File name: Pandora109s1_StGeorge_20180202_L2Fit_fwvt1c5d20161108p1-8.txt File generation date: 20251001T100931.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 109 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora109_of_v1d20160108.txt Instrument calibration file used: Pandora109s1_CF_v5d20161108.txt Level 1 file used: Pandora109s1_StGeorge_20180202_L1_smca1c5d20161108p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20180202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0824 492.2024 492.3223 492.4423 492.5622 492.6822 492.8021 492.9219 493.0418 493.1617 493.2815 493.4013 493.5211 493.6409 493.7607 493.8804 494.0002 494.1199 494.2396 494.3593 494.4789 494.5986 494.7182 494.8378 494.9574 495.0770 495.1966 495.3161 495.4356 495.5551 495.6746 495.7941 495.9136 496.0330 496.1524 496.2718 496.3912 496.5106 496.6300 496.7493 496.8686 496.9879 497.1072 497.2265 497.3457 497.4650 497.5842 497.7034 497.8226 497.9418 498.0609 498.1800 498.2992 498.4183 498.5373 498.6564 498.7754 498.8945 499.0135 499.1325 499.2515 499.3704 499.4894 499.6083 499.7272 499.8461 499.9650 500.0838 500.2027 500.3215 500.4403 500.5591 500.6779 500.7966 500.9153 501.0341 501.1528 501.2715 501.3901 501.5088 501.6274 501.7460 501.8646 501.9832 502.1018 502.2203 502.3388 502.4573 502.5758 502.6943 502.8128 502.9312 503.0496 503.1681 503.2864 503.4048 503.5232 503.6415 503.7598 503.8781 503.9964 504.1147 504.2329 504.3512 504.4694 504.5876 504.7058 504.8239 504.9421 505.0602 505.1783 505.2964 505.4145 505.5326 505.6506 505.7686 505.8866 506.0046 506.1226 506.2406 506.3585 506.4764 506.5943 506.7122 506.8301 506.9479 507.0658 507.1836 507.3014 507.4192 507.5369 507.6547 507.7724 507.8901 508.0078 508.1255 508.2431 508.3608 508.4784 508.5960 508.7136 508.8312 508.9487 509.0663 509.1838 509.3013 509.4188 509.5362 509.6537 509.7711 509.8885 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180202T123847.0Z 6607.526933 2 1 32.00 2 89.87 113.59 77.08 270.23 0.00 1 0.00 1 0 15 4.271e-02 4.178e-02 4.034e-02 3.978e-02 4.525588e+03 2.448892e+03 2.184040e+02 -6.000000e+00 2.227419e+03 271.93 -2.00 20.00 -2.00 505.19 0.00e+00 1.754806e-03 1.045507e-03 1.235360e-04 -6.000000e+00 1.153395e-03 271.93 -2.00 20.00 -2.00 500.00 0.00e+00 1.883596e+00 7.965544e-01 6.082728e-02 -6.000000e+00 8.401741e-01 224.13 -2.00 3.57 -2.00 501.65 0.00e+00 20.561 0.169 489.00 513.00 1 8.7216e+00 6.0664e-02 3.7589e-02 -6.0000e+00 6.4079e-02 1.2381e-01 1.5913e-02 2.3265e-03 -6.0000e+00 1.6840e-02 1.5399e-05 1.4250e-03 3.5974e-03 4.6947e-05 -6.0000e+00 4.0330e-03 -5.0100e-02 4.0229e-04 12 8 8 10 0 0 -939.91 16.06 7.79 -0.05010 -0.04022 8 2 1 4 0 4000.000 21.69 14.99 16.06 -6801 2464 -856 5679 -3168 5433 6421 8168 -1298 -5322 1508 -3151 249 -5660 -1812 788 -1309 3444 -1805 -1215 -4144 3208 -1252 4378 -3265 2026 4095 -2753 -3733 -337 -575 -6160 975 -2288 -926 4353 4537 9915 2898 -164 1730 1964 1383 -1036 -3102 -3971 4317 -4867 7742 -608 171 2595 1045 -3778 -2852 3364 325 5174 -1037 -549 2606 -2928 -3363 -6995 10247 -5542 6685 1717 -2627 6341 -5080 3695 -9386 183 -3079 