File name: Pandora170s1_StGeorge_20241129_L2Fit_fout2c11d20231109p1-8.txt File generation date: 20250822T120748.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt Level 1 file used: Pandora170s1_StGeorge_20241129_L1_smca1c11d20231109p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20241129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0510 305.1920 305.3331 305.4742 305.6152 305.7562 305.8973 306.0383 306.1793 306.3203 306.4612 306.6022 306.7431 306.8841 307.0250 307.1659 307.3068 307.4477 307.5886 307.7295 307.8704 308.0112 308.1520 308.2929 308.4337 308.5745 308.7153 308.8561 308.9968 309.1376 309.2783 309.4191 309.5598 309.7005 309.8412 309.9819 310.1226 310.2633 310.4039 310.5446 310.6852 310.8258 310.9664 311.1070 311.2476 311.3882 311.5287 311.6693 311.8098 311.9504 312.0909 312.2314 312.3719 312.5124 312.6528 312.7933 312.9338 313.0742 313.2146 313.3550 313.4954 313.6358 313.7762 313.9166 314.0569 314.1973 314.3376 314.4780 314.6183 314.7586 314.8989 315.0391 315.1794 315.3197 315.4599 315.6001 315.7404 315.8806 316.0208 316.1610 316.3011 316.4413 316.5814 316.7216 316.8617 317.0018 317.1419 317.2820 317.4221 317.5622 317.7023 317.8423 317.9823 318.1224 318.2624 318.4024 318.5424 318.6824 318.8223 318.9623 319.1022 319.2422 319.3821 319.5220 319.6619 319.8018 319.9417 320.0815 320.2214 320.3612 320.5011 320.6409 320.7807 320.9205 321.0603 321.2000 321.3398 321.4795 321.6193 321.7590 321.8987 322.0384 322.1781 322.3178 322.4575 322.5971 322.7368 322.8764 323.0160 323.1557 323.2953 323.4348 323.5744 323.7140 323.8535 323.9931 324.1326 324.2721 324.4116 324.5511 324.6906 324.8301 324.9696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241129T161521.2Z 9099.677329 198 1 49.85 2 66.33 167.11 66.00 187.15 0.00 1 0.00 1 0 17 3.256e-02 8.780e-03 1.269e-02 1.595e-03 3.979751e-01 7.885550e-04 4.781425e-03 -6.000000e+00 1.824657e-02 222.40 -2.00 3.57 -2.00 318.48 0.00e+00 9.931927e-04 1.615682e-04 2.759458e-04 -6.000000e+00 8.007656e-04 275.59 -2.00 20.00 -2.00 317.90 0.00e+00 2.472 0.000 302.00 328.00 3 4.4153e+00 2.1170e-03 3.1528e-02 -6.0000e+00 4.4895e-02 1.4642e-03 2.4230e-03 2.0225e-02 -6.0000e+00 4.9030e-02 1.8449e-02 1.7111e-03 1.0232e-02 -6.0000e+00 2.9208e-02 -1.4136e-02 9.1022e-04 3.1119e-03 -6.0000e+00 1.2389e-02 3.4208e-04 -1.5318e-04 4.5037e-05 3.2627e-05 -6.0000e+00 8.8482e-04 -6.7833e-03 0.0000e+00 11 8 0 10 0 0 99.30 22.85 0.42 -0.00678 -0.00793 40 8 1 5 0 1245.990 26.73 20.00 22.85 7.14 12.7 989.75 -3497 7053 -2410 14030 -14934 -5809 1013 741 2933 582 -1734 -18173 10349 -7276 4666 395 -4603 2094 -3051 5903 -583 6088 -5 