File name: Pandora109s1_StGeorge_20170304_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T083555.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20170304_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20170304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170304T115404.0Z 6272.495880 2 1 32.00 2 89.86 98.80 118.78 23.57 0.00 1 0.00 1 0 29 3.414e-02 3.383e-02 2.678e-02 2.667e-02 3.925634e+03 1.590709e+03 2.296124e+02 -6.000000e+00 1.789960e+03 273.23 -2.00 20.00 -2.00 505.28 0.00e+00 2.469362e-03 7.116624e-04 1.315013e-04 -6.000000e+00 9.251919e-04 273.23 -2.00 20.00 -2.00 500.46 0.00e+00 3.109050e+00 5.215768e-01 5.196342e-02 -6.000000e+00 6.737644e-01 225.33 -2.00 3.57 -2.00 502.05 0.00e+00 20.518 0.168 489.00 513.00 1 8.1957e+00 3.9805e-02 3.7474e-02 -6.0000e+00 5.1375e-02 4.0367e-02 1.0244e-02 2.2599e-03 -6.0000e+00 1.3548e-02 2.3640e-05 4.0335e-03 2.4345e-03 5.1382e-05 -6.0000e+00 3.2264e-03 -3.3579e-03 -8.4840e-05 12 8 8 10 0 0 46.58 16.12 2.57 -0.00336 0.02462 8 2 1 4 0 4000.000 21.48 14.99 16.12 -4067 -797 -3392 3474 -1953 1098 3471 -563 3033 -1449 5595 -3120 1465 -4053 -4268 1023 -2786 978 -18 9135 1035 413 -1311 1876 -3227 -2073 4646 -4813 2486 -4636 1996 1148 -2211 -985 -3731 4846 -2206 6071 322 -1279 547 310 1220 -3271 6504 -4340 9059 -3275 -468 -1946 669 -428 -7366 6013 -1304 -222 -471 -1975 3912 -2373 4630 2793 5274 381 3965 -217 -2846 1809 1572 842 -4097 1878 -3031 4709 -846 -84 -1294 463 5421 -5605 1387 -5253 -1673 -1406 434 728 231 5361 -4401 4444 -5591 -2033 -1411 -863 1372 -3064 5205 -960 3805 -7250 -849 1762 -2956 1303 1057 8061 1846 4493 -2473 717 -815 -2685 1208 -3559 8753 -1180 2818 1850 -1204 -1289 -5156 1821 -1776 4987 -752 939 -424 -3941 -1 2602 1634 3212 314 -1034 -1316 -6776 -434 1535 -2300 4517 269 4205 -1874 1132 3137 156 4843 -3987 -325 -7362 1517 -3861 -752 -3413 3381 -2058 1148 3606 -613 3170 -1562 5543 -3329 1470 -4254 -4480 1027 -2960 1028 -20 9170 1129 419 -1357 1893 -3451 -2196 4585 -5156 2409 -4668 1853 1083 -2209 -1010 -4049 4860 -2355 5894 327 -1314 553 317 1253 -3563 6498 -4850 8813 -3561 -486 -2003 651 -410 -7477 5379 -1290 -225 -489 -2108 3940 -2537 4616 2851 5279 401 3993 -225 -2975 1778 1529 814 -4117 1778 -3040 4429 -851 -84 -1282 442 4860 -5577 1288 -5247 -1624 -1371 420 708 227 4989 -4502 4163 -5821 -2067 -1449 -890 1376 -3160 4834 -924 3403 -7083 -768 1562 -2816 1236 1041 7518 1825 4271 -2491 699 -817 -2596 1143 -3580 7858 -1178 2724 1819 -1223 -1299 -5322 1727 -1727 4533 -730 903 -414 -4002 -1 2477 1571 3016 299 -984 -1248 -6817 -417 1481 -2353 4384 276 4176 -1990 1175 3209 165 4836 -4271 -329 -7846 1478 SO 20170304T115605.0Z 6272.497280 4 1 32.00 2 89.50 99.14 118.63 24.07 0.00 1 0.00 1 0 22 2.290e-02 2.300e-02 