File name: Pandora109s1_StGeorge_20170902_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T092549.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20170902_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20170902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170902T104811.0Z 6454.450127 2 1 32.00 2 89.86 79.39 130.39 282.76 0.00 1 0.00 1 0 15 3.649e-02 3.638e-02 3.950e-02 3.924e-02 1.131582e+04 2.738999e+03 7.457521e+02 -6.000000e+00 2.012655e+03 286.12 -2.00 20.00 -2.00 505.27 0.00e+00 1.428338e-03 1.076123e-03 5.330783e-05 -6.000000e+00 1.020629e-03 286.12 -2.00 20.00 -2.00 500.34 0.00e+00 7.500319e-01 7.729975e-01 7.271378e-02 -6.000000e+00 7.195178e-01 230.27 -2.00 3.57 -2.00 501.95 0.00e+00 20.150 0.159 489.00 513.00 1 8.7757e+00 5.9065e-02 3.6601e-02 -6.0000e+00 5.5081e-02 8.8121e-02 1.5305e-02 2.6280e-03 -6.0000e+00 1.4499e-02 1.6447e-05 -1.6244e-03 3.4502e-03 7.9605e-05 -6.0000e+00 3.4519e-03 5.1855e-02 -4.5881e-04 12 8 8 10 0 0 -9.01 16.53 5.24 0.05186 0.04059 8 2 1 4 0 4000.000 21.88 15.00 16.53 -7591 931 -901 -1326 1398 -7102 2446 -3593 7989 2 4348 -3347 891 -8264 3163 -3930 3214 6690 739 -1571 1367 905 430 3465 3810 -825 8075 -5073 -5170 252 -3205 -3458 -734 4619 -2750 7357 2976 -1648 -5886 289 -1275 1134 -1758 1565 2485 261 -5654 1887 -3055 -3566 1149 4282 9585 9610 -4793 -1762 -2334 1025 -4199 2061 4275 3827 5048 -1292 1420 2571 985 2427 -4678 566 628 2505 1053 1755 -1094 -1335 5641 -2755 -1421 -2032 4380 -6608 -1597 -2278 -2300 5090 -1524 -973 6250 -1785 -3059 4744 -227 2691 5510 -4094 5030 -94 695 -3108 2939 -1253 -2417 -17 2615 2560 4769 -24 3791 -3948 -6331 -4311 3945 122 3453 3189 990 -6008 306 2989 -582 3165 -3327 -1756 -2363 -4738 2538 -1304 3029 3454 698 -8311 1472 3004 -790 -3827 -4959 112 353 5142 540 1076 -1135 2759 -120 -2763 643 -1852 3650 -2462 -634 -7540 865 -883 -1355 1429 -8078 2578 -4064 8037 2 4416 -3625 911 -9134 3101 -4156 3213 6623 798 -1761 1494 994 475 3731 4114 -936 8357 -5476 -5459 244 -3137 -3395 -714 4413 -2928 7181 3019 -1730 -6372 292 -1305 1140 -1841 1606 2558 277 -6337 1942 -3253 -3734 1115 3913 8164 8185 -4820 -1777 -2437 1052 -4557 2096 4248 3837 5032 -1376 1465 2593 993 2376 -4857 551 604 2356 1012 1698 -1103 -1354 5272 -2746 -1374 -1959 3951 -6684 -1549 -2244 -2292 4773 -1537 -976 5804 -1790 -3112 4504 -230 2666 5264 -4201 4567 -87 621 -2822 2478 -1104 -2209 -16 2490 2521 4640 -24 3655 -4086 -6760 -4577 3908 127 3483 3235 1034 -6319 305 2898 -577 2964 -3261 -1678 -2278 -4711 2356 -1261 2803 3177 659 -8537 1350 2673 -725 -3626 -4821 106 340 4787 533 1070 -1162 2736 -123 -2906 650 -1892 3459 -2434 -611 SO 20170902T105011.0Z 6454.451516 4 1 32.00 2 89.50 79.73 130.73 283.17 0.00 1 0.00 1 0 15 2.857e-02 2.812e-02 