4652 -2985 6227 273 -1660 -1335 -210 -575 -2901 2891 -1343 -3296 -5767 -3749 -3180 736 -3412 -1793 -168 -1576 249 -1920 1284 236 774 -2388 -1474 319 813 1820 729 1407 1620 702 477 315 -1113 389 1635 1513 3617 461 32 -703 -1124 -43 1546 718 1428 1126 1241 806 -849 -441 -2945 -1108 -1540 -780 -1258 -2706 -2067 -675 -580 85 1168 1317 853 681 284 -725 -641 -227 -203 555 1213 1030 -32 -317 -2028 -901 -289 -853 -1440 -615 -980 -336 955 663 552 341 -47 -242 72 76 -315 658 63 17 -149 729 329 586 46 -709 1344 585 409 94 -665 -628 -237 8 -417 251 882 86 -12 283 -886 -500 -122 253 -99 484 -620 -213 37 31 133 29 -90 -1164 588 -580 394 39 -520 236 -382 712 -77 757 -1 640 -472 952 44 -265 -204 -32 -96 -553 580 -292 -705 -1235 -847 -826 219 -1208 -685 -67 -654 103 -816 537 99 324 -1032 -648 146 399 940 398 792 934 415 282 184 -651 230 1020 1019 2551 338 22 -480 -768 -31 1207 602 1228 968 1034 639 -632 -307 -2044 -799 -1228 -680 -1187 -2710 -2140 -722 -649 99 1365 1535 973 743 294 -720 -634 -236 -227 669 1562 1387 -43 -410 -2494 -1059 -344 -1069 -1879 -822 -1357 -483 1433 1039 879 536 -71 -352 102 106 -456 985 98 27 -230 1096 485 838 64 -968 1839 847 627 150 -1088 -1046 -406 14 -761 463 1637 161 -22 505 -1546 -863 SS 20241129T162602.0Z 9099.684745 201 1 49.90 2 65.94 169.79 66.30 189.78 0.00 1 0.00 1 0 17 5.739e-02 1.155e-02 2.282e-02 2.697e-03 3.931132e-01 1.333377e-03 4.716719e-03 -6.000000e+00 3.215961e-02 222.40 -2.00 3.57 -2.00 318.61 0.00e+00 3.945052e-04 2.827406e-04 3.862780e-04 -6.000000e+00 1.411375e-03 275.59 -2.00 20.00 -2.00 318.03 0.00e+00 2.436 0.000 302.00 328.00 3 5.4008e+00 3.5891e-03 3.1109e-02 -6.0000e+00 7.9127e-02 7.1186e-03 4.1206e-03 2.0018e-02 -6.0000e+00 8.6417e-02 1.1725e-02 2.9540e-03 1.0108e-02 -6.0000e+00 5.1479e-02 -9.1800e-03 1.5716e-03 2.9554e-03 -6.0000e+00 2.1834e-02 1.3299e-04 -1.8200e-04 7.6640e-05 3.1587e-05 -6.0000e+00 1.5595e-03 -6.6236e-03 0.0000e+00 12 9 8 11 40 0 98.87 22.85 0.47 -0.00662 -0.00799 14 3 1 5 0 3563.540 26.73 20.00 22.85 7.41 12.7 989.76 1056 9166 -5316 23958 -7098 -10932 13268 1566 -4386 -35037 2272 -28776 8803 -5345 10237 8226 3094 -1421 -12366 4984 -947 7566 10460 6040 -869 10300 3418 -6628 -5139 9678 -5786 -5853 2015 1036 -3242 -5088 -5036 -886 2769 -8224 -1355 1901 -1992 1246 -3591 872 2856 -619 -2182 -971 1094 1360 372 1390 2668 3522 739 1007 1193 -2443 -524 1759 810 3854 964 211 -1219 -3150 443 1257 610 2746 1006 717 1998 -1660 -486 -3913 -1826 -1926 -992 -1401 -2368 -1735 -494 108 -1067 1723 1491 602 864 -450 -732 -674 -679 -199 480 1418 992 92 -112 -1878 -1527 -243 -926 -1472 26 -1040 -486 1167 651 606 