File name: Pandora170s1_StGeorge_20240924_L2Fit_fwvt1c11d20231109p1-8.txt
File generation date: 20250822T113631.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c11p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 170
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora170_OF_v11d20200302.txt
Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt
Level 1 file used: Pandora170s1_StGeorge_20240924_L1_smca1c11d20231109p1-8.txt
Full location name: University of Toronto - Downtown (St. George) campus
Short location name: StGeorge
Country of location: Canada
Location latitude [deg]: 43.6605
Location longitude [deg]: -79.3986
Location altitude [m]: 176
Local noon date: 20240924
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1633 1782
Nominal wavelengths inside fitting window [nm]: 492.0067 492.1280 492.2493 492.3705 492.4918 492.6130 492.7342 492.8554 492.9766 493.0978 493.2189 493.3400 493.4612 493.5823 493.7033 493.8244 493.9454 494.0665 494.1875 494.3085 494.4295 494.5504 494.6714 494.7923 494.9132 495.0341 495.1550 495.2759 495.3967 495.5175 495.6383 495.7591 495.8799 496.0007 496.1214 496.2422 496.3629 496.4836 496.6042 496.7249 496.8455 496.9662 497.0868 497.2074 497.3280 497.4485 497.5691 497.6896 497.8101 497.9306 498.0511 498.1715 498.2920 498.4124 498.5328 498.6532 498.7736 498.8939 499.0143 499.1346 499.2549 499.3752 499.4955 499.6157 499.7360 499.8562 499.9764 500.0966 500.2168 500.3369 500.4570 500.5772 500.6973 500.8174 500.9374 501.0575 501.1775 501.2975 501.4175 501.5375 501.6575 501.7774 501.8974 502.0173 502.1372 502.2571 502.3769 502.4968 502.6166 502.7364 502.8562 502.9760 503.0958 503.2155 503.3353 503.4550 503.5747 503.6943 503.8140 503.9337 504.0533 504.1729 504.2925 504.4121 504.5316 504.6512 504.7707 504.8902 505.0097 505.1292 505.2486 505.3680 505.4875 505.6069 505.7263 505.8456 505.9650 506.0843 506.2036 506.3229 506.4422 506.5615 506.6807 506.8000 506.9192 507.0384 507.1576 507.2767 507.3959 507.5150 507.6341 507.7532 507.8723 507.9913 508.1104 508.2294 508.3484 508.4674 508.5864 508.7053 508.8243 508.9432 509.0621 509.1810 509.2999 509.4187 509.5375 509.6564 509.7752 509.8939
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240924T204308.5Z 9033.863293 544 1 3.66 2 65.18 242.25 100.58 326.65 0.00 1 0.00 1 0 22 3.747e-03 3.715e-03 9.331e-04 9.315e-04 4.733316e+03 5.602509e+01 3.407332e+02 -6.000000e+00 1.987528e+02 283.73 -2.00 20.00 -2.00 505.25 0.00e+00 6.631082e-04 2.524041e-05 3.947315e-05 -6.000000e+00 1.036189e-04 283.73 -2.00 20.00 -2.00 500.39 0.00e+00 1.552102e-01 1.804338e-02 3.055128e-02 -6.000000e+00 7.281937e-02 227.83 -2.00 3.57 -2.00 501.98 0.00e+00 2.367 0.000 489.00 513.00 1 5.3245e+00 1.3781e-03 4.3374e-03 -6.0000e+00 5.5651e-03 9.3078e-03 3.6244e-04 7.7086e-04 -6.0000e+00 1.4730e-03 6.6653e-03 8.4648e-04 7.5632e-05 4.5835e-05 -6.0000e+00 3.1553e-04 -6.5288e-03 2.5747e-05 12 1 1 12 1 1 43.80 22.85 1.00 -0.00653 -0.00066 9 27 1 4 0 365.800 26.73 20.00 22.85 26.74 11.8 1013.33 -931 -904 -537 61 -202 209 546 449 540 430 289 191 -175 -207 -383 -439 -319 -255 56 64 180 126 54 362 396 361 547 481 -134 -325 -370 -646 -470 310 522 295 311 139 -134 -290 -183 -242 36 237 389 367 409 183 336 -105 -218 -428 -969 -767 -503 -144 243 