 177.45 0.00 1 0.00 1 0 17 4.090e-01 8.725e-03 7.950e-02 2.443e-03 5.896804e-01 1.303580e-03 6.032180e-03 -6.000000e+00 2.344332e-01 225.62 -2.00 3.05 -2.00 321.31 0.00e+00 8.831669e-04 6.837951e-04 3.294155e-03 -6.000000e+00 1.093791e-02 294.02 -2.00 20.00 -2.00 320.62 0.00e+00 6.089 0.000 302.00 328.00 3 5.1395e-01 4.8244e-03 6.7215e-02 -6.0000e+00 5.7712e-01 1.0079e-01 6.6319e-03 3.5521e-02 -6.0000e+00 6.2601e-01 -1.6207e-01 6.0544e-03 1.5359e-02 -6.0000e+00 3.7615e-01 5.9163e-02 2.8738e-03 4.1127e-03 -6.0000e+00 1.6272e-01 4.8386e-04 -3.4497e-04 7.2770e-05 5.7231e-05 -6.0000e+00 1.1381e-02 -4.3170e-04 0.0000e+00 11 9 0 11 16 0 17.36 25.42 0.34 -0.00043 -0.00302 259 49 1 5 0 195.030 27.67 20.00 25.42 30.93 16.3 978.95 -151356 -120164 -156995 -119709 -155174 -119347 -145492 -104463 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653 1172 1074 1103 572 242 237 559 691 844 1059 667 85 444 -387 -1101 -1238 -1300 -641 -875 -700 -1034 -1005 -419 -95 576 673 1082 691 524 -74 -622 -1048 -975 -636 -180 669 406 -337 -1052 -1607 -1476 -1247 -1761 -1261 -607 -888 511 1034 1046 1057 1339 -18 -769 -441 -695 207 -68 719 121 1285 1088 1101 175 -113 268 408 198 -608 -291 -189 -322 -406 -279 -56 861 987 536 94 -282 -801 -1404 SS 20260211T000754.8Z 9538.005496 219 1 50.43 2 78.51 104.66 28.61 182.28 0.00 1 0.00 1 0 25 1.563e-01 7.302e-03 1.178e-02 6.878e-04 4.888430e-01 3.535764e-04 5.044516e-03 -6.000000e+00 8.962582e-02 225.62 -2.00 3.05 -2.00 319.79 0.00e+00 1.145660e-03 1.133848e-04 1.266966e-03 -6.000000e+00 4.181486e-03 294.02 -2.00 20.00 -2.00 318.92 0.00e+00 4.849 0.000 302.00 328.00 3 4.5679e-01 1.0422e-03 5.2366e-02 -6.0000e+00 2.2064e-01 1.1226e-02 1.2691e-03 2.3179e-02 -6.0000e+00 2.3933e-01 -3.5605e-02 1.0155e-03 1.1175e-02 -6.0000e+00 1.4380e-01 8.1774e-03 5.2871e-04 3.0389e-03 -6.0000e+00 6.2210e-02 1.8008e-03 -2.5082e-04 1.9936e-05 3.8641e-05 -6.0000e+00 4.3507e-03 -6.6838e-04 0.0000e+00 11 8 0 10 0 0 6.10 25.42 0.34 -0.00067 -0.00255 523 99 1 5 0 96.420 27.67 20.00 25.42 31.81 16.3 984.37 -61224 -47308 -57113 -43708 -63296 -60496 -42501 -45602 -50530 -46803 -39845 -35073 -35103 -16695 -13256 -8675 -13903 -6423 -5193 -6744 -7490 -6815 -8120 -5480 -5257 -5153 -4734 -6133 -6421 -5076 -3855 -2359 -2369 -6488 -5580 -5368 -4882 -1870 -461 1459 948 2273 2442 987 2006 1380 751 -137 181 699 1831 1788 2369 1919 1682 1229 831 559 61 624 1559 2606 2777 2367 785 -31 -512 482 1079 955 1336 1081 533 -231 -1015 -1970 -3000 -2304 -2051 -1622 -1652 -1765 -1704 -896 -222 332 645 1073 1020 502 150 -607 -526 -602 -359 259 648 430 -364 -630 -1151 -863 -903 -1237 -1104 -746 -313 177 855 735 694 485 302 -319 -23 -354 271 86 142 114 438 607 522 277 -126 178 371 134 -45 -191 -120 -273 -52 -111 61 258 333 185 -87 -296 -376 -414 -1060 -784 -1059 -656 -1084 -1047 -692 -879 -1247 -1168 -978 -957 -1182 -574 -525 -371 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