2.767e-02 2.748e-02 3.749614e+03 1.649698e+03 2.789932e+02 -6.000000e+00 1.200857e+03 273.23 -2.00 20.00 -2.00 505.20 0.00e+00 1.684254e-03 7.280660e-04 8.142011e-05 -6.000000e+00 6.207881e-04 273.23 -2.00 20.00 -2.00 500.16 0.00e+00 1.733996e+00 5.459788e-01 2.881584e-02 -6.000000e+00 4.522400e-01 225.33 -2.00 3.57 -2.00 501.78 0.00e+00 19.943 0.154 489.00 513.00 1 8.4222e+00 4.1608e-02 3.5412e-02 -6.0000e+00 3.4480e-02 1.0297e-01 1.0873e-02 2.0386e-03 -6.0000e+00 9.0991e-03 2.2885e-05 1.4530e-03 2.5042e-03 4.6570e-05 -6.0000e+00 2.1650e-03 2.1761e-02 -2.7742e-04 12 9 8 11 8 0 -203.68 16.12 -0.47 0.02176 0.03184 8 2 1 4 0 4000.000 21.48 15.00 16.12 -3517 1128 -2406 976 1393 612 1999 963 -5616 1262 794 -2402 348 -1983 95 -2728 -3356 2099 1569 2568 -3134 -541 -4113 758 959 -1779 -1003 1211 845 -2356 3348 -3222 2166 -1628 1378 2180 1041 5861 1549 1915 -5049 775 914 1009 1318 -2467 3519 770 3503 2580 -871 -700 3452 1048 2784 1339 -1699 -138 -2320 -877 2177 805 1113 1400 8 -1534 214 -2968 -1606 -436 738 -1615 1937 1714 566 3167 15 -1759 -1772 -976 2108 -3410 165 -1320 2272 -163 -2819 1766 2372 -1924 598 1000 -1001 1917 2831 635 1003 -882 2445 -1953 2984 -1476 -1545 800 -1690 2546 -1315 -320 1854 2032 -665 1842 4767 -4721 4776 -4066 -1708 917 3080 -3777 -3187 -281 -189 2806 1898 443 -1950 784 -1582 142 3200 999 901 -1728 -2703 -6342 -2252 -2691 297 -995 -2792 3896 4626 1780 691 -1541 -3185 722 577 1070 -1988 -3481 1088 -2495 1015 1478 669 2193 1076 -6679 1382 860 -2652 368 -2118 99 -2938 -3698 2246 1732 2841 -3678 -619 -4507 795 1009 -1928 -1075 1254 856 -2382 3134 -3230 2100 -1700 1441 2285 1096 5803 1582 1932 -5459 796 949 1060 1395 -2724 3645 811 3526 2560 -868 -677 3154 983 2630 1326 -1781 -144 -2484 -923 2219 835 1158 1452 8 -1608 217 -3055 -1610 -427 705 -1576 1838 1651 558 3044 15 -1717 -1703 -924 1934 -3327 157 -1279 2146 -159 -2844 1701 2265 -1917 583 982 -1018 1914 2791 630 970 -848 2213 -1804 2583 -1339 -1434 753 -1690 2489 -1335 -318 1774 1932 -655 1800 4601 -4713 4709 -4091 -1688 889 2927 -3814 -3151 -265 -176 2526 1734 413 -1868 732 -1510 133 2905 920 818 -1586 -2480 -6039 -2088 -2562 280 -965 -2787 3664 4342 1729 682 -1556 -3247 696 544 984 -1874 SO 20170304T115802.0Z 6272.498634 6 1 32.01 2 89.15 99.48 118.49 24.55 0.00 1 0.00 1 0 15 2.637e-02 2.616e-02 2.197e-02 2.183e-02 -5.858193e+01 1.167168e+03 2.650385e+01 -6.000000e+00 1.382581e+03 273.23 -2.00 20.00 -2.00 505.21 0.00e+00 2.023029e-03 5.800228e-04 1.042598e-04 -6.000000e+00 7.145976e-04 273.23 -2.00 20.00 -2.00 500.22 0.00e+00 3.131089e+00 4.297801e-01 1.942304e-02 -6.000000e+00 5.202961e-01 225.33 -2.00 3.57 -2.00 501.83 0.00e+00 19.210 0.138 489.00 513.00 1 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