File name: Pandora170s1_StGeorge_20240711_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20250730T220355.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v10d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20240711_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20240711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240711T123828.7Z 8958.526721 138 1 48.74 2 61.66 85.80 117.99 53.33 0.00 1 0.00 1 0 17 2.595e-02 1.055e-02 7.002e-03 2.136e-03 2.884316e-01 1.096610e-03 3.418401e-03 -6.000000e+00 1.512519e-02 233.03 -2.00 3.57 -2.00 317.44 0.00e+00 1.188592e-03 1.646213e-04 2.378069e-04 -6.000000e+00 6.743235e-04 286.66 -2.00 20.00 -2.00 316.62 0.00e+00 2.096 0.000 302.00 328.00 3 4.6735e+00 2.9311e-03 2.5764e-02 -6.0000e+00 3.8013e-02 9.2015e-03 3.2958e-03 1.5270e-02 -6.0000e+00 4.1123e-02 -9.9994e-03 1.9808e-03 7.3808e-03 -6.0000e+00 2.4465e-02 1.2041e-03 9.7331e-04 2.1407e-03 -6.0000e+00 1.0298e-02 4.4153e-04 4.9289e-04 6.1495e-05 2.1656e-05 -6.0000e+00 7.0782e-04 8.2043e-03 0.0000e+00 12 9 8 11 32 0 99.81 23.08 0.27 0.00820 0.01191 16 3 1 5 0 3045.590 27.05 20.00 23.08 26.25 11.3 1063.79 445 900000 -3405 -4221 -11412 -11981 -3667 -1349 -5389 3010 -7323 -13029 -856 617 -483 2912 1060 -139 -1281 1280 1303 2088 3866 1611 1532 4840 2433 -5144 -3346 353 -1843 -868 588 342 -5621 -3861 -4823 -1374 2359 -2098 -1318 35 -633 709 -344 895 1088 1184 -2206 613 772 1698 734 2072 -291 2608 1303 1057 232 -1322 619 1599 1811 3307 1405 -86 -1283 -2722 555 466 740 1724 997 1027 938 -1431 -1086 -3203 -1484 -2291 -814 -1715 -2425 -2240 -724 -427 190 771 1166 942 341 -269 -1007 -1171 -503 -395 365 1045 1139 -81 -490 -2064 -956 -89 -1278 -1431 -99 -1192 -100 1025 1024 353 228 -53 -162 311 -608 -106 777 620 409 363 577 1026 994 -394 -534 1582 852 180 238 -757 -617 -72 45 -401 385 762 175 156 -318 -1057 -1001 42 900000 -375 -447 -1174 -1180 -351 -142 -651 353 -945 -1826 -120 98 -89 570 222 -31 -297 301 313 497 920 411 412 1311 669 -1446 -882 89 -502 -255 184 110 -1816 -1204 -1628 -516 1001 -1041 -699 19 -356 399 -196 506 607 651 -1232 338 445 1029 470 1365 -200 1787 914 741 162 -929 440 1194 1438 2720 1170 -69 -983 -2083 438 402 678 1613 936 939 817 -1176 -831 -2418 -1154 -1954 -749 -1697 -2518 -2405 -805 -496 227 940 1417 1119 388 -288 -1028 -1182 -528 -444 438 1333 1506 -107 -621 -2497 -1118 -106 -1615 -1877 -132 -1654 -143 1515 1563 544 344 -76 -224 413 -814 -146 1111 920 615 541 843 1459 1372 -532 -702 2071 1172 260 355 -1154 -953 -113 75 -678 660 1315 303 267 -534 -1737 -1634 SS 20240711T124335.5Z 8958.530272 141 1 49.97 2 60.73 86.65 117.29 54.47 0.00 1 0.00 1 0 17 2.300e-02 1.056e-02 7.163e-03 2.108e-03 2.824163e-01 1.078726e-03 3.349566e-03 -6.000000e+00 1.340065e-02 233.03 -2.00 3.57 -2.00 317.40 0.00e+00 9.596153e-04 1.601912e-04 1.733102e-04 -6.000000e+00 5.924052e-04 286.66 -2.00 20.00 -2.00 316.58 0.00e+00 2.036 0.000 302.00 328.00 3 4.7150e+00 2.8843e-03 2.5119e-02 -6.0000e+00 3.3678e-02 4.4179e-03 3.2420e-03 1.4979e-02 -6.0000e+00 3.6436e-02 3.1134e-03 1.9408e-03 7.2257e-03 -6.0000e+00 2.1663e-02 -5.8383e-03 9.5079e-04 2.0510e-03 -6.0000e+00 9.0701e-03 4.5230e-04 3.4274e-04 6.0564e-05 2.1313e-05 -6.0000e+00 6.2695e-04 9.5551e-03 0.0000e+00 12 8 8 10 0 0 