File name: Pandora109s1_StGeorge_20170908_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T092607.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20170908_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20170908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170908T105450.0Z 6460.454745 2 1 32.00 2 89.86 82.49 67.58 248.15 0.00 1 0.00 1 0 22 9.762e-02 9.353e-02 7.401e-02 7.200e-02 1.776475e+04 5.516383e+03 1.079204e+03 -6.000000e+00 5.372917e+03 285.61 -2.00 20.00 -2.00 505.24 0.00e+00 3.674936e-03 1.985328e-03 1.767843e-04 -6.000000e+00 2.731944e-03 285.61 -2.00 20.00 -2.00 499.97 0.00e+00 7.847232e-01 1.457640e+00 1.123135e-01 -6.000000e+00 1.932786e+00 229.72 -2.00 3.57 -2.00 501.63 0.00e+00 20.170 0.160 489.00 513.00 1 9.3441e+00 1.1180e-01 3.7547e-02 -6.0000e+00 1.4777e-01 1.1364e-01 2.8764e-02 3.2398e-03 -6.0000e+00 3.9170e-02 8.7761e-06 7.1172e-03 5.9968e-03 1.3712e-04 -6.0000e+00 9.2207e-03 7.2626e-02 -1.0134e-03 12 9 8 11 8 0 -130.75 16.53 9.87 0.07263 0.12199 8 2 1 4 0 4000.000 21.79 15.00 16.53 21478 -5587 9478 -7570 8458 5366 -7492 15066 -7905 -10734 -2353 10345 -15890 4330 1939 -9667 3715 -6917 3013 -4554 2370 -1260 5771 7325 6382 10666 -896 14761 -11615 8328 -925 -4229 8382 2107 5535 -6399 5234 -9128 14298 -15745 2595 -3930 5234 1875 -12241 5434 -2362 12579 5992 7144 11270 2572 6134 -1934 9553 -10911 -5602 576 -3574 6046 -921 4193 -9530 23074 -5486 5550 3887 9004 13664 -2534 -2185 -8389 18939 2984 8204 -14452 891 6811 -14943 12516 -19509 1088 -5590 5942 4044 85 600 -18898 -614 -5273 10196 3142 9772 9229 426 7852 -6134 5805 -10181 16992 1129 591 2391 -11698 -2446 -206 17145 -5435 22595 -9158 5414 -2666 -4608 4130 975 32292 -1413 11842 -10455 14169 15969 -1627 -3938 -3183 9520 -13619 4891 -1459 -7150 18752 -19960 7797 -6724 16045 -14516 17763 8809 -3458 9048 1415 11376 -2733 -6328 7718 9596 -6752 34 -5906 -11694 15636 -3081 16544 -5749 8694 -8546 8355 5585 -9031 14617 -9621 -13254 -2629 10036 -19714 4329 1972 -11084 3779 -8012 3242 -5355 2606 -1437 6142 7709 6829 10975 -1033 14408 -14411 8177 -974 -4600 8182 2267 5955 -7259 5694 -10453 13872 -18886 2591 -4223 5199 1954 -14882 5574 -2615 11879 5951 6864 10093 2443 5527 -1889 8503 -12318 -6172 607 -3938 6038 -985 4278 -11224 19663 -6194 5543 3882 8405 12014 -2585 -2194 -8925 15419 2883 7614 -16865 880 6211 -16626 10462 -22342 1016 -5613 5353 3753 83 586 -22361 -600 -5352 8854 2950 8698 8316 414 6862 -5926 4789 -9560 11897 913 482 1959 -11555 -2323 -199 14145 -5604 17415 -9643 4966 -2692 -4802 3968 968 23486 -1450 10798 -12087 12843 14041 -1669 -4040 -3196 8422 -15301 4593 -1465 -7063 15368 -22332 6563 -6438 12049 -14705 13071 7193 -3259 7661 1313 9689 -2714 -6570 7001 8561 -7078 33 -6012 -12377 