File name: Pandora109s1_StGeorge_20171228_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T095639.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20171228_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20171228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171228T125655.0Z 6571.539525 2 1 32.00 2 89.88 123.21 129.09 358.38 0.00 1 0.00 1 0 29 4.413e-02 4.287e-02 4.414e-02 4.350e-02 5.654772e+02 2.409356e+03 7.021011e+01 -6.000000e+00 2.311202e+03 273.08 -2.00 20.00 -2.00 505.18 0.00e+00 4.300422e-03 1.152632e-03 2.226122e-04 -6.000000e+00 1.196176e-03 273.08 -2.00 20.00 -2.00 499.95 0.00e+00 2.715587e+00 8.722747e-01 4.175384e-02 -6.000000e+00 8.688064e-01 222.70 -2.00 3.57 -2.00 501.61 0.00e+00 20.552 0.169 489.00 513.00 1 8.7264e+00 6.6462e-02 3.7675e-02 -6.0000e+00 6.6255e-02 1.1643e-01 1.7585e-02 2.0945e-03 -6.0000e+00 1.7482e-02 1.3979e-05 2.9527e-04 3.9787e-03 7.7571e-05 -6.0000e+00 4.1711e-03 -3.7428e-03 -1.4992e-04 12 8 8 10 0 0 97.58 15.20 3.36 -0.00374 -0.00169 8 2 1 4 0 4000.000 21.06 15.00 15.20 -2487 3769 -9135 4214 800 -324 -112 3540 -3952 2047 2306 -5222 2163 -6447 4939 -6467 -3502 -2475 4568 -303 -465 5322 -1906 1974 3335 4658 3760 -4357 2238 -4792 4570 -5889 7010 2894 773 -451 1377 2651 4052 -668 1924 -3570 -4407 -3284 -4974 6009 741 -1836 -1641 -1425 2105 270 -5768 2023 -1941 955 -2042 4895 -4216 -551 3694 -384 -1116 -3744 2473 -1081 9120 2629 7096 118 -3588 2724 -1908 -481 2318 4859 -629 2870 10525 1125 596 -28 570 -3843 2330 3440 3401 5752 -3952 8611 -5363 -378 -1716 -846 -2093 -3257 -524 -5911 14268 -4470 1794 6335 1236 5580 318 3866 -6385 2220 -10050 7183 -2589 8634 5256 -761 239 -4003 -540 -1070 -4300 -2746 -7968 3448 1984 2102 -4859 9903 -1552 2939 533 -5963 4252 -1395 7492 -1288 -5593 -5260 5211 -12221 -130 2357 -4062 5287 2 4077 669 7469 2818 -2481 1552 1021 -5817 -2474 3588 -10254 4296 867 -363 -127 3911 -4689 2255 2490 -5992 2267 -7259 4930 -7259 -3869 -2769 4885 -344 -530 5728 -2208 2209 3709 5129 4167 -5185 2432 -5397 4578 -6548 6972 2866 809 -484 1441 2703 4026 -690 1937 -3828 -4826 -3607 -5626 6128 795 -1998 -1754 -1486 2057 261 -5825 1891 -1929 952 -2156 4896 -4631 -582 3731 -405 -1193 -4112 2538 -1134 8493 2569 6538 115 -3577 2536 -1871 -470 2227 4557 -615 2653 8869 1033 550 -26 531 -3755 2155 3169 3145 5186 -3914 7511 -5399 -366 -1710 -849 -2135 -3332 -514 -5989 11509 -4236 1565 5255 1094 4867 302 3587 -6532 2053 -10348 6194 -2488 7559 4860 -761 240 -4227 -554 -1109 -4597 -2863 -8622 3279 1894 1856 -4631 8201 -1446 2622 487 -5810 3742 -1292 6250 -1153 -5160 -4821 4347 -12391 -119 2139 -3970 4732 2 3724 635 6641 2609 -2379 1394 901 -5455 SO 20171228T125855.0Z 6571.540914 4 1 32.00 2 89.58 123.56 129.09 358.99 0.00 1 0.00 1 0 15 