File name: Pandora109s1_StGeorge_20170823_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T092559.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20170823_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20170823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170823T103658.0Z 6444.442338 2 1 31.99 2 89.88 74.41 109.24 63.01 0.00 1 0.00 1 0 57 2.325e-02 2.301e-02 2.537e-03 2.514e-03 1.296533e+04 1.709673e+02 8.440033e+02 -6.000000e+00 1.286260e+03 286.96 -2.00 20.00 -2.00 505.46 0.00e+00 6.251947e-03 6.987619e-05 3.416495e-04 -6.000000e+00 6.519281e-04 286.96 -2.00 20.00 -2.00 501.29 0.00e+00 1.558560e-02 4.730110e-02 1.014304e-01 -6.000000e+00 4.596041e-01 231.20 -2.00 3.57 -2.00 502.73 0.00e+00 20.146 0.159 489.00 513.00 1 5.6833e+00 3.6133e-03 3.7959e-02 -6.0000e+00 3.5175e-02 -2.4428e-02 9.0973e-04 2.9431e-03 -6.0000e+00 9.2864e-03 3.5938e-04 1.1203e-02 2.2379e-04 1.4803e-04 -6.0000e+00 2.1987e-03 7.3642e-02 -7.6514e-04 12 8 8 10 0 0 -72.65 16.93 16.94 0.07364 0.15135 8 2 1 4 0 4000.000 22.09 15.00 16.93 -5035 -4296 -1023 722 2211 3000 3697 4156 2306 1961 309 -581 -2139 -1952 -2437 -3028 -1140 40 1720 1947 1441 1680 1965 1996 2283 2914 1976 934 -1368 -3256 -4237 -3303 -1826 179 1639 1102 384 -376 -612 -720 -612 860 1198 2538 2720 3469 2885 2247 116 -642 -2853 -4100 -3833 -3517 -1177 618 1958 1902 2328 1552 2029 3073 2637 2628 1524 558 -450 -1813 -1394 -2600 -3588 -2803 -2061 -1299 -907 -656 -2322 -2397 -3326 -3044 -3515 -2442 -2390 -2304 -1475 -1573 -1035 -1706 -999 -2094 -49 235 1989 2403 2652 2146 448 -269 -2319 -3745 -5173 -4276 -2912 -1724 656 515 -128 -1845 -1102 -1197 -671 1301 1927 2595 3424 4398 4128 4755 3822 2903 1538 416 1048 789 1715 2084 2088 1579 1109 1290 564 503 -1142 -1432 -2410 -2186 -1266 -158 923 1061 1807 946 1623 1155 1857 1218 750 -822 -2987 -4347 -4775 -4324 -3783 -909 653 2019 2778 3452 3877 2029 1826 270 -504 -1858 -1799 -2108 -2663 -1004 36 1546 1759 1311 1530 1794 1841 2121 2700 1843 868 -1263 -2976 -3879 -3033 -1703 170 1580 1072 373 -365 -591 -697 -598 841 1190 2533 2748 3501 2921 2268 118 -642 -2842 -4057 -3766 -3502 -1184 593 1901 1871 2288 1539 2012 3046 2646 2642 1540 562 -452 -1823 -1382 -2581 -3574 -2783 -2055 -1306 -917 -660 -2336 -2372 -3289 -2989 -3475 -2405 -2373 -2307 -1484 -1599 -1048 -1734 -1002 -2122 -49 238 2017 2440 2648 2096 431 -253 -2183 -3511 -4882 -4050 -2814 -1726 669 537 -135 -1960 -1154 -1263 -675 1310 1961 2651 3496 4483 4274 4965 4058 3092 1635 439 1085 819 1780 2175 2193 1675 1184 1376 605 535 -1215 -1512 -2565 -2343 -1371 -173 1017 1185 2031 1083 1859 1336 2138 1409 864 -944 -3440 -5017 -5247 SO 20170823T103857.0Z 6444.443715 4 1 33.90 2 89.54 74.76 108.93 63.39 0.00 1 0.00 1 0 50 1.897e-02 1.876e-02 