5771 5010 -6054 -1559 -4049 3795 826 2166 -658 -3640 1554 864 3850 -905 1904 2414 4218 -4638 7614 1701 -2680 -4211 -3849 7556 -4601 5228 13 -336 2620 -2765 -1375 -4846 -2686 -5776 6466 -406 -2404 3049 2570 3242 -736 3496 -1480 2582 -1104 5103 6290 -3618 1485 -7703 8461 -2960 993 -4004 4163 -2231 6131 -1017 -552 5982 -4201 -579 4800 -7252 -3005 -4843 8989 2394 1751 -7182 480 -3695 1599 3879 -4807 10784 -7093 2401 -896 5756 -3592 5772 6863 8624 -1497 -6294 1641 -3542 266 -6343 -1948 832 -1437 3704 -2093 -1414 -4968 3575 -1460 4850 -3924 2310 4550 -3229 -3963 -362 -564 -6428 971 -2443 -1002 4491 4626 9455 2929 -170 1758 2009 1440 -1118 -3451 -4466 4440 -5415 7452 -620 168 2420 978 -3739 -2874 3288 335 5136 -1094 -574 2642 -3152 -3651 -7867 9618 -6000 6295 1673 -2639 5743 -5103 3402 -9935 179 -3130 5348 4597 -6082 -1477 -3910 3391 765 1994 -627 -3613 1477 829 3579 -880 1799 2280 3959 -4826 7056 1658 -2676 -4167 -3693 6299 -4235 4312 12 -303 2389 -2753 -1369 -4970 -2658 -5820 5758 -392 -2408 2935 2513 3170 -753 3449 -1545 2586 -1136 4851 5810 -3385 1319 -7550 7092 -2786 899 -3802 3640 -2075 5190 -909 -484 4881 -3813 -516 4143 -7189 -2895 -4801 7810 2234 1653 -7439 460 -3653 1470 3403 -4525 8679 SO 20180202T124048.0Z 6607.528333 4 1 32.00 2 89.54 113.94 77.44 270.56 0.00 1 0.00 1 0 15 3.842e-02 3.702e-02 3.230e-02 3.194e-02 2.550396e+03 1.862936e+03 2.379153e+02 -6.000000e+00 2.003452e+03 271.93 -2.00 20.00 -2.00 505.16 0.00e+00 1.738225e-03 8.443094e-04 1.004516e-04 -6.000000e+00 1.038460e-03 271.93 -2.00 20.00 -2.00 500.04 0.00e+00 1.436539e+00 6.386253e-01 1.984409e-02 -6.000000e+00 7.586577e-01 224.13 -2.00 3.57 -2.00 501.68 0.00e+00 20.038 0.156 489.00 513.00 1 8.6048e+00 4.8735e-02 3.5622e-02 -6.0000e+00 5.7816e-02 1.2424e-01 1.2790e-02 1.9896e-03 -6.0000e+00 1.5276e-02 1.9328e-05 3.5019e-03 2.9297e-03 4.7723e-05 -6.0000e+00 3.6300e-03 3.5997e-03 -2.4173e-04 12 9 8 11 8 0 49.94 16.06 1.57 0.00360 0.02789 8 2 1 4 0 4000.000 21.69 15.00 16.06 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1790 -1612 1285 -5617 3505 -1318 3167 -4066 518 -1783 -871 3705 -2580 1246 -4848 4445 -2134 6135 4711 -1784 4526 -2050 1301 -3036 1161 -3635 5905 3353 -3766 1269 -5998 2386 293 -4376 -871 -2392 5439 -1378 -634 -3300 6002 -1748 2902 -3617 -1992 4152 -3537 9226 -2613 -1116 -875 -4126 4582 -2955 147 -3509 5112 -4527 6696 -1093 792 323 -7000 6672 -6347 4793 -630 5178 -6100 9218 -1833 1019 3563 -5162 2086 -1557 4263 -2829 -3686 6695 -6007 4191 -5687 2852 -3726 -450 -2640 -4079 507 -1225 2427 352 6331 -263 7922 1330 -696 4420 -1564 6465 -5004 1249 966 2265 346 -1451 -43 -4908 -1610 -5618 4608 154 SO 20180202T124245.0Z 6607.529688 6 1 32.01 2 89.22 114.27 77.78 270.88 0.00 1 0.00 1 0 22 3.295e-02 3.227e-02 2.782e-02 2.754e-02 2.981029e+03 1.629007e+03 1.573787e+02 -6.000000e+00 1.718341e+03 271.93 -2.00 20.00 -2.00 505.19 0.00e+00 1.748803e-03 7.270720e-04 9.121892e-05 -6.000000e+00 8.900368e-04 271.93 -2.00 20.00 -2.00 500.08 0.00e+00 2.255636e+00 5.483101e-01 4.235706e-02 -6.000000e+00 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