File name: Pandora170s1_StGeorge_20241228_L2Fit_fout2c11d20231109p1-8.txt File generation date: 20250822T121608.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt Level 1 file used: Pandora170s1_StGeorge_20241228_L1_smca1c11d20231109p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20241228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0510 305.1920 305.3331 305.4742 305.6152 305.7562 305.8973 306.0383 306.1793 306.3203 306.4612 306.6022 306.7431 306.8841 307.0250 307.1659 307.3068 307.4477 307.5886 307.7295 307.8704 308.0112 308.1520 308.2929 308.4337 308.5745 308.7153 308.8561 308.9968 309.1376 309.2783 309.4191 309.5598 309.7005 309.8412 309.9819 310.1226 310.2633 310.4039 310.5446 310.6852 310.8258 310.9664 311.1070 311.2476 311.3882 311.5287 311.6693 311.8098 311.9504 312.0909 312.2314 312.3719 312.5124 312.6528 312.7933 312.9338 313.0742 313.2146 313.3550 313.4954 313.6358 313.7762 313.9166 314.0569 314.1973 314.3376 314.4780 314.6183 314.7586 314.8989 315.0391 315.1794 315.3197 315.4599 315.6001 315.7404 315.8806 316.0208 316.1610 316.3011 316.4413 316.5814 316.7216 316.8617 317.0018 317.1419 317.2820 317.4221 317.5622 317.7023 317.8423 317.9823 318.1224 318.2624 318.4024 318.5424 318.6824 318.8223 318.9623 319.1022 319.2422 319.3821 319.5220 319.6619 319.8018 319.9417 320.0815 320.2214 320.3612 320.5011 320.6409 320.7807 320.9205 321.0603 321.2000 321.3398 321.4795 321.6193 321.7590 321.8987 322.0384 322.1781 322.3178 322.4575 322.5971 322.7368 322.8764 323.0160 323.1557 323.2953 323.4348 323.5744 323.7140 323.8535 323.9931 324.1326 324.2721 324.4116 324.5511 324.6906 324.8301 324.9696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241228T164147.6Z 9128.695689 207 1 50.30 2 67.45 170.62 73.64 198.80 0.00 1 0.00 1 0 17 1.904e-02 8.848e-03 1.176e-03 2.669e-04 3.540560e-01 1.316510e-04 4.263137e-03 -6.000000e+00 1.068186e-02 222.75 -2.00 3.57 -2.00 317.78 0.00e+00 1.110605e-03 2.147753e-05 2.291897e-04 -6.000000e+00 4.632297e-04 273.01 -2.00 20.00 -2.00 317.22 0.00e+00 2.586 0.000 302.00 328.00 3 9.3448e-01 3.4705e-04 3.0880e-02 -6.0000e+00 2.6325e-02 2.2374e-02 3.9311e-04 1.7903e-02 -6.0000e+00 2.8754e-02 -1.0439e-02 2.5098e-04 8.9943e-03 -6.0000e+00 1.7099e-02 -2.0322e-03 1.2912e-04 2.7449e-03 -6.0000e+00 7.2325e-03 1.0779e-02 -5.3545e-05 7.5603e-06 2.9059e-05 -6.0000e+00 5.1725e-04 -8.1877e-03 0.0000e+00 11 8 0 10 0 0 99.95 22.60 0.23 -0.00819 -0.00859 1209 242 1 5 0 41.320 26.51 20.00 22.60 14.85 13.4 998.20 214 -1880 256 -4167 -6815 -6019 -5945 -2228 -1831 -4003 -7804 -6220 -3647 -1329 599 1021 400 1529 1506 2169 1385 -111 