File name: Pandora109s1_StGeorge_20161206_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T082145.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20161206_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20161206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161206T124308.0Z 6184.529954 2 1 32.00 2 89.88 122.18 137.37 47.59 0.00 1 0.00 1 0 15 1.185e-01 1.099e-01 9.745e-02 9.353e-02 1.201532e+04 6.670010e+03 9.441459e+02 -6.000000e+00 6.250379e+03 274.82 -2.00 20.00 -2.00 505.27 0.00e+00 2.696123e-03 2.508967e-03 9.771234e-05 -6.000000e+00 3.223522e-03 274.82 -2.00 20.00 -2.00 499.83 0.00e+00 1.439108e+00 1.917854e+00 6.049572e-02 -6.000000e+00 2.319477e+00 222.31 -2.00 3.57 -2.00 501.54 0.00e+00 20.521 0.168 489.00 513.00 1 9.5869e+00 1.4695e-01 3.7596e-02 -6.0000e+00 1.7716e-01 1.3688e-01 3.7618e-02 2.6793e-03 -6.0000e+00 4.6431e-02 6.4107e-06 2.5155e-03 8.0809e-03 8.8650e-05 -6.0000e+00 1.1186e-02 -5.6541e-02 5.2742e-04 12 8 8 10 0 0 -606.49 16.70 8.07 -0.05654 -0.03909 8 2 1 4 0 4000.000 21.79 14.99 16.70 -16362 15853 -14855 3761 3156 3785 5882 -1241 16361 -12472 -2627 -3485 -1016 2927 -2267 5121 -1530 12725 -10275 -904 -14882 8742 12561 -5846 12151 -16476 12225 1344 -3161 7961 3099 10898 -5798 1921 5695 5122 -13526 10556 6499 11143 42 7298 2962 -9088 21369 -11016 -1403 5892 -6667 5512 9998 11631 -16401 29800 -9107 5642 13752 7130 15951 7366 9628 -2254 2747 1188 890 -2732 5984 16168 -17986 -1168 -5598 16050 -14940 13243 -11064 -21465 -3077 1414 28567 -7897 3177 -10799 10791 11588 -1295 11794 914 29133 -6089 1585 -3796 20408 3651 6525 8418 -9582 21161 -5356 24454 -5223 -10715 -2145 -9576 16608 -7184 35224 -19058 9134 -1939 2774 8010 -2582 6526 3250 20408 1036 20980 -6393 4276 -926 -1423 27596 -20087 -13397 -10766 10304 -4490 -5103 6479 1006 14891 -9272 14429 -4296 7173 -5735 6851 -11337 -19118 27385 -3235 9851 -8436 -6772 16406 -1884 -1030 10351 4362 -16242 17304 -19121 13804 -18267 3965 3423 4163 6425 -1460 15996 -16004 -3010 -3966 -1110 3040 -2476 5241 -1707 12635 -13106 -1056 -20006 9281 12856 -7234 12622 -22778 12606 1519 -3622 7905 3195 10488 -6775 2157 6307 5711 -17976 10885 6899 11234 44 7152 3070 -10765 18833 -13437 -1544 5941 -7474 5324 8953 10005 -18501 21430 -9953 5490 12605 7038 14395 7219 9232 -2448 2847 1248 929 -2909 5738 13793 -21304 -1153 -5723 13240 -16959 11485 -12326 -26332 -3081 1326 20141 -7962 2867 -11268 9130 9804 -1260 10145 876 20951 -6182 1487 -3774 16115 3449 5981 7419 -9796 15367 -4909 16207 -4566 -9821 -1830 -9114 12763 -7294 23842 -22171 7921 -1860 2543 7059 -2567 5982 3094 16403 1015 17010 -6896 4161 -940 -1425 20235 -23368 -14546 -11462 8935 -4527 -5181 5847 957 12284 -9610 11598 -3825 5682 -5219 5607 -11356 -21027 19184 -3114 