File name: Pandora170s1_StGeorge_20240413_L2Fit_fout2c11d20231109p1-8.txt File generation date: 20250822T105534.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v9d20200302.txt Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt Level 1 file used: Pandora170s1_StGeorge_20240413_L1_smca1c11d20231109p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20240413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0510 305.1920 305.3331 305.4742 305.6152 305.7562 305.8973 306.0383 306.1793 306.3203 306.4612 306.6022 306.7431 306.8841 307.0250 307.1659 307.3068 307.4477 307.5886 307.7295 307.8704 308.0112 308.1520 308.2929 308.4337 308.5745 308.7153 308.8561 308.9968 309.1376 309.2783 309.4191 309.5598 309.7005 309.8412 309.9819 310.1226 310.2633 310.4039 310.5446 310.6852 310.8258 310.9664 311.1070 311.2476 311.3882 311.5287 311.6693 311.8098 311.9504 312.0909 312.2314 312.3719 312.5124 312.6528 312.7933 312.9338 313.0742 313.2146 313.3550 313.4954 313.6358 313.7762 313.9166 314.0569 314.1973 314.3376 314.4780 314.6183 314.7586 314.8989 315.0391 315.1794 315.3197 315.4599 315.6001 315.7404 315.8806 316.0208 316.1610 316.3011 316.4413 316.5814 316.7216 316.8617 317.0018 317.1419 317.2820 317.4221 317.5622 317.7023 317.8423 317.9823 318.1224 318.2624 318.4024 318.5424 318.6824 318.8223 318.9623 319.1022 319.2422 319.3821 319.5220 319.6619 319.8018 319.9417 320.0815 320.2214 320.3612 320.5011 320.6409 320.7807 320.9205 321.0603 321.2000 321.3398 321.4795 321.6193 321.7590 321.8987 322.0384 322.1781 322.3178 322.4575 322.5971 322.7368 322.8764 323.0160 323.1557 323.2953 323.4348 323.5744 323.7140 323.8535 323.9931 324.1326 324.2721 324.4116 324.5511 324.6906 324.8301 324.9696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240413T165043.0Z 8869.701887 251 1 3.89 2 34.77 168.15 60.36 78.19 0.00 1 0.00 1 0 17 1.748e-02 1.058e-02 9.001e-03 4.654e-03 2.387948e-01 2.365920e-03 2.895190e-03 -6.000000e+00 1.000877e-02 228.10 -2.00 3.57 -2.00 315.95 0.00e+00 4.488619e-04 2.446307e-04 5.304053e-05 -6.000000e+00 4.332991e-04 277.43 -2.00 20.00 -2.00 315.36 0.00e+00 1.217 0.000 302.00 328.00 3 5.0771e+00 6.1313e-03 1.7327e-02 -6.0000e+00 2.4931e-02 3.7574e-02 6.8535e-03 1.2273e-02 -6.0000e+00 2.7110e-02 1.7317e-03 3.9453e-03 6.0484e-03 -6.0000e+00 1.6097e-02 -5.4457e-03 1.8056e-03 1.7083e-03 -6.0000e+00 6.7559e-03 7.2551e-04 1.1136e-04 1.3176e-04 2.0316e-05 -6.0000e+00 4.7583e-04 -5.4933e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.75 0.48 -0.00549 -0.00466 2 8 1 5 0 1292.440 26.62 20.00 22.75 13.83 10.0 988.48 4502 -5105 2035 -4196 -7216 897 1295 3773 -1882 525 -3815 -1430 -3456 