3.719e-02 3.622e-02 3.672e-02 3.626e-02 1.552087e+03 2.050879e+03 1.731719e+01 -6.000000e+00 1.947463e+03 273.08 -2.00 20.00 -2.00 505.17 0.00e+00 2.319945e-03 9.571287e-04 1.213671e-04 -6.000000e+00 1.007861e-03 273.08 -2.00 20.00 -2.00 500.01 0.00e+00 2.476689e+00 7.204805e-01 4.372451e-02 -6.000000e+00 7.319102e-01 222.70 -2.00 3.57 -2.00 501.66 0.00e+00 20.092 0.158 489.00 513.00 1 8.6475e+00 5.4973e-02 3.5973e-02 -6.0000e+00 5.5818e-02 1.0656e-01 1.4482e-02 2.0677e-03 -6.0000e+00 1.4723e-02 1.6861e-05 2.0544e-03 3.3224e-03 4.1774e-05 -6.0000e+00 3.5149e-03 8.3727e-03 -2.0307e-04 12 8 8 10 0 0 80.03 15.21 3.57 0.00837 0.02262 8 2 1 4 0 4000.000 21.06 15.00 15.21 -4417 4417 -7068 1228 6638 909 -1553 3408 -4276 3749 571 550 -1360 697 -6631 200 1251 742 -480 -3438 -210 -411 3899 2475 -3811 -110 -1002 -881 3419 -2742 -25 1375 3687 -1456 -1644 -1709 3442 11922 -922 4986 -3570 2983 -2678 -6334 472 4001 2259 -4258 1978 1187 604 5333 -3759 -936 1737 1865 386 5223 230 146 -6642 -660 -719 -1720 747 -3009 1126 -2647 114 4753 -2813 -1950 1312 9729 5113 2191 -4851 3342 -1399 -2119 488 -6636 590 -3152 6522 3796 -2126 5596 -763 2679 -325 -2055 -1566 2397 3155 -1668 1233 -4442 -837 -6190 9857 -1326 -3541 676 1913 7518 90 -2764 -3966 1901 -7958 -459 814 -3096 1986 5172 2163 2638 2824 -3680 -3925 1007 5293 1635 2007 -1258 2023 -2285 -4786 -553 237 2606 2187 1137 5413 1779 9235 -1752 -9698 2836 -6898 167 -1230 8347 -1437 -285 1373 914 -2891 -3319 830 -4447 4160 -7743 1283 6742 999 -1780 3744 -5052 4030 624 593 -1470 729 -7422 210 1322 808 -543 -4052 -240 -471 4284 2770 -4570 -128 -1166 -1012 3665 -3020 -24 1429 3528 -1521 -1775 -1864 3538 11112 -965 4879 -3805 3000 -2885 -7167 504 4145 2371 -4713 2022 1194 593 4854 -3689 -896 1657 1835 395 5168 239 152 -7371 -693 -759 -1833 772 -3182 1123 -2699 111 4378 -2760 -1892 1241 8563 4765 2103 -4919 3060 -1323 -2004 449 -6602 550 -3067 5812 3507 -2092 5094 -738 2504 -314 -2045 -1575 2346 3062 -1678 1182 -4407 -781 -5939 7921 -1193 -3320 629 1815 6843 88 -2735 -3914 1761 -8223 -448 799 -3207 1976 5018 2176 2654 2833 -3903 -3816 917 4568 1461 1798 -1172 1828 -2157 -4628 -513 217 2322 1927 996 4493 1531 7477 -1618 -9895 2591 -7020 159 -1195 7415 -1415 -278 1307 858 -2752 -3108 742 SO 20171228T130053.0Z 6571.542280 6 1 32.00 2 89.28 123.90 129.09 359.59 0.00 1 0.00 1 0 15 2.995e-02 2.981e-02 3.095e-02 3.065e-02 -2.488216e+03 1.654918e+03 2.215041e+02 -6.000000e+00 1.568363e+03 273.08 -2.00 20.00 -2.00 505.17 0.00e+00 3.383797e-03 8.096858e-04 1.764156e-04 -6.000000e+00 8.114934e-04 273.08 -2.00 20.00 -2.00 500.09 0.00e+00 3.203573e+00 6.102302e-01 3.117655e-02 -6.000000e+00 5.890044e-01 222.70 -2.00 3.57 -2.00 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