256 -440 -210 654 -407 -335 1313 86 -67 -18 604 669 531 -412 -1078 1721 1606 161 191 -1061 -1142 -395 -355 -715 494 1063 222 516 219 -640 -940 34 308 -215 716 -261 -399 408 61 -204 -2328 109 -1951 483 -398 778 721 308 -156 -1594 572 -118 875 1209 778 -128 1443 513 -1051 -771 1272 -952 -1080 383 208 -653 -1019 -1085 -214 770 -2909 -496 715 -799 494 -1488 351 1126 -251 -900 -406 477 638 187 730 1438 1935 424 576 669 -1398 -302 1063 534 2645 687 146 -812 -2122 308 961 503 2301 851 589 1535 -1211 -328 -2653 -1285 -1503 -850 -1303 -2339 -1774 -523 120 -1236 2001 1731 685 935 -463 -718 -658 -700 -221 577 1822 1338 124 -145 -2300 -1793 -288 -1159 -1923 35 -1447 -702 1762 1029 974 406 -675 -306 915 -575 -486 1968 135 -105 -28 914 988 762 -577 -1476 2346 2315 249 307 -1753 -1921 -683 -637 -1323 921 1994 419 955 394 -1125 -1638 SS 20241129T165644.7Z 9099.706073 217 1 50.62 2 65.33 177.59 67.65 197.21 0.00 1 0.00 1 0 17 3.735e-02 9.122e-03 1.435e-02 1.791e-03 3.880785e-01 8.845734e-04 4.657964e-03 -6.000000e+00 2.093488e-02 222.40 -2.00 3.57 -2.00 318.46 0.00e+00 9.162873e-04 1.798882e-04 2.584109e-04 -6.000000e+00 9.185999e-04 275.59 -2.00 20.00 -2.00 317.87 0.00e+00 2.380 0.000 302.00 328.00 3 4.7167e+00 2.3721e-03 3.0513e-02 -6.0000e+00 5.1509e-02 4.0548e-03 2.7141e-03 1.9704e-02 -6.0000e+00 5.6251e-02 2.5190e-02 1.9111e-03 9.9691e-03 -6.0000e+00 3.3510e-02 -1.8531e-02 1.0167e-03 3.0240e-03 -6.0000e+00 1.4216e-02 2.7859e-04 -9.7110e-05 5.0744e-05 3.1664e-05 -6.0000e+00 1.0150e-03 -7.9229e-03 0.0000e+00 11 8 0 10 0 0 99.98 22.85 0.47 -0.00792 -0.00865 37 7 1 5 0 1367.710 26.73 20.00 22.85 8.15 12.7 989.36 19484 -14011 10981 12980 -3365 -8799 12342 11489 -2984 8869 -5379 -8213 3696 2663 -1480 4316 -5885 2597 -2696 5872 -627 4197 5599 1978 -296 2489 3101 -4602 -1787 -478 -3643 -1240 2845 25 -6510 -4759 -5475 -2676 1664 -4738 -884 -654 -1171 -212 -1714 206 1246 -354 -1621 -1007 9 733 874 653 1387 2885 26 550 191 -628 -15 1215 1429 2932 1229 -103 -633 -1949 1097 1303 642 1905 1041 887 875 -731 -800 -2363 -1065 -1082 -894 -1171 -2613 -2461 -927 -464 501 1369 1494 826 1028 -215 -508 -459 -234 -26 405 1189 903 -126 -303 -1757 -983 -76 -1012 -1753 -485 -1593 -309 626 1089 505 385 -246 -427 35 -146 -179 631 173 -158 503 608 355 822 -206 -662 1187 795 345 297 -924 -677 -131 4 -273 126 820 256 136 92 -790 -678 570 -636 416 470 -130 -343 418 444 -149 422 -299 -495 230 199 -136 424 -687 297 -343 722 -84 541 730 284 -46 401 499 -767 -279 -74 -631 -235 576 5 -1444 -1017 -1265 -697 495 -1713 -339 -264 -489 -89 -735 88 525 -151 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