File name: Pandora170s1_StGeorge_20240804_L2Fit_fwvt1c11d20231109p1-8.txt
File generation date: 20250822T110904.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c11p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 170
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora170_OF_v10d20200302.txt
Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt
Level 1 file used: Pandora170s1_StGeorge_20240804_L1_smca1c11d20231109p1-8.txt
Full location name: University of Toronto - Downtown (St. George) campus
Short location name: StGeorge
Country of location: Canada
Location latitude [deg]: 43.6605
Location longitude [deg]: -79.3986
Location altitude [m]: 176
Local noon date: 20240804
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1633 1782
Nominal wavelengths inside fitting window [nm]: 492.0067 492.1280 492.2493 492.3705 492.4918 492.6130 492.7342 492.8554 492.9766 493.0978 493.2189 493.3400 493.4612 493.5823 493.7033 493.8244 493.9454 494.0665 494.1875 494.3085 494.4295 494.5504 494.6714 494.7923 494.9132 495.0341 495.1550 495.2759 495.3967 495.5175 495.6383 495.7591 495.8799 496.0007 496.1214 496.2422 496.3629 496.4836 496.6042 496.7249 496.8455 496.9662 497.0868 497.2074 497.3280 497.4485 497.5691 497.6896 497.8101 497.9306 498.0511 498.1715 498.2920 498.4124 498.5328 498.6532 498.7736 498.8939 499.0143 499.1346 499.2549 499.3752 499.4955 499.6157 499.7360 499.8562 499.9764 500.0966 500.2168 500.3369 500.4570 500.5772 500.6973 500.8174 500.9374 501.0575 501.1775 501.2975 501.4175 501.5375 501.6575 501.7774 501.8974 502.0173 502.1372 502.2571 502.3769 502.4968 502.6166 502.7364 502.8562 502.9760 503.0958 503.2155 503.3353 503.4550 503.5747 503.6943 503.8140 503.9337 504.0533 504.1729 504.2925 504.4121 504.5316 504.6512 504.7707 504.8902 505.0097 505.1292 505.2486 505.3680 505.4875 505.6069 505.7263 505.8456 505.9650 506.0843 506.2036 506.3229 506.4422 506.5615 506.6807 506.8000 506.9192 507.0384 507.1576 507.2767 507.3959 507.5150 507.6341 507.7532 507.8723 507.9913 508.1104 508.2294 508.3484 508.4674 508.5864 508.7053 508.8243 508.9432 509.0621 509.1810 509.2999 509.4187 509.5375 509.6564 509.7752 509.8939
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240804T103024.6Z 8982.437784 56 1 39.53 2 87.54 68.63 86.14 65.09 0.00 1 0.00 1 0 29 1.358e-02 1.333e-02 4.489e-04 4.472e-04 1.511289e+04 3.012915e+01 9.816013e+02 -6.000000e+00 7.308258e+02 287.38 -2.00 20.00 -2.00 505.41 0.00e+00 2.768878e-03 1.230644e-05 1.506201e-04 -6.000000e+00 3.787860e-04 287.38 -2.00 20.00 -2.00 501.00 0.00e+00 1.027349e+00 8.455122e-03 1.000014e-01 -6.000000e+00 2.647465e-01 232.28 -2.00 3.57 -2.00 502.51 0.00e+00 14.787 0.063 489.00 513.00 1 4.4115e+00 6.4553e-04 2.4377e-02 -6.0000e+00 2.0252e-02 -6.4874e-02 1.6573e-04 2.6919e-03 -6.0000e+00 5.3576e-03 2.6201e-03 1.7290e-03 3.4330e-05 1.2325e-04 -6.0000e+00 1.1444e-03 1.2658e-03 5.6615e-06 12 9 9 12 1 1 84.72 23.21 6.86 0.00127 0.01326 64 16 1 4 0 608.030 27.15 20.00 23.21 27.13 11.7 1064.18 -4309 -3728 -2280 -776 -67 815 1516 1747 1674 1008 387 -113 -784 -1418 -1722 -1737 -1386 -331 636 799 871 721 629 996 1145 1365 1416 1078 42 -1285 -2034 -2133 -1449 204 1377 1446 981 538 98 -96 -46 251 673 1235 1737 1951 1779 1317 960 -30 -1249 -2016 -2698 -2382 -1045 113 994 1288 1089 899 1087 1417 1603 1801 1424 746 276 -90 -546 -1111 -1471 -1432 -948 -269 13 -287 -1028 -1667 -1935 -2111 -1762 -1282 -1281 -974 -561 -340 -661 -612 -621 -309 65 888 1705 1817 1736 1358 748 -53 -1259 -2462 -2832 -2472 -1189 282 820 598 -167 -994 -1148 -749 -63 362 1064 1508 1732 2129 2627 2467 1668 881 222 -300 76 719 819 988 935 593 565 724 118 -495 -944 -1804 -1892 -1091 -405 -65 490 602 421 413 487 715 952 579 -475 -1684 -2591 -2554 -3779 -3297 -2060 -721 -61 757 1431 1672 1609 967 367 -106 -735 -1320 -1595 -1613 -1302 -316 622 764 834 693 606 963 1116 1337 1386 1054 41 -1214 -1965 -2066 -1366 197 1374 1463 990 539 97 -95 -46 251 681 1215 1727 1952 1781 1311 946 -29 -1243 -1967 -2611 -2311 -1034 111 994 1303 1105 911 1101 1445 1646 1852 1463 761 279 -90 -543 -1097 -1442 -1408 -939 -270 13 -291 -1030 -1646 -1893 -2058 -1715 -1253 -1264 -968 -564 -346 -676 -622 -628 -310 65 903 1689 1795 1737 1314 701 -50 -1192 -2320 -2665 -2368 -1134 282 825 614 -172 -1017 -1166 -766 -66 367 1080 1530 1758 2167 2712 2602 1781 936 232 -308 77 728 840 1018 970 617 588 756 123 -510 -964 -1852 -1953 -1142 -434 -69 520 650 462 456 524 771 1024 622 -525 -1841 -2811 -2774
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SQ 20240804T104623.5Z 8982.448883 64 1 27.34 2 84.83 71.32 83.61 67.67 0.00 1 0.00 1 0 22 6.152e-03 6.061e-03 1.341e-04 1.339e-04 1.205621e+04 8.857529e+00 8.094833e+02 -6.000000e+00 3.311490e+02 287.38 -2.00 20.00 -2.00 505.34 0.00e+00 1.610071e-03 3.676348e-06 9.734098e-05 -6.000000e+00 1.716361e-04 287.38 -2.00 20.00 -2.00 500.74 0.00e+00 9.131127e-01 2.562659e-03 7.450327e-02 -6.000000e+00 1.199661e-01 232.28 -2.00 3.57 -2.00 502.29 0.00e+00 9.559 0.017 489.00 513.00 1 2.4521e+00 1.9566e-04 1.5227e-02 -6.0000e+00 9.1770e-03 -4.4607e-02 5.0674e-05 1.9775e-03 -6.0000e+00 2.4279e-03 3.9696e-02 7.5150e-04 1.0476e-05 1.0105e-04 -6.0000e+00 5.1852e-04 4.0869e-03 -1.5726e-05 12 8 8 10 0 0 11.34 23.21 1.93 0.00409 0.00930 537 108 1 4 0 50.820 27.15 20.00 23.21 27.85 11.4 1066.96 -1712 -1498 -796 -198 85 499 797 921 831 553 343 90 -315 -507 -713 -748 -579 -96 283 261 320 324 183 401 542 622 692 638 -56 -592 -912 -1054 -800 231 554 566 424 192 -91 -215 -129 -69 195 458 692 720 680 525 376 -123 -644 -1056 -1379 -1226 -585 -49 322 471 352 377 413 602 673 764 624 341 148 -51 -279 -573 -674 -660 -491 1 174 -64 -334 -644 -842 -913 -758 -605 -641 -402 -210 -183 -238 -229 -271 -147 -1 503 864 880 930 753 453 38 -530 -1162 -1407 -1310 -775 84 172 195 -104 -561 -590 -351 -172 71 421 596 666 919 1199 1129 790 531 164 -178 46 318 250 369 396 149 292 524 13 -200 -335 -861 -875 -393 -234 -34 287 270 173 267 322 406 498 326 -137 -749 -1129 -1128 -1568 -1385 -755 -189 82 486 792 929 819 557 341 89 -306 -487 -681 -715 -560 -94 279 263 324 327 185 407 555 622 691 652 -56 -578 -892 -1032 -774 231 558 580 431 193 -91 -212 -128 -68 197 467 714 749 705 540 381 -123 -642 -1028 -1323 -1178 -575 -49 327 484 354 387 423 605 682 775 631 350 150 -51 -277 -562 -654 -641 -482 1 176 -65 -331 -625 -831 -897 -745 -583 -623 -393 -209 -184 -241 -230 -271 -147 -1 496 864 881 934 732 439 36 -493 -1097 -1323 -1218 -749 83 174 200 -107 -565 -589 -352 -175 71 427 606 678 938 1240 1158 815 541 168 -179 46 318 253 374 403 152 296 533 13 -200 -330 -847 -862 -393 -241 -35 296 284 179 279 338 429 525 343 -142 -783 -1161 -1159
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