File name: Pandora170s1_StGeorge_20250605_L2Fit_fout2c11d20231109p1-8.txt File generation date: 20250822T131627.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora170_OF_v11d20200302.txt Instrument calibration file used: Pandora170s1_CF_v11d20231109.txt Level 1 file used: Pandora170s1_StGeorge_20250605_L1_smca1c11d20231109p1-8.txt Full location name: University of Toronto - Downtown (St. George) campus Short location name: StGeorge Country of location: Canada Location latitude [deg]: 43.6605 Location longitude [deg]: -79.3986 Location altitude [m]: 176 Local noon date: 20250605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0510 305.1920 305.3331 305.4742 305.6152 305.7562 305.8973 306.0383 306.1793 306.3203 306.4612 306.6022 306.7431 306.8841 307.0250 307.1659 307.3068 307.4477 307.5886 307.7295 307.8704 308.0112 308.1520 308.2929 308.4337 308.5745 308.7153 308.8561 308.9968 309.1376 309.2783 309.4191 309.5598 309.7005 309.8412 309.9819 310.1226 310.2633 310.4039 310.5446 310.6852 310.8258 310.9664 311.1070 311.2476 311.3882 311.5287 311.6693 311.8098 311.9504 312.0909 312.2314 312.3719 312.5124 312.6528 312.7933 312.9338 313.0742 313.2146 313.3550 313.4954 313.6358 313.7762 313.9166 314.0569 314.1973 314.3376 314.4780 314.6183 314.7586 314.8989 315.0391 315.1794 315.3197 315.4599 315.6001 315.7404 315.8806 316.0208 316.1610 316.3011 316.4413 316.5814 316.7216 316.8617 317.0018 317.1419 317.2820 317.4221 317.5622 317.7023 317.8423 317.9823 318.1224 318.2624 318.4024 318.5424 318.6824 318.8223 318.9623 319.1022 319.2422 319.3821 319.5220 319.6619 319.8018 319.9417 320.0815 320.2214 320.3612 320.5011 320.6409 320.7807 320.9205 321.0603 321.2000 321.3398 321.4795 321.6193 321.7590 321.8987 322.0384 322.1781 322.3178 322.4575 322.5971 322.7368 322.8764 323.0160 323.1557 323.2953 323.4348 323.5744 323.7140 323.8535 323.9931 324.1326 324.2721 324.4116 324.5511 324.6906 324.8301 324.9696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250605T143114.2Z 9287.605026 259 1 0.66 2 39.86 108.28 138.61 33.77 0.00 1 0.00 1 0 17 1.370e-02 9.856e-03 4.680e-03 3.181e-03 1.879491e-01 1.652122e-03 2.281144e-03 -6.000000e+00 7.967557e-03 232.25 -2.00 3.57 -2.00 315.00 0.00e+00 4.114575e-04 1.406217e-04 5.520749e-05 -6.000000e+00 3.478050e-04 283.15 -2.00 20.00 -2.00 314.38 0.00e+00 1.301 0.000 302.00 328.00 3 2.7473e+00 4.2749e-03 1.6247e-02 -6.0000e+00 2.0009e-02 2.4833e-02 4.7397e-03 9.8743e-03 -6.0000e+00 2.1668e-02 -4.0480e-03 2.7053e-03 4.7807e-03 -6.0000e+00 1.2865e-02 -2.0319e-03 1.1782e-03 1.3100e-03 -6.0000e+00 5.3819e-03 7.7163e-03 -4.5382e-04 8.9652e-05 1.6908e-05 -6.0000e+00 3.7340e-04 -5.8255e-03 0.0000e+00 12 9 9 12 9 1 83.42 23.28 0.26 -0.00583 -0.00924 3 62 1 5 0 162.270 27.26 19.99 23.28 26.02 16.5 1017.63 2601 -211 2171 -2669 -2774 -4011 -2723 709 1895 -1441 -2541 -2152 -1501 -307 826 1146 -132 1451 1096 2292 1459 -399 1019 1549 2282 1831 1230 -1109 -1604 -835 1676 204 2129 -200 -4986 -2653 -4591 -1869 -192 112 -1809 -424 -1256 -152 -471 835 -149 -799 -660 -1264 1117 926 1545 1518 440 1042 1214 305 114 469 192 1785 2059 2566 689 -1513 -826 -1888 4 1225 1077 678 593 1438 1039 -765 -1032 -2192 -1006 -1141 -1310 -1096 -2717 -1475 -1152 -504 308 439 800 437 710 141 -428 -37 -155 -696 286 1029 665 118 64 -1643 -1111 260 -936 -1634 -696 -1234 -164 626 1151 453 367 230 38 100 1 45 763 109 119 639 519 285 1206 112 -536 1066 295 244 167 -369 -464 -402 -92 -203 276 535 -272 -41 174 -728 -710 812 -72 734 -896 -859 -1190 -820 226 649 -522 -919 -776 -571 -126 364 532 -63 698 540 1145 743 -205 521 811 1231 1013 679 -599 -829 -419 841 108 1161 -112 -2778 -1422 -2606 -1146 -130 82 -1420 -340 -1023 -123 -383 673 -120 -628 -509 -973 868 747 1280 1289 382 910 1069 270 100 409 170 1634 1966 2515 679 -1443 -745 -1675 3 1179 1091 705 619 1468 1025 -720 -915 -1887 -875 -1055 -1292 -1136 -2938 -1627 -1315 -596 374 542 988 531 827 156 -451 -38 -163 -773 334 1257 839 148 77 -1925 -1269 302 -1140 -2062 -894 -1625 -220 861 1616 640 507 304 48 122 1 56 988 147 163 870 697 375 1536 139 -651 1285 368 315 221 -494 -626 -553 -131 -296 407 797 -408 -61 254 -1047 -1013 SS 20250605T144044.9Z 9287.611631 262 1 49.69 2 38.24 110.63 137.68 36.88 0.00 1 0.00 1 0 9 1.503e-02 9.773e-03 1.639e-03 1.009e-03 1.864901e-01 5.219477e-04 2.251016e-03 -6.000000e+00 8.739472e-03 232.25 -2.00 3.57 -2.00 315.40 0.00e+00 6.515830e-04 4.827317e-05 3.599722e-05 -6.000000e+00 3.813501e-04 283.15 -2.00 20.00 -2.00 314.76 0.00e+00 1.272 0.000 302.00 328.00 3 4.9742e+00 1.3558e-03 1.5981e-02 -6.0000e+00 2.1948e-02 3.2439e-02 1.5043e-03 9.8214e-03 -6.0000e+00 2.3764e-02 -4.0273e-03 8.5928e-04 4.7404e-03 -6.0000e+00 1.4110e-02 -2.9562e-03 3.8061e-04 1.3387e-03 -6.0000e+00 5.9056e-03 8.5500e-04 -5.8076e-05 2.8611e-05 1.6321e-05 -6.0000e+00 4.0938e-04 -8.8720e-03 0.0000e+00 12 8 8 10 0 0 99.88 23.28 0.49 -0.00887 -0.00931 61 12 1 5 0 814.450 27.26 19.99 23.28 26.87 16.6 1023.81 2724 -9005 1539 -154 -3360 -302 287 3149 1608 -93 -2962 -3428 367 -193 1826 758 -403 894 880 2226 1485 573 1576 1774 745 1944 418 -917 -740 31 878 1111 3100 -513 -4190 -3666 -3235 -2145 114 -1071 -1281 -756 -782 -507 -470 441 -255 -120 -1399 -648 457 843 933 1352 646 1267 1084 633 17 -170 544 1349 1977 2433 615 -555 -1042 -2058 706 1389 635 1063 757 1305 834 -415 -776 -2601 -797 -1378 -1222 -1356 -2551 -1980 -1113 -819 143 671 954 850 715 165 -821 -293 -192 -180 375 1134 