3.151e-02 3.132e-02 7.723393e+03 2.088361e+03 5.386170e+02 -6.000000e+00 1.575768e+03 286.12 -2.00 20.00 -2.00 505.25 0.00e+00 1.469016e-03 8.527308e-04 7.843654e-05 -6.000000e+00 7.990755e-04 286.12 -2.00 20.00 -2.00 500.37 0.00e+00 1.418747e+00 6.130871e-01 4.405759e-02 -6.000000e+00 5.633206e-01 230.27 -2.00 3.57 -2.00 501.96 0.00e+00 19.612 0.147 489.00 513.00 1 8.5770e+00 4.6782e-02 3.4656e-02 -6.0000e+00 4.3124e-02 7.5387e-02 1.2133e-02 2.1811e-03 -6.0000e+00 1.1351e-02 2.0713e-05 5.0015e-03 2.8150e-03 6.6798e-05 -6.0000e+00 2.7026e-03 5.3476e-02 -4.6704e-04 12 8 8 10 0 0 -724.84 16.54 2.19 0.05348 0.08817 8 2 1 4 0 4000.000 21.88 14.99 16.54 -419 5288 -1101 -1461 -2204 -3557 2573 -2698 3297 -297 4207 -364 -933 -2235 2880 704 -810 3175 285 748 -3611 -1020 -5075 3177 -173 354 -338 1505 1725 -4115 2640 -1347 1921 2346 528 3566 -3639 -643 2870 -1051 82 3083 -1011 1219 209 -839 2419 -867 999 594 -3149 -348 2036 -390 2418 -2415 -2697 -2490 1377 2020 1822 3569 -3593 7892 -6028 -1968 -625 -2983 -1397 5175 -283 -4929 1059 279 -1018 823 5349 -1570 1306 2742 -2913 -1724 1065 -3896 655 3173 1836 3404 -3872 -2763 -4097 3946 1755 177 686 -1381 4232 3208 401 -4195 -522 4796 -6458 595 -2127 -2231 -1626 2837 -2867 -654 -2735 724 -1569 4424 7631 -903 327 -43 -155 5644 -989 1987 -114 8581 -659 1109 3260 366 -1574 -1190 -3585 -2977 -4383 1785 -2588 -606 -435 -2060 2519 -2423 975 5653 -1411 2642 -3163 -755 -3301 925 -821 -162 5809 -391 4774 -1101 -1517 -2362 -3949 2731 -3036 3475 -320 4272 -381 -969 -2327 2844 716 -854 3306 313 824 -4166 -1148 -5500 3188 -180 368 -352 1517 1686 -4129 2443 -1307 1850 2337 551 3629 -3944 -668 2846 -1077 83 3064 -1059 1267 222 -901 2502 -915 1016 592 -3160 -332 1870 -370 2295 -2486 -2852 -2658 1415 2055 1859 3598 -3911 7658 -6675 -2063 -636 -3064 -1396 4778 -273 -4992 1020 275 -1027 812 4964 -1531 1221 2512 -2827 -1664 1008 -3909 635 3034 1786 3255 -3968 -2798 -4227 3801 1753 181 688 -1383 3897 2901 364 -3902 -463 4076 -6328 567 -2169 -2323 -1682 2773 -2931 -653 -2822 734 -1648 4419 7423 -893 322 -43 -155 5296 -976 1869 -108 7431 -630 1048 3024 350 -1532 -1153 -3553 -2905 -4266 1612 -2429 -561 -409 -2014 2397 -2459 969 5403 -1457 2635 -3356 -781 -3474 916 -810 -156 5273 SO 20170902T105208.0Z 6454.452870 6 1 32.00 2 89.16 80.07 131.06 283.56 0.00 1 0.00 1 0 15 2.670e-02 2.621e-02 2.560e-02 2.545e-02 8.887763e+03 1.733370e+03 6.372980e+02 -6.000000e+00 1.472900e+03 286.12 -2.00 20.00 -2.00 505.27 0.00e+00 2.732609e-03 6.999919e-04 1.354401e-04 -6.000000e+00 7.466638e-04 286.12 -2.00 20.00 -2.00 500.39 0.00e+00 1.723788e+00 5.021214e-01 5.226289e-02 -6.000000e+00 5.257781e-01 230.27 -2.00 3.57 -2.00 501.98 0.00e+00 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