1.175e-03 1.168e-03 1.637555e+04 8.195666e+01 1.098962e+03 -6.000000e+00 1.049835e+03 286.96 -2.00 20.00 -2.00 505.44 0.00e+00 5.439373e-03 3.247270e-05 3.066091e-04 -6.000000e+00 5.315979e-04 286.96 -2.00 20.00 -2.00 501.18 0.00e+00 3.906874e-01 2.224411e-02 1.095983e-01 -6.000000e+00 3.740485e-01 231.20 -2.00 3.57 -2.00 502.65 0.00e+00 19.638 0.147 489.00 513.00 1 4.8393e+00 1.7030e-03 3.6465e-02 -6.0000e+00 2.8646e-02 -5.6228e-02 4.2829e-04 3.1997e-03 -6.0000e+00 7.5320e-03 8.7868e-04 6.9986e-03 1.0071e-04 1.6205e-04 -6.0000e+00 1.7941e-03 1.1256e-02 -1.5294e-04 12 9 9 12 2 2 70.43 16.93 22.60 0.01126 0.05980 13 0 1 4 0 2607.923 22.09 15.00 16.93 -3697 -1619 -788 1508 2297 3178 3266 3415 2599 2262 454 -66 -617 -2692 -3594 -1578 -550 131 1442 -756 -120 786 366 2256 2780 1428 1797 201 -1229 -2933 -4307 -2665 -1146 -202 1156 731 1582 -191 -316 -1068 173 950 844 1041 2231 2358 2374 373 1433 -724 -1673 -3008 -3705 -2693 -628 667 1663 2374 1531 1922 1665 510 980 1939 1590 293 -532 -410 -1456 -3583 -2051 -2906 -1356 -89 -330 -1582 -769 -2804 -3323 -2209 -2098 -2276 -2300 -1541 -1288 -506 -404 -664 -2235 -662 -389 1183 1668 2285 2596 1405 918 178 -1244 -4211 -3929 -3735 -2582 -1106 -189 248 850 -517 -728 -599 -894 -479 1360 2322 3013 3094 4270 4412 2539 511 95 1217 459 209 1085 326 -376 453 1667 1063 461 -409 593 -901 -2221 -838 -598 125 136 1906 1154 1552 710 1437 1305 1102 490 -392 -3062 -2478 -3206 -3214 -1423 -687 1331 2063 2895 3021 3170 2415 2078 420 -60 -561 -2480 -3344 -1456 -513 120 1331 -720 -113 742 349 2130 2638 1379 1725 194 -1166 -2749 -4061 -2502 -1093 -191 1109 708 1507 -184 -302 -1029 166 920 833 1044 2243 2382 2392 366 1422 -718 -1631 -2915 -3600 -2631 -622 650 1647 2364 1542 1931 1686 527 1017 1997 1633 301 -544 -414 -1471 -3659 -2050 -2944 -1369 -90 -338 -1578 -777 -2841 -3348 -2190 -2082 -2278 -2324 -1561 -1273 -502 -401 -658 -2234 -651 -384 1168 1665 2270 2523 1388 880 167 -1157 -3969 -3673 -3540 -2513 -1078 -191 257 877 -519 -728 -603 -919 -500 1411 2406 3119 3226 4465 4689 2684 548 101 1295 485 221 1150 340 -397 477 1739 1117 487 -432 610 -933 -2333 -878 -639 136 145 2033 1259 1706 794 1605 1462 1235 548 -435 -3428 -2732 -3579 SO 20170823T104037.6Z 6444.444879 6 1 33.13 2 89.24 75.05 108.67 63.72 0.00 1 0.00 1 0 43 1.508e-02 1.485e-02 9.992e-04 9.897e-04 1.695053e+04 7.055070e+01 1.121048e+03 -6.000000e+00 8.346735e+02 286.96 -2.00 20.00 -2.00 505.49 0.00e+00 5.251946e-03 2.765897e-05 2.891022e-04 -6.000000e+00 4.227815e-04 286.96 -2.00 20.00 -2.00 501.29 0.00e+00 5.137814e-01 1.875322e-02 1.140743e-01 -6.000000e+00 2.977389e-01 231.20 -2.00 3.57 -2.00 502.75 0.00e+00 19.076 0.135 489.00 513.00 1 4.3328e+00 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