2095 -384 1606 708 47 654 1048 2932 703 2491 -181 2673 2197 1437 -3170 -2732 271 -84 2416 2913 -152 -5932 -3545 -4035 -2167 152 -214 -483 -970 -971 -1028 -536 -846 10 320 -1063 -1564 1487 1476 2066 1271 693 2995 492 732 39 -95 1174 772 1541 2089 479 -873 -1002 -1537 747 1096 1270 1043 198 1563 427 -339 -507 -2445 -691 -969 -1306 -1404 -3230 -1906 -1654 -910 235 310 384 993 681 572 -383 -401 -232 268 1100 987 662 347 -13 -1771 -1336 -20 -559 -1863 -673 -1184 176 331 1172 393 896 -115 -435 228 -421 -605 33 493 -35 848 709 1124 364 -39 -32 1312 911 -192 757 -1364 -249 342 485 -617 -207 409 39 452 -331 -914 -738 866 -1157 443 -920 -1478 163 243 766 -440 125 -940 -350 -933 605 -126 555 255 17 249 409 1146 279 982 -76 1142 969 634 -1388 -1134 107 -35 1036 1319 -72 -2799 -1606 -1937 -1148 90 -140 -337 -701 -713 -761 -395 -624 7 227 -749 -1106 1063 1103 1597 1017 567 2447 413 612 32 -78 981 676 1413 1978 457 -801 -872 -1320 657 1039 1268 1070 204 1563 412 -308 -433 -2042 -586 -884 -1283 -1459 -3522 -2122 -1911 -1092 289 388 480 1210 796 632 -403 -415 -248 301 1309 1242 862 449 -17 -2121 -1556 -24 -692 -2404 -885 -1598 242 471 1707 577 1282 -159 -572 289 -534 -789 44 690 -49 1191 979 1514 479 -50 -39 1625 1173 -259 1040 -1920 -352 493 721 -948 -321 641 61 701 -505 -1369 -1095 SS 20240413T170723.6Z 8869.713467 263 1 2.37 2 34.33 175.37 57.48 80.62 0.00 1 0.00 1 0 17 1.287e-02 8.708e-03 2.078e-03 1.184e-03 2.376534e-01 6.045383e-04 2.894597e-03 -6.000000e+00 7.367743e-03 228.10 -2.00 3.57 -2.00 315.65 0.00e+00 5.571628e-04 5.829289e-05 6.275875e-05 -6.000000e+00 3.189097e-04 277.43 -2.00 20.00 -2.00 315.07 0.00e+00 1.210 0.000 302.00 328.00 3 2.3003e+00 1.5614e-03 1.7246e-02 -6.0000e+00 1.8353e-02 3.3632e-02 1.7430e-03 1.2222e-02 -6.0000e+00 1.9956e-02 -3.2871e-03 9.9984e-04 6.0246e-03 -6.0000e+00 1.1849e-02 -3.0248e-03 4.5043e-04 1.7079e-03 -6.0000e+00 4.9740e-03 1.1790e-02 2.6284e-05 3.3416e-05 2.0464e-05 -6.0000e+00 3.5020e-04 -6.7066e-03 0.0000e+00 12 9 1 12 1 1 99.92 22.75 0.23 -0.00671 -0.00651 29 127 1 5 0 78.650 26.62 20.00 22.75 14.30 10.0 988.75 1609 1225 139 -1942 -4061 -3150 -2042 1277 938 -2062 -3398 -3708 -881 -448 1089 237 48 1163 601 1766 920 297 1110 1775 954 2213 625 -693 -1040 -826 1059 893 3306 -786 -4219 -3738 -3545 -2108 -250 -268 -1121 -492 -611 -426 187 520 -317 -59 -896 -404 910 560 865 1106 685 1302 1293 375 281 115 229 1482 1787 2640 512 -606 -874 -1793 545 1224 240 761 584 927 324 -562 -855 -1973 -618 -923 -1155 -1118 -2556 -1918 -1012 -613 3 443 768 523 621 165 -825 -188 102 -335 421 987 674 -117 -299 -1599 -759 179 -852 -1322 -707 -1050 -210 502 740 559 532 358 -134 -21 148 -127 677 303 188 353 832 400 1013 210 -326 1151 410 259 64 -689 -550 24 145 -198 42 486 116 -180 50 -969 -723 361 303 36 -478 -910 -708 -471 295 242 -575 -951 -1052 -267 -144 391 94 19 459 247 741 397 128 478 794 455 1080 307 -326 -457 -351 460 420 1635 -389 -2040 -1853 -1762 -1206 -159 -186 -813 -371 -450 -316 144 398 -240 -43 -645 -289 670 443 685 914 584 1072 1081 315 243 99 193 1315 1635 2536 501 -554 -768 -1538 486 1165 241 793 608 928 318 -523 -754 -1662 -534 -853 -1146 -1165 -2757 -2155 -1154 -716 4 558 962 632 722 182 -873 -191 109 -379 503 1240 864 -149 -369 -1907 -891 207 -1035 -1709 -913 -1417 -285 718 1068 813 743 480 -177 -26 183 -165 901 415 265 489 1153 533 1323 262 -403 1412 519 352 87 -969 -758 35 211 -303 64 747 179 -273 76 -1419 -1075 SS 20240413T173324.2Z 8869.731530 276 1 10.39 2 34.41 186.75 52.95 84.51 0.00 1 0.00 1 0 17 1.267e-02 8.688e-03 1.033e-03 5.438e-04 2.377111e-01 2.765544e-04 2.896137e-03 -6.000000e+00 7.253042e-03 228.11 -2.00 3.57 -2.00 315.92 0.00e+00 4.689202e-04 2.837201e-05 7.171956e-05 -6.000000e+00 3.139226e-04 277.43 -2.00 20.00 -2.00 315.33 0.00e+00 1.211 0.000 302.00 328.00 3 2.1947e+00 7.1659e-04 1.7269e-02 -6.0000e+00 1.8067e-02 3.2949e-02 8.0089e-04 1.2240e-02 -6.0000e+00 1.9644e-02 -2.6149e-03 4.6012e-04 6.0348e-03 -6.0000e+00 1.1664e-02 -3.4144e-03 2.1025e-04 1.7028e-03 -6.0000e+00 4.8969e-03 1.3093e-02 5.2719e-05 1.5345e-05 2.0108e-05 -6.0000e+00 3.4472e-04 -7.2886e-03 0.0000e+00 12 9 1 12 1 1 99.99 22.75 0.21 -0.00729 -0.00689 239 232 1 5 0 43.230 26.62 20.00 22.75 14.81 10.0 988.55 1970 720 691 -2563 -3930 -2815 -1340 1088 838 -1120 -3814 -3151 -909 -503 1161 361 -225 1108 637 1990 930 -24 1059 1378 1257 1518 228 -938 -720 -684 948 1030 2913 -794 -4215 -3746 -3635 -2085 -366 -378 -952 -445 -268 -589 206 521 -432 -225 -1028 -446 943 798 1104 1275 732 1264 1211 386 17 6 434 1508 1869 2540 446 -679 -963 -1650 788 1051 429 881 471 1093 531 -263 -914 -1973 -607 -991 -1252 -1215 -2780 -1952 -1117 -647 68 386 952 670 610 197 -749 37 82 -205 389 1113 619 -147 -350 -1569 -942 128 -955 -1443 -769 -1079 -218 631 725 514 540 181 -106 40 214 -77 691 201 14 283 737 432 962 219 -365 1131 534 405 185 -560 -335 -30 48 -281 -25 460 148 -103 -60 -940 -665 392 159 156 -565 -783 -562 -273 224 193 -276 -956 -793 -246 -155 372 127 -84 418 250 795 383 -10 436 592 534 666 101 -423 -302 -277 394 462 1290 -374 -1938 -1775 -1719 -1134 -220 -248 -687 -316 -195 -433 150 376 -308 -164 -738 -318 692 592 865 1043 587 1027 999 320 14 5 359 1319 1676 2397 428 -610 -835 -1393 691 984 420 896 481 1122 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