1167 931 1027 922 -450 -2316 -2303 -1998 -53 709 2695 -823 -5063 -4472 -4782 -2586 -371 -327 -765 -375 -22 -445 427 705 -6 114 -877 -466 934 929 1238 1570 788 1466 1252 366 -32 -184 357 1585 2279 3043 885 -567 -966 -2072 632 1388 723 1181 672 1150 374 -628 -1444 -2736 -1342 -1303 -1343 -1160 -2673 -2083 -985 -453 459 843 1285 904 839 182 -1145 -559 -270 -351 322 1343 764 58 -393 -1855 -1191 123 -841 -1454 -811 -1148 -238 691 926 629 508 90 -292 -197 57 -50 732 371 155 472 843 433 904 23 -636 897 404 286 142 -819 -602 -140 48 -257 48 692 215 3 89 -889 -598 14 -142 20 -323 -491 -407 -421 -172 -158 -376 -771 -632 -413 -161 84 161 68 272 282 421 278 -22 238 202 238 224 -111 -557 -526 -454 -13 190 722 -238 -1460 -1247 -1439 -895 -141 -146 -355 -183 -11 -229 219 362 -3 58 -448 -242 510 551 736 985 518 984 860 252 -22 -124 246 1095 1722 2326 702 -431 -729 -1557 498 1164 634 1077 613 1001 321 -519 -1093 -2024 -1040 -1087 -1209 -1158 -2767 -2257 -1072 -525 531 1002 1517 1032 933 196 -1156 -553 -286 -396 387 1699 1036 79 -499 -2271 -1431 150 -1068 -1883 -1094 -1564 -341 1019 1396 971 763 133 -414 -276 80 -70 1087 562 238 710 1222 632 1252 32 -849 1200 564 418 221 -1273 -959 -233 81 -443 85 1232 385 5 153 -1484 -1014 SS 20241228T165154.5Z 9128.702715 210 1 50.47 2 67.19 173.13 74.26 200.99 0.00 1 0.00 1 0 17 1.874e-02 8.901e-03 1.109e-03 2.627e-04 3.506351e-01 1.297926e-04 4.231949e-03 -6.000000e+00 1.051474e-02 222.75 -2.00 3.57 -2.00 317.71 0.00e+00 1.110781e-03 2.076678e-05 2.270976e-04 -6.000000e+00 4.559962e-04 273.01 -2.00 20.00 -2.00 317.15 0.00e+00 2.559 0.000 302.00 328.00 3 9.4459e-01 3.4152e-04 3.0567e-02 -6.0000e+00 2.5913e-02 2.1207e-02 3.8665e-04 1.7727e-02 -6.0000e+00 2.8304e-02 -1.1036e-02 2.4492e-04 8.9162e-03 -6.0000e+00 1.6832e-02 -1.5715e-03 1.2557e-04 2.7252e-03 -6.0000e+00 7.1191e-03 1.1009e-02 -1.3378e-04 7.4082e-06 2.8164e-05 -6.0000e+00 5.0918e-04 -7.9314e-03 0.0000e+00 11 8 0 10 0 0 95.37 22.61 0.22 -0.00793 -0.00894 1151 231 1 5 0 43.390 26.51 20.00 22.61 16.22 13.5 997.34 -216 -732 -533 -3245 -7372 -6147 -5386 -1887 -2151 -4107 -7152 -6372 -2708 -1835 1515 833 393 1511 1082 2285 1269 254 989 1332 727 1080 -572 -2303 -2521 -1956 53 670 2928 -1066 -4776 -4843 -4713 -2669 -400 -235 -837 -227 -32 -194 407 810 -55 202 -821 -401 922 952 1222 1497 846 1383 1339 343 42 -170 367 1522 2253 3059 869 -526 -1025 -1956 602 1360 687 1218 672 1097 400 -689 -1333 -2842 -1262 -1319 -1306 -1229 -2687 -2048 -1032 -505 385 814 1176 902 821 207 -1141 -510 -270 -386 340 1294 761 46 -363 -1886 -1174 111 -852 -1456 -794 -1148 -239 684 892 663 511 156 -310 -204 87 -70 745 354 172 460 848 435 912 -10 -665 904 387 299 92 -756 -586 -98 52 -218 68 674 206 -31 116 -908 -601 -15 -57 -44 -262 -561 -436 -397 -152 -196 -405 -735 -678 -317 -232 219 137 70 279 212 460 265 53 210 299 176 272 -147 -574 -598 -460 13 171 808 -319 -1417 -1398 -1462 -953 -157 -108 -400 -114 -16 -102 215 428 -29 106 -431 -214 517 543 744 963 569 896 885 228 28 -117 243 1078 1742 2392 705 -408 -791 -1499 457 1164 615 1132 626 976 350 -549 -1029 -2147 -997 -1121 -1196 -1188 -2833 -2151 -1144 -569 454 986 1416 1050 931 216 -1172 -513 -290 -443 415 1663 1005 61 -468 -2347 -1369 131 -1052 -1917 -1043 -1588 -334 1025 1365 1038 779 232 -447 -277 118 -99 1077 522 258 701 1247 618 1282 -13 -901 1226 548 443 140 -1189 -945 -158 86 -380 121 1173 361 -55 196 -1535 -994 SS 20241228T165854.5Z 9128.707576 214 1 50.45 2 67.06 174.87 74.72 202.48 0.00 1 0.00 1 0 17 1.835e-02 8.928e-03 1.042e-03 2.503e-04 3.495019e-01 1.238205e-04 4.223393e-03 -6.000000e+00 1.029884e-02 222.75 -2.00 3.57 -2.00 317.68 0.00e+00 1.122542e-03 1.965298e-05 2.295582e-04 -6.000000e+00 4.466321e-04 273.01 -2.00 20.00 -2.00 317.13 0.00e+00 2.545 0.000 302.00 328.00 3 8.6636e-01 3.2558e-04 3.0430e-02 -6.0000e+00 2.5381e-02 2.2286e-02 3.6847e-04 1.7678e-02 -6.0000e+00 2.7723e-02 -1.1874e-02 2.3285e-04 8.8883e-03 -6.0000e+00 1.6486e-02 -1.3306e-03 1.1924e-04 2.7151e-03 -6.0000e+00 6.9730e-03 1.2074e-02 -1.2488e-04 7.0691e-06 2.8217e-05 -6.0000e+00 4.9873e-04 -7.9381e-03 0.0000e+00 11 8 0 10 0 0 89.78 22.61 0.22 -0.00794 -0.00888 1247 250 1 5 0 40.060 26.51 19.99 22.61 17.05 13.7 998.29 77 -1594 144 -3407 -6315 -5829 -5045 -2100 -1901 -4424 -7429 -6217 -3155 -1181 914 1034 284 1357 1124 2279 1327 -111 1181 1048 871 1048 -555 -2289 -2517 -2007 -104 575 2685 -843 -4893 -4750 -4563 -2410 -304 -221 -691 -334 -63 -289 438 808 22 199 -794 -384 908 996 1232 1498 838 1454 1352 420 22 -182 422 1503 2302 3010 864 -523 -955 -2009 558 1327 703 1202 638 1117 323 -752 -1423 -2765 -1296 -1281 -1366 -1228 -2696 -2021 -1005 -466 399 811 1201 855 801 218 -1147 -512 -229 -350 325 1306 786 31 -401 -1902 -1171 85 -844 -1494 -809 -1152 -248 686 911 658 550 138 -279 -213 83 -48 749 390 147 474 850 455 939 36 -649 896 399 282 110 -782 -576 -134 65 -269 57 654 215 7 114 -897 -617 5 -129 12 -280 -483 -419 -377 -172 -175 -444 -777 -670 -377 -151 134 172 51 255 222 465 280 -24 253 239 213 267 -144 -577 -604 -477 -26 148 749 -254 -1467 -1382 -1426 -866 -120 -102 -333 -170 -33 -154 232 430 12 105 -420 -206 512 571 755 970 534 946 899 281 14 -119 281 1070 1790 2367 705 -407 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