File name: Pandora170s1_StGeorge_20250510_L2Fit_fout2c8d20220508p1-8.txt File generation date: 20250511T052929.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt Level 1 file used: Pandora170s1_StGeorge_20250510_L1_smca1c8d20220508p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20250510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0405 305.1816 305.3227 305.4638 305.6048 305.7458 305.8869 306.0279 306.1689 306.3099 306.4509 306.5918 306.7328 306.8737 307.0147 307.1556 307.2965 307.4374 307.5783 307.7192 307.8600 308.0009 308.1417 308.2826 308.4234 308.5642 308.7050 308.8458 308.9866 309.1273 309.2681 309.4088 309.5496 309.6903 309.8310 309.9717 310.1124 310.2530 310.3937 310.5344 310.6750 310.8156 310.9562 311.0968 311.2374 311.3780 311.5186 311.6591 311.7997 311.9402 312.0808 312.2213 312.3618 312.5023 312.6427 312.7832 312.9237 313.0641 313.2045 313.3450 313.4854 313.6258 313.7662 313.9065 314.0469 314.1873 314.3276 314.4679 314.6082 314.7486 314.8889 315.0291 315.1694 315.3097 315.4499 315.5902 315.7304 315.8706 316.0108 316.1510 316.2912 316.4314 316.5715 316.7117 316.8518 316.9919 317.1320 317.2721 317.4122 317.5523 317.6924 317.8324 317.9725 318.1125 318.2525 318.3925 318.5325 318.6725 318.8125 318.9525 319.0924 319.2323 319.3723 319.5122 319.6521 319.7920 319.9319 320.0717 320.2116 320.3515 320.4913 320.6311 320.7709 320.9107 321.0505 321.1903 321.3301 321.4698 321.6096 321.7493 321.8890 322.0287 322.1684 322.3081 322.4478 322.5875 322.7271 322.8668 323.0064 323.1460 323.2856 323.4252 323.5648 323.7044 323.8439 323.9835 324.1230 324.2625 324.4021 324.5416 324.6810 324.8205 324.9600 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250510T103353.5Z 9261.440203 188 1 48.82 2 84.82 70.34 109.98 271.36 0.00 1 0.00 1 0 25 1.271e+00 1.068e-01 4.230e-01 3.636e-02 1.121856e+00 2.495529e-02 1.407310e-02 -6.000000e+00 8.163283e-01 230.43 -2.00 3.57 -2.00 317.32 0.00e+00 2.693804e-02 6.768937e-03 1.435930e-02 -6.000000e+00 4.204981e-02 280.38 -2.00 20.00 -2.00 317.59 0.00e+00 9.562 0.017 302.00 328.00 3 9.5826e-02 8.1231e-02 1.6744e-01 -6.0000e+00 2.0415e+00 3.0422e+00 9.2704e-02 1.7555e-01 -6.0000e+00 2.2333e+00 -3.3490e+00 4.1017e-02 2.8459e-02 -6.0000e+00 1.3092e+00 1.2285e+00 2.6436e-02 4.4129e-02 -6.0000e+00 5.6486e-01 7.2471e-06 -2.9660e-03 1.0229e-03 1.6643e-04 -6.0000e+00 4.3118e-02 1.0238e-03 0.0000e+00 12 9 8 11 32 0 69.26 22.97 2.02 0.00102 -0.02126 14 3 1 5 0 3485.520 26.94 20.00 22.97 14.34 15.9 999.36 900000 -2751 900000 900000 243670 248113 900000 410508 208847 900000 174545 4170 900000 214356 230273 427550 124415 361606 111452 900000 211147 