98.98 23.08 0.44 0.00956 0.01213 19 4 1 5 0 2629.260 27.05 20.00 23.08 26.65 11.3 1067.35 1188 -3699 -2371 5166 -7141 -9190 1781 7358 -2357 5740 -3680 -9422 4211 -1306 -884 1685 757 -2011 -1406 161 1796 3785 1700 3298 889 4186 924 -4254 -3226 -431 -979 -1260 2892 -469 -4947 -5032 -4452 -1911 1465 -2643 -1676 -552 -1182 738 -732 459 1465 694 -2730 -484 191 904 1250 1751 2002 2386 900 642 227 -1159 847 1643 1372 3070 1097 -205 -1584 -2155 -163 1200 702 1769 1414 737 1188 -610 -851 -3526 -1089 -1890 -855 -1935 -2004 -2439 -1287 -554 82 1569 1163 600 434 75 -1010 -400 -122 -74 626 1431 1133 -145 -80 -1954 -1290 -362 -1383 -1665 -246 -1257 -121 1174 803 622 56 -289 -347 -364 -139 -510 751 645 492 264 594 490 805 -240 -573 1756 840 209 68 -409 -710 -88 -126 -376 349 992 206 83 48 -1202 -903 111 -401 -261 507 -713 -892 164 723 -281 667 -467 -1299 572 -215 -165 337 161 -455 -330 39 434 899 418 840 244 1157 261 -1204 -862 -111 -267 -375 895 -153 -1604 -1600 -1514 -730 634 -1335 -904 -308 -677 421 -423 264 825 387 -1548 -272 112 557 806 1167 1367 1655 640 457 160 -823 607 1240 1104 2555 925 -166 -1225 -1654 -130 1038 649 1668 1334 681 1041 -502 -655 -2684 -849 -1617 -791 -1928 -2087 -2640 -1445 -649 99 1917 1423 719 496 81 -1035 -403 -128 -84 754 1827 1504 -192 -102 -2369 -1515 -434 -1756 -2196 -331 -1751 -174 1740 1231 961 85 -420 -480 -485 -185 -704 1076 958 741 394 869 701 1114 -324 -753 2296 1156 303 102 -622 -1097 -139 -206 -635 598 1711 358 142 80 -1980 -1475 SS 20240711T125652.2Z 8958.539493 150 1 37.98 2 58.33 88.89 115.41 57.36 0.00 1 0.00 1 0 17 9.209e-02 2.594e-02 6.895e-03 2.311e-03 2.604160e-01 1.180678e-03 3.115985e-03 -6.000000e+00 5.362428e-02 233.03 -2.00 3.57 -2.00 317.07 0.00e+00 4.525125e-03 1.609189e-04 8.420457e-05 -6.000000e+00 2.372137e-03 286.66 -2.00 20.00 -2.00 316.28 0.00e+00 1.898 0.000 302.00 328.00 3 4.7440e+00 3.1455e-03 2.3459e-02 -6.0000e+00 1.3476e-01 6.9268e-03 3.5262e-03 1.4826e-02 -6.0000e+00 1.4583e-01 -3.4646e-02 2.0539e-03 6.8804e-03 -6.0000e+00 8.6701e-02 2.2350e-02 9.7736e-04 3.7718e-03 -6.0000e+00 3.6276e-02 5.1544e-04 -1.1074e-04 6.6295e-05 3.2151e-05 -6.0000e+00 2.5110e-03 1.3715e-02 0.0000e+00 12 9 9 12 1 1 99.94 23.08 0.93 0.01372 0.01288 12 3 1 5 0 2920.820 27.05 20.00 23.08 27.90 11.3 1073.80 28086 -83074 21529 18398 15808 13837 21485 18135 9696 12508 5348 2551 10785 9936 10461 12047 8513 11516 9777 8590 9414 10591 9766 7098 4247 3981 1486 -2135 -939 3269 3303 5599 6050 3146 447 298 -2107 639 2312 -2944 -3625 -1527 -843 -694 -90 1834 2622 2557 -309 705 1758 2390 1331 1634 855 1566 -486 -1337 -1400 -2524 -352 1748 1198 2721 885 228 -1556 -2376 255 191 -271 848 376 207 -166 -1362 -1602 -3189 -1543 -2013 -1059 -1815 -3184 -3095 -1460 -1271 -280 878 1058 354 114 -653 -1096 -821 -781 -44 521 1232 1037 -47 -161 -1737 -883 106 -1223 -1295 40 -996 200 1363 1177 482 296 -95 -168 567 107 -86 1274 985 694 653 1131 1269 1362 53 -403 2092 1339 655 386 -570 -414 -351 -197 -1087 93 668 -168 -470 -115 -1241 -1595 2853 -24982 2629 2202 1749 1466 2179 2082 1308 1695 766 385 1695 1821 2181 2711 2074 2832 2536 2325 2572 2842 2645 2026 1287 1238 469 -667 -279 932 995 1792 2071 1123 156 102 -782 263 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