8384 -8671 -6872 13211 -1813 -971 8539 3741 -16907 12915 SO 20161206T124509.0Z 6184.531354 4 1 32.00 2 89.57 122.53 137.10 48.17 0.00 1 0.00 1 0 15 7.547e-02 7.211e-02 8.348e-02 8.138e-02 2.028215e+03 4.825143e+03 3.174746e+02 -6.000000e+00 3.979190e+03 274.82 -2.00 20.00 -2.00 505.15 0.00e+00 1.293112e-03 2.179923e-03 5.584220e-05 -6.000000e+00 2.052807e-03 274.82 -2.00 20.00 -2.00 499.87 0.00e+00 -6.054431e-01 1.651058e+00 2.469345e-02 -6.000000e+00 1.478603e+00 222.31 -2.00 3.57 -2.00 501.55 0.00e+00 20.054 0.157 489.00 513.00 1 9.7096e+00 1.2637e-01 3.5691e-02 -6.0000e+00 1.1291e-01 1.9652e-01 3.3422e-02 1.9605e-03 -6.0000e+00 2.9643e-02 7.3985e-06 2.0318e-03 7.4075e-03 4.5410e-05 -6.0000e+00 7.1268e-03 -1.5151e-02 1.7913e-04 12 9 8 11 8 0 27.21 16.71 -3.79 -0.01515 -0.00106 8 2 1 4 0 4000.000 21.79 15.00 16.71 -8754 -622 -7378 4932 357 -1762 1985 -3896 -3597 5920 112 -1442 4227 -6186 16370 -4625 14571 -4868 4301 13869 7444 3125 188 -3399 6894 -343 4876 -9247 11732 -9045 1708 -2039 -2011 -2481 -3868 -13116 -118 -2640 5112 3746 1389 3399 4512 -274 7202 135 1180 -5922 -8936 673 1343 -3114 7133 -2699 9449 3297 2445 -6592 7085 -2443 531 -1909 -326 -6735 -3598 9842 7510 -2862 -12308 10359 9411 5387 2350 7081 10819 4950 -3779 12550 -5005 11653 8255 4819 -12074 -8379 -4286 -5803 -568 -7306 -6863 -581 -6644 5137 12036 17761 -13236 16295 -3155 13929 3404 -6164 3497 11688 -8979 -11812 -4751 -1432 7287 9762 -970 11782 18906 -6878 -4779 -4249 12920 11985 11725 -1286 10192 -2464 -14434 -2308 -1611 5446 -4322 -2212 -7129 -4326 1578 -6769 -8360 11395 -3494 -2581 6809 678 15400 914 -6930 1754 4461 -11062 5123 13078 -1895 6110 13217 -3209 -5830 -3169 -726 -9541 -641 -8433 5145 398 -2049 2255 -4712 -4303 6334 125 -1610 4382 -7030 14795 -5195 13750 -5726 4716 13918 7965 3490 216 -4066 7468 -399 5347 -11492 11461 -10519 1759 -2196 -2219 -2852 -4627 -17259 -134 -3053 5402 3983 1397 3378 4484 -289 7113 143 1230 -6539 -9977 665 1277 -3018 6170 -2600 8289 3175 2430 -7239 6780 -2563 541 -2002 -338 -7436 -3818 8996 6910 -2879 -13439 8896 8082 4824 2191 6385 9491 4586 -3756 10394 -4882 9579 7039 4286 -12814 -8635 -4285 -5944 -554 -7619 -7115 -567 -6929 4822 10706 15036 -15183 13695 -3155 11450 3028 -5899 3004 9321 -9033 -12680 -4896 -1441 6660 8564 -935 9974 15077 -7214 -4984 -4457 11492 10808 10645 -1334 9378 -2539 -16469 -2294 -1571 4944 -4349 -2184 -7391 -4352 1491 -6934 -8667 9576 -3105 -2235 5314 564 11228 786 -6552 1538 3837 -11154 4407 10429 -1760 5220 10389 -2906 -5280 -2744 -612 SO 20161206T124706.0Z 6184.532708 6 1 32.01 2 89.28 122.87 136.85 48.73 0.00 1 0.00 1 0 22 8.083e-02 7.682e-02 7.769e-02 7.552e-02 -1.602690e+03 4.169582e+03 5.997311e+02 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