900000 900000 900000 56772 900000 900000 14328 216943 900000 -13275 -42621 900000 134833 900000 39174 900000 900000 900000 900000 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900000 -13057 3814 900000 352 -5042 900000 900000 900000 5687 1547 6701 900000 900000 900000 6630 900000 4555 900000 -13520 3186 -8636 13066 1746 10859 3900 8696 -20124 854 16873 9658 7308 4390 -3592 7850 4063 3574 11467 9600 753 9993 -3983 5739 4233 -2925 5053 4918 2142 17801 -4212 -13121 11861 736 -6802 -15135 -21604 7056 31817 -1167 -10196 3950 -4824 10221 -9628 -4779 7544 6685 -2513 -2208 17431 18027 -6168 1773 -6959 23861 -6070 -7978 -17267 5930 15986 2893 3260 7838 -3099 -17515 SS 20250510T120456.4Z 9261.503431 230 1 50.04 2 68.75 85.33 125.83 287.84 0.00 1 0.00 1 0 17 2.502e-02 8.260e-03 2.129e-03 3.259e-04 4.026674e-01 1.654181e-04 4.750733e-03 -6.000000e+00 1.445374e-02 230.43 -2.00 3.57 -2.00 318.34 0.00e+00 1.177273e-03 3.181876e-05 3.922335e-04 -6.000000e+00 6.276466e-04 280.38 -2.00 20.00 -2.00 317.64 0.00e+00 2.734 0.000 302.00 328.00 3 3.3345e-01 4.4831e-04 3.4320e-02 -6.0000e+00 3.6169e-02 -7.8039e-04 5.0966e-04 2.1142e-02 -6.0000e+00 3.9236e-02 -1.2358e-02 3.4140e-04 1.0403e-02 -6.0000e+00 2.3294e-02 -1.5022e-03 1.7725e-04 3.0658e-03 -6.0000e+00 9.7605e-03 1.5799e-02 2.2712e-04 9.1785e-06 3.1343e-05 -6.0000e+00 6.8124e-04 6.8388e-04 0.0000e+00 11 8 0 10 0 0 92.46 22.95 0.22 0.00068 0.00239 885 177 1 5 0 56.470 26.83 20.00 22.95 17.04 15.8 1000.54 -2202 -7907 -2991 -5919 -8961 -7761 -9150 -4748 -5600 -6417 -10772 -8448 -4620 -2233 22 321 14 1020 1172 1681 1019 -454 665 778 484 1002 -360 -2516 -2940 -2105 73 654 2493 -1097 -5108 -4422 -4882 -2653 -480 -451 -774 -510 -160 -374 482 628 -108 -76 -1015 -500 815 991 1180 1607 808 1555 1372 377 38 -203 464 1510 2250 3036 843 -443 -753 -1792 745 1432 776 1245 644 1049 198 -773 -1405 -2700 -1270 -1262 -1315 -1168 -2527 -1908 -955 -494 437 825 1198 817 824 234 -1053 -501 -267 -339 274 1259 646 -47 -379 -1859 -1073 155 -871 -1428 -791 -1142 -168 621 860 539 468 40 -329 -146 132 12 665 294 118 458 854 445 915 -54 -601 869 316 212 33 -761 -561 -89 20 -220 71 684 205 -8 82 -846 -536 -89 -389 -148 -291 -413 -337 -426 -241 -324 -400 -717 -581 -355 -202 2 35 2 129 158 236 149 -67 100 124 84 181 -66 -455 -511 -365 14 137 574 -254 -1181 -992 -1190 -748 -161 -166 -318 -222 -67 -160 207 271 -47 -33 -446 -225 388 515 619 894 473 933 844 234 23 -123 288 1003 1546 2247 615 -329 -528 -1262 555 1139 647 1080 560 870 162 -573 -1014 -1920 -954 -1027 -1160 -1091 -2582 -1948 -1031 -542 503 973 1405 927 911 239 -1065 -501 -274 -374 324 1645 870 -63 -499 -2255 -1272 187 -1092 -1830 -1058 -1547 -241 923 1314 848 719 60 -481 -201 183 17 983 459 187 707 1270 666 1301 -77 -825 1202 459 325 52 -1252 -916 -152 36 -392 129 1261 381 -15 146 -1449 -931 SS 20250510T123019.1Z 9261.521054 245 1 23.01 2 64.16 89.62 130.04 293.22 0.00 1 0.00 1 0 17 5.061e-02 1.268e-02 2.740e-02 4.807e-03 3.416343e-01 2.436079e-03 4.038103e-03 -6.000000e+00 2.924159e-02 230.43 -2.00 3.57 -2.00 318.25 0.00e+00 1.830706e-03 4.544520e-04 1.537965e-04 -6.000000e+00 1.269541e-03 280.38 -2.00 20.00 -2.00 317.56 0.00e+00 2.281 0.000 302.00 328.00 3 4.9566e+00 6.5852e-03 2.8861e-02 -6.0000e+00 7.3176e-02 4.2467e-02 7.4684e-03 1.8036e-02 -6.0000e+00 7.9374e-02 -1.6316e-04 4.8869e-03 8.8509e-03 -6.0000e+00 4.7124e-02 -5.0591e-03 2.5224e-03 2.9540e-03 -6.0000e+00 1.9750e-02 2.5036e-04 3.7820e-04 1.3804e-04 2.8582e-05 -6.0000e+00 1.3779e-03 -8.3069e-04 0.0000e+00 12 9 9 12 1 1 99.99 22.95 0.87 -0.00083 0.00201 8 4 1 5 0 2555.910 26.83 20.00 22.95 18.71 16.0 1000.16 134 -229 12827 -969 -21951 -15439 -5186 14590 -13941 17699 -6494 -17634 16021 -6712 9683 8669 -5147 -8432 -1518 3812 -369 6529 11145 3229 -1516 8593 2945 -2076 -8026 12332 -4271 -2025 1597 1622 -5797 -4904 -3377 -3744 3887 -8127 -1352 -643 -2980 92 -1625 805 2146 2835 -3924 -659 -984 2097 293 2328 2040 3503 1727 2102 1280 -3931 -309 953 1193 3504 1188 76 -406 -2165 -571 2404 1056 2685 1614 1738 881 -239 -3495 -3686 -1962 -2480 -564 -2322 -2349 -3035 -216 -1674 464 2529 1644 1329 -338 21 -974 -684 -1207 838 110 1503 642 -480 -58 -1847 -558 -406 -705 -1616 118 -1138 465 703 761 492 248 -92 -1007 544 -509 -1046 391 426 556 145 507 268 1037 -679 -520 1666 955 -155 -268 -603 252 -202 -255 -149 582 1277 -285 -165 394 -1017 -977 7 -13 681 -57 -1424 -895 -285 749 -1043 1041 -485 -1520 1147 -700 1012 1025 -741 -1315 -234 583 -60 1000 1662 546 -284 1532 554 -393 -1536 1953 -846 -435 364 384 -1410 -1154 -841 -1081 1242 -3313 -567 -282 -1374 42 -756 369 968 1260 -1840 -305 -482 1072 161 1319 1195 2074 1055 1278 771 -2459 -193 627 845 2585 901 55 -281 -1506 -415 1892 902 2342 1416 1478 713 -180 -2501 -2563 -1411 -1982 -491 -2216 -2362 -3191 -233 -1923 546 3001 1961 1547 -378 22 -966 -669 -1246 924 133 1930 868 -649 -75 -2256 -650 -483 -886 -2130 159 -1597 672 1068 1203 789 390 -139 -1451 746 -703 -1496 580 655 865 223 763 394 1465 -940 -696 2222 1349 -234 -419 -965 408 -338 -444 -268 1058 2340 -529 -301 696 -1759 -1671 SS 20250510T132501.4Z 9261.559044 288 1 49.16 2 54.31 99.55 138.43 306.84 0.00 1 0.00 1 0 17 1.826e-02 1.020e-02 6.087e-03 2.276e-03 2.614866e-01 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