File name: Pandora170s1_StGeorge_20231208_L2Fit_fout2c11d20231109p1-8.txt File generation date: 20250822T100942.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt Level 1 file used: Pandora170s1_StGeorge_20231208_L1_smca1c11d20231109p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20231208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0510 305.1920 305.3331 305.4742 305.6152 305.7562 305.8973 306.0383 306.1793 306.3203 306.4612 306.6022 306.7431 306.8841 307.0250 307.1659 307.3068 307.4477 307.5886 307.7295 307.8704 308.0112 308.1520 308.2929 308.4337 308.5745 308.7153 308.8561 308.9968 309.1376 309.2783 309.4191 309.5598 309.7005 309.8412 309.9819 310.1226 310.2633 310.4039 310.5446 310.6852 310.8258 310.9664 311.1070 311.2476 311.3882 311.5287 311.6693 311.8098 311.9504 312.0909 312.2314 312.3719 312.5124 312.6528 312.7933 312.9338 313.0742 313.2146 313.3550 313.4954 313.6358 313.7762 313.9166 314.0569 314.1973 314.3376 314.4780 314.6183 314.7586 314.8989 315.0391 315.1794 315.3197 315.4599 315.6001 315.7404 315.8806 316.0208 316.1610 316.3011 316.4413 316.5814 316.7216 316.8617 317.0018 317.1419 317.2820 317.4221 317.5622 317.7023 317.8423 317.9823 318.1224 318.2624 318.4024 318.5424 318.6824 318.8223 318.9623 319.1022 319.2422 319.3821 319.5220 319.6619 319.8018 319.9417 320.0815 320.2214 320.3612 320.5011 320.6409 320.7807 320.9205 321.0603 321.2000 321.3398 321.4795 321.6193 321.7590 321.8987 322.0384 322.1781 322.3178 322.4575 322.5971 322.7368 322.8764 323.0160 323.1557 323.2953 323.4348 323.5744 323.7140 323.8535 323.9931 324.1326 324.2721 324.4116 324.5511 324.6906 324.8301 324.9696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231208T155221.1Z 8742.661355 282 1 50.01 2 68.71 160.93 61.95 218.66 0.00 1 0.00 1 0 17 1.591e-02 8.665e-03 1.887e-03 4.808e-04 3.117542e-01 2.373898e-04 3.773778e-03 -6.000000e+00 8.915192e-03 222.30 -2.00 3.57 -2.00 317.65 0.00e+00 1.001433e-03 3.755303e-05 2.157484e-04 -6.000000e+00 3.898957e-04 274.69 -2.00 20.00 -2.00 317.06 0.00e+00 2.729 0.000 302.00 328.00 3 1.9765e+00 6.2335e-04 3.0835e-02 -6.0000e+00 2.1937e-02 2.8024e-02 7.0531e-04 1.5816e-02 -6.0000e+00 2.3962e-02 -7.5401e-03 4.4134e-04 7.9228e-03 -6.0000e+00 1.4268e-02 -4.1088e-03 2.2475e-04 2.4054e-03 -6.0000e+00 6.0497e-03 3.5610e-03 -1.1962e-04 1.3769e-05 2.5298e-05 -6.0000e+00 4.3237e-04 -8.3287e-03 0.0000e+00 11 8 0 10 0 0 100.00 23.23 0.21 -0.00833 -0.00923 516 103 1 5 0 96.800 27.15 20.00 23.23 11.03 6.8 995.38 2215 -780 441 -2607 -5862 -3498 -3349 434 -1419 -2739 -5935 -5382 -1763 -1084 1126 822 327 657 1139 2143 1309 167 1450 