279 93 68 179 381 398 437 286 193 164 -34 105 -437 -405 -375 -346 35 166 191 -127 -318 -467 -571 -464 -101 -377 -361 -114 -41 -159 -103 -168 -55 -103 497 647 416 531 529 132 70 -270 -737 -582 -1031 -459 231 19 -17 -105 -466 -317 -132 -150 -79 190 430 333 524 673 617 446 364 154 -107 134 83 96 209 224 -34 248 319 110 -78 -83 -516 -528 -225 -76 -147 84 202 105 175 192 350 314 107 -219 -348 -739 -664 -901 -881 -538 61 -210 215 572 477 575 454 300 196 -178 -212 -389 -446 -327 -259 58 67 187 131 56 375 414 378 570 498 -140 -328 -374 -652 -467 317 540 310 324 143 -136 -300 -189 -252 36 244 405 384 426 188 341 -108 -216 -424 -945 -748 -502 -145 251 283 95 69 180 385 405 445 290 198 165 -34 103 -426 -401 -371 -336 35 166 190 -124 -313 -455 -555 -451 -99 -362 -349 -111 -40 -158 -102 -166 -54 -103 498 642 416 523 524 127 68 -256 -686 -537 -969 -444 227 18 -17 -103 -465 -311 -130 -146 -78 191 433 336 530 687 617 444 367 152 -104 128 80 94 204 218 -33 240 310 106 -76 -80 -491 -500 -216 -73 -144 83 202 103 172 190 347 312 106 -219 -338 -703 -628
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SQ 20240924T204724.7Z 9033.866258 547 2 6.86 2 65.87 243.15 100.98 327.46 0.00 1 0.00 1 0 22 3.708e-03 3.670e-03 1.212e-04 1.210e-04 4.751420e+03 7.265592e+00 3.402925e+02 -6.000000e+00 1.966761e+02 283.73 -2.00 20.00 -2.00 505.26 0.00e+00 6.729013e-04 3.277610e-06 4.089871e-05 -6.000000e+00 1.025320e-04 283.73 -2.00 20.00 -2.00 500.42 0.00e+00 1.526324e-01 2.340999e-03 3.134621e-02 -6.000000e+00 7.204817e-02 227.82 -2.00 3.57 -2.00 502.01 0.00e+00 2.429 0.000 489.00 513.00 1 1.9278e+00 1.7880e-04 4.4467e-03 -6.0000e+00 5.5063e-03 1.4455e-03 4.6982e-05 7.8577e-04 -6.0000e+00 1.4572e-03 1.9735e-01 4.3940e-04 9.8338e-06 4.4798e-05 -6.0000e+00 3.1234e-04 -2.5911e-03 1.6380e-05 10 0 0 10 0 0 86.68 22.85 1.00 -0.00259 0.00046 503 101 1 4 0 12.960 26.73 19.99 22.85 26.80 11.8 1014.49 -1013 -939 -474 -134 -38 286 474 522 545 295 242 104 -155 -208 -375 -457 -409 -53 181 94 191 193 98 263 373 357 476 489 -49 -310 -460 -673 -530 243 347 373 379 165 -83 -177 -114 -113 65 213 388 383 407 310 230 -109 -363 -696 -929 -820 -413 -125 93 236 121 198 156 334 367 490 427 248 154 31 -101 -368 -382 -379 -279 105 197 29 -90 -245 -420 -525 -360 -278 -389 -148 -97 -108 -126 -146 -151 -133 -107 293 479 452 522 454 254 31 -262 -621 -815 -817 -441 96 33 126 -38 -412 -383 -252 -135 11 226 335 393 555 732 632 447 375 115 -132 67 182 51 206 238 61 269 386 3 -43 -112 -537 -526 -191 -175 -109 167 209 75 144 184 240 330 180 -138 -515 -688 -714 -985 -921 -464 -136 -38 297 489 547 571 307 247 108 -159 -210 -375 -456 -413 -54 187 100 201 203 104 278 385 370 492 514 -50 -318 -458 -669 -534 246 357 390 392 168 -86 -182 -116 -117 68 218 401 398 421 317 238 -110 -366 -682 -896 -791 -408 -125 95 238 122 204 160 336 372 496 431 253 155 31 -99 -365 -374 -372 -277 103 196 29 -88 -240 -407 -506 -348 -271 -383 -146 -95 -107 -125 -144 -149 -132 -106 294 477 452 515 449 246 30 -247 -591 -770 -763 -425 94 33 125 -37 -411 -376 -248 -132 11 227 339 398 564 731 636 449 379 114 -129 65 177 50 202 233 60 262 376 3 -42 -107 -512 -500 -184 -168 -107 167 205 74 142 184 241 331 180 -136 -505 -660 -682
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