12372 -2920 SO 20170908T105650.0Z 6460.456134 4 1 32.00 2 89.50 82.83 67.90 248.54 0.00 1 0.00 1 0 29 6.612e-02 6.477e-02 5.620e-02 5.493e-02 1.151146e+04 4.056452e+03 9.286652e+02 -6.000000e+00 3.639796e+03 285.61 -2.00 20.00 -2.00 505.24 0.00e+00 -3.824043e-05 1.499723e-03 7.512964e-05 -6.000000e+00 1.846484e-03 285.61 -2.00 20.00 -2.00 499.86 0.00e+00 2.752008e+00 1.119823e+00 3.490518e-02 -6.000000e+00 1.300960e+00 229.72 -2.00 3.57 -2.00 501.55 0.00e+00 19.626 0.147 489.00 513.00 1 9.0714e+00 8.5676e-02 3.4617e-02 -6.0000e+00 9.9618e-02 9.7590e-02 2.1985e-02 2.2699e-03 -6.0000e+00 2.6161e-02 1.1540e-05 3.3189e-03 4.7132e-03 8.5291e-05 -6.0000e+00 6.2499e-03 3.3050e-02 -2.0833e-04 12 8 8 10 0 0 -109.67 16.53 1.88 0.03305 0.05607 8 2 1 4 0 4000.000 21.79 15.00 16.53 -8799 5872 -2815 3458 -5976 75 -9944 -2410 1667 -929 5950 -4780 4330 -7379 6216 7153 5229 5923 -3229 5446 -10094 13250 -1634 6633 3068 -7041 3186 896 4797 -4894 8153 5360 2390 4079 -5820 -725 -5429 -5316 -6224 2224 3878 6630 385 -39 3480 -4033 2795 -4000 12871 -7924 5168 345 1290 11367 -8416 8840 -2678 6717 7403 4419 -2136 670 1005 -12962 -2035 -1638 -7713 -881 -113 3721 -9920 5051 -9335 12919 -3915 15272 -429 2745 9283 912 10942 -6871 11267 -7744 12870 1715 -2344 5235 -244 4399 -4421 2560 -2403 6210 -3147 -2365 2914 2127 6120 5271 -147 -5643 -9902 2240 -7337 -2578 -6561 5609 -8955 5515 -225 14551 -1416 -3456 3967 -3329 6059 -2071 2608 -4233 4041 1555 -6025 16080 -5473 6005 10024 5466 3047 1600 11550 -3600 -3526 -3771 2693 -22488 8885 -5617 -1332 6717 -2869 6444 -4613 6944 -7890 10950 1902 -3844 -177 -10375 8093 -9394 5558 -3018 3599 -6997 84 -12579 -2843 1877 -1058 6246 -5511 4487 -8507 6246 7188 5465 6324 -3868 6034 -13086 13611 -1950 7319 3523 -8939 3630 1029 5143 -5598 8083 5506 2594 4519 -6748 -801 -6228 -6009 -7010 2283 3918 6562 409 -42 3660 -4576 2940 -4439 11832 -8728 4836 330 1207 9696 -8991 8200 -2850 6564 7173 4392 -2265 694 1040 -15405 -2149 -1695 -8336 -875 -110 3436 -10392 4560 -9818 11020 -3988 12774 -412 2500 7803 827 8971 -6772 9331 -7825 10712 1612 -2300 4747 -233 3989 -4394 2396 -2388 5657 -3088 -2232 2522 1797 4840 4125 -121 -4954 -9390 1976 -7443 -2552 -6765 5063 -9233 4910 -214 12110 -1396 -3492 3729 -3378 5645 -2118 2559 -4417 3815 1475 -6062 12918 -5484 5396 8675 4956 2827 1504 9804 -3267 -3145 -3335 2226 -24125 7106 -5313 -1229 5811 -2769 5723 -4612 6221 -8222 9431 1777 -3740 -162 -10412 6752 SO 20170908T105847.0Z 6460.457488 6 1 31.99 2 89.15 83.17 68.22 248.92 0.00 1 0.00 1 0 22 4.436e-02 4.391e-02 4.178e-02 4.114e-02 7.871146e+03 2.810391e+03 8.125536e+02 -6.000000e+00 2.442064e+03 285.61 -2.00 20.00 -2.00 505.17 0.00e+00 1.410239e-03 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