847 -16 -257 -1868 -1000 2 -804 -1464 -516 -1141 -363 694 796 612 537 40 -97 -7 -59 -338 669 348 181 337 634 335 1015 155 -442 1236 527 329 229 -580 -297 90 119 -305 126 617 54 -34 -24 -1093 -877 709 -2872 448 -43 -907 -73 71 849 462 -28 -913 -1057 118 -70 694 315 -175 392 397 1021 699 270 736 859 364 969 209 -461 -344 14 395 532 1552 -271 -2164 -1813 -1700 -1232 73 -764 -955 -586 -620 -404 -373 344 -196 -92 -1055 -480 347 648 754 1133 559 1061 922 539 14 -148 465 1220 1839 2372 605 -529 -906 -1807 637 1342 648 1086 776 1340 805 -380 -666 -2228 -689 -1275 -1210 -1413 -2746 -2219 -1270 -965 176 851 1206 1038 840 183 -865 -295 -202 -199 437 1386 1096 -21 -310 -2182 -1151 2 -1001 -1875 -684 -1526 -504 972 1160 867 752 53 -124 -8 -72 -435 884 477 256 472 860 452 1291 196 -531 1516 663 426 309 -802 -400 125 170 -458 187 934 82 -50 -35 -1601 -1260 SS 20250605T144644.8Z 9287.615797 266 1 49.28 2 37.23 112.17 137.06 38.79 0.00 1 0.00 1 0 17 1.610e-02 1.060e-02 2.910e-03 1.682e-03 1.858855e-01 8.674905e-04 2.227661e-03 -6.000000e+00 9.363882e-03 232.25 -2.00 3.57 -2.00 315.65 0.00e+00 6.174809e-04 8.412492e-05 5.605808e-05 -6.000000e+00 4.085851e-04 283.16 -2.00 20.00 -2.00 314.98 0.00e+00 1.255 0.000 302.00 328.00 3 5.8720e+00 2.2605e-03 1.5810e-02 -6.0000e+00 2.3516e-02 4.1544e-02 2.5140e-03 9.7430e-03 -6.0000e+00 2.5462e-02 -3.6151e-03 1.4361e-03 4.7081e-03 -6.0000e+00 1.5118e-02 -3.3046e-03 6.4038e-04 1.3212e-03 -6.0000e+00 6.3277e-03 3.5327e-04 1.8667e-05 4.7927e-05 1.5609e-05 -6.0000e+00 4.3861e-04 -9.0944e-03 0.0000e+00 12 8 8 10 0 0 99.99 23.28 0.63 -0.00909 -0.00895 35 7 1 5 0 1407.980 27.26 20.00 23.28 27.15 16.7 1024.75 2293 -7450 2164 -352 -3231 -766 -348 3851 859 1918 -4068 -5300 562 -438 1993 189 -1086 331 580 2535 1246 992 2512 2173 833 2720 300 -1153 -1656 525 -392 124 2608 -360 -4629 -3463 -3977 -1535 850 -1506 -981 -817 -940 -844 -505 393 263 112 -2081 -558 62 1154 838 1456 904 1462 1117 842 141 -396 832 1207 1950 2789 839 -380 -999 -2698 260 1333 757 1945 926 1387 887 -482 -732 -3211 -1055 -1530 -878 -1299 -2702 -2185 -819 -1433 -46 850 1200 650 987 -46 -1406 -566 -449 -137 -73 1264 951 60 -245 -1835 -1078 -97 -807 -1569 -329 -1148 -137 1126 693 540 372 239 -261 301 -296 -651 563 597 300 163 738 509 762 233 -645 1165 840 293 277 -651 -282 -225 201 -170 184 925 122 -62 -86 -1199 -1031 553 -2111 573 -91 -771 -168 -78 922 232 533 -1176 -1547 167 -146 719 74 -442 135 244 1075 543 431 1083 972 392 1298 145 -537 -731 220 -169 56 1225 -176 -2233 -1607 -1958 -834 520 -1044 -722 -621 -727 -656 -391 302 198 83 -1520 -400 45 879 664 1183 751 1226 949 715 119 -334 711 1078 1824 2689 814 -352 -870 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