1036 658 1618 -375 -2108 -2060 -1287 378 650 2777 -1012 -4670 -4353 -4361 -2575 -117 -391 -759 -483 -264 -650 89 608 -19 40 -1154 -534 902 954 1111 1413 774 1243 1123 322 -46 -220 314 1478 2185 2956 720 -544 -962 -1986 752 1476 715 1231 671 1259 464 -519 -1106 -2586 -1170 -1327 -1339 -1223 -2596 -1993 -902 -475 389 800 1214 827 774 209 -1099 -487 -235 -327 378 1259 719 13 -307 -1946 -1245 114 -833 -1547 -708 -1125 -191 688 934 610 499 153 -309 -233 -39 -96 690 279 68 497 803 334 938 64 -672 938 260 171 142 -721 -591 -81 90 -219 128 684 153 -8 182 -852 -685 169 -69 40 -232 -486 -267 -266 38 -140 -291 -654 -609 -217 -156 185 152 65 136 227 440 277 36 310 235 160 407 -96 -524 -484 -321 91 174 797 -313 -1428 -1287 -1386 -943 -47 -184 -369 -248 -139 -350 48 325 -10 21 -605 -282 497 568 706 885 506 830 766 220 -31 -147 215 1079 1634 2355 593 -425 -746 -1523 566 1250 632 1131 619 1110 406 -413 -852 -1938 -912 -1106 -1195 -1208 -2643 -2121 -1015 -541 465 982 1482 977 850 221 -1149 -496 -242 -374 456 1592 973 17 -389 -2396 -1443 135 -1022 -2026 -964 -1538 -274 1006 1447 964 764 220 -430 -319 -54 -132 1004 414 103 736 1202 483 1287 89 -892 1242 373 255 213 -1125 -944 -129 152 -374 224 1212 274 -15 317 -1435 -1132 SS 20231208T160210.6Z 8742.668179 285 1 1.86 2 68.17 163.29 63.09 221.00 0.00 1 0.00 1 0 17 2.350e-02 9.424e-03 2.384e-02 5.015e-03 3.070037e-01 2.464881e-03 3.711726e-03 -6.000000e+00 1.316776e-02 222.30 -2.00 3.57 -2.00 318.07 0.00e+00 1.164841e-03 4.351313e-04 1.686705e-04 -6.000000e+00 5.758274e-04 274.69 -2.00 20.00 -2.00 317.47 0.00e+00 2.666 0.000 302.00 328.00 3 3.0974e+00 6.5378e-03 3.0210e-02 -6.0000e+00 3.2402e-02 3.2998e-02 7.4264e-03 1.5647e-02 -6.0000e+00 3.5391e-02 8.9281e-03 4.8266e-03 7.8475e-03 -6.0000e+00 2.1073e-02 -1.3704e-02 2.5011e-03 2.4556e-03 -6.0000e+00 8.9361e-03 1.2298e-03 -1.5951e-04 1.4524e-04 2.5849e-05 -6.0000e+00 6.3855e-04 -8.9774e-03 0.0000e+00 12 9 9 12 1 1 100.00 23.23 0.31 -0.00898 -0.01018 15 87 1 5 0 115.400 27.15 20.00 23.23 11.22 6.7 994.84 8877 -7755 5027 2032 -5942 -497 -3460 -4131 -2072 -3395 -5998 1544 9731 1953 9783 -308 82 204 -32 5271 1081 4342 -38 2579 728 386 -1373 -936 -1810 -3015 1820 2084 1697 -3867 -3211 -5497 -3343 -1913 982 406 44 -2760 -2079 -1110 -806 634 -1780 1047 -897 -1721 867 206 1477 1093 -124 1245 578 196 1295 -266 -489 1134 1535 2383 280 -280 -1101 -2777 -405 2639 474 2114 812 1568 576 90 149 -1292 -771 -1773 -169 -697 -2556 -1992 -1048 -685 362 1093 1021 1155 882 370 -1603 -772 -1045 47 611 1513 470 -177 84 -1672 -1394 -237 -990 -1326 -617 -1530 299 660 985 1657 36 445 -182 -1016 -317 -589 705 165 -16 359 365 203 628 -127 -837 900 725 27 -134 -839 -656 108 19 -480 524 1295 -150 -22 103 -533 -605 527 -595 357 143 -412 -31 -232 -312 -171 -299 -546 136 890 222 1198 -46 13 34 -6 903 197 769 -7 496 151 84 -303 -198 -368 -613 376 471 420 -1039 -825 -1404 -896 -583 344 164 19 -1307 -1007 -541 -393 307 -873 496 -429 -838 434 111 829 644 -76 772 367 124 803 -166 -314 764 1109 1810 218 -209 -780 -1964 -297 2086 409 1864 722 1350 474 68 105 -892 -553 -1413 -146 -656 -2569 -2073 -1135 -780 426 1309 1224 1348 981 387 -1602 -755 -1073 52 727 1923 630 -236 107 -2026 -1625 -281 -1242 -1739 -832 -2146 431 996 1544 2617 57 663 -258 -1393 -432 -831 1032 253 -24 551 550 298 891 -176 -1125 1207 1024 40 -209 -1338 -1062 179 33 -859 949 2361 -277 -40 183 -923 -1038 SS 20231208T160737.4Z 8742.671960 289 1 4.57 2 67.90 164.61 63.75 222.28 0.00 1 0.00 1 0 17 1.807e-02 9.534e-03 6.315e-03 1.900e-03 3.015586e-01 9.386283e-04 3.658509e-03 -6.000000e+00 1.012182e-02 222.30 -2.00 3.57 -2.00 317.31 0.00e+00 1.184740e-03 1.355608e-04 1.546750e-04 -6.000000e+00 4.426682e-04 274.69 -2.00 20.00 -2.00 316.72 0.00e+00 2.635 0.000 302.00 328.00 3 2.4427e+00 2.4502e-03 2.9774e-02 -6.0000e+00 2.4906e-02 3.3173e-02 2.7639e-03 1.5286e-02 -6.0000e+00 2.7205e-02 -1.0099e-02 1.6890e-03 7.6386e-03 -6.0000e+00 1.6199e-02 -2.4893e-03 8.4624e-04 2.3593e-03 -6.0000e+00 6.8684e-03 2.4712e-03 -1.7770e-04 5.4266e-05 2.4846e-05 -6.0000e+00 4.9090e-04 -8.2555e-03 0.0000e+00 12 9 9 12 1 1 99.93 23.22 0.23 -0.00826 -0.00959 21 48 1 5 0 207.070 27.15 19.99 23.22 11.33 6.8 994.95 1937 -1840 1191 -2053 -5846 -1248 -5240 5836 -226 -4555 -8353 -2600 -3218 -820 1686 -360 1798 220 2804 734 2787 -930 1669 1194 1142 1781 -22 -2242 -1798 -1121 -351 968 1848 -1064 -5084 -3898 -4372 -2788 3 -1003 -901 -745 -177 -666 699 629 251 -503 -1044 -286 722 1321 1010 1673 950 1428 1514 698 162 -431 463 1404 2303 3098 1120 -827 -1309 -2105 777 1620 762 1478 494 1273 135 -694 -1344 -2552 -1656 -1749 -1245 -1291 -2647 -2363 -851 -559 622 775 1283 1023 855 125 -1212 -351 -158 -270 178 1227 495 1 -332 -1589 -1441 -51 -724 -1670 -651 -1448 -106 774 1023 497 587 136 -368 -147 -8 -265 601 382 183 546 811 447 811 107 -818 1330 433 172 287 -575 -510 -172 19 -136 38 778 152 -9 -109 -693 -958 182 -201 131 -222 -590 -113 -515 578 -27 -592 -1131 -342 -481 -140 327 -74 383 50 647 180 684 -236 418 316 323 521 -7 -649 -489 -299 -99 297 615 -378 -1791 -1315 -1591 -1086 1 -504 -499 -408 -100 -381 396 358 141 -281 -579 -159 421 826 676 1103 653 1001 1081 501 115 -304 333 1078 1812 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