File name: Pandora170s1_StGeorge_20250622_L2Fit_fwvt1c8d20220508p1-8.txt
File generation date: 20250623T053000.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c8p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 170
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora170_OF_v11d20200302.txt
Instrument calibration file used: Pandora170s1_CF_v8d20220508.txt
Level 1 file used: Pandora170s1_StGeorge_20250622_L1_smca1c8d20220508p1-8.txt
Full location name: University of Toronto - Downtown (St. George) campus
Short location name: StGeorge
Country of location: Canada
Location latitude [deg]: 43.6605
Location longitude [deg]: -79.3986
Location altitude [m]: 176
Local noon date: 20250622
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1633 1782
Nominal wavelengths inside fitting window [nm]: 492.0081 492.1294 492.2507 492.3720 492.4932 492.6145 492.7357 492.8569 492.9781 493.0993 493.2204 493.3416 493.4627 493.5838 493.7049 493.8260 493.9470 494.0681 494.1891 494.3101 494.4311 494.5521 494.6730 494.7940 494.9149 495.0358 495.1567 495.2776 495.3984 495.5193 495.6401 495.7609 495.8817 496.0025 496.1232 496.2440 496.3647 496.4854 496.6061 496.7268 496.8474 496.9681 497.0887 497.2093 497.3299 497.4505 497.5710 497.6915 497.8121 497.9326 498.0531 498.1735 498.2940 498.4144 498.5348 498.6552 498.7756 498.8960 499.0164 499.1367 499.2570 499.3773 499.4976 499.6179 499.7381 499.8584 499.9786 500.0988 500.2190 500.3391 500.4593 500.5794 500.6995 500.8196 500.9397 501.0598 501.1798 501.2999 501.4199 501.5399 501.6598 501.7798 501.8998 502.0197 502.1396 502.2595 502.3794 502.4992 502.6191 502.7389 502.8587 502.9785 503.0983 503.2180 503.3378 503.4575 503.5772 503.6969 503.8166 503.9362 504.0559 504.1755 504.2951 504.4147 504.5343 504.6538 504.7733 504.8929 505.0124 505.1319 505.2513 505.3708 505.4902 505.6096 505.7290 505.8484 505.9678 506.0871 506.2064 506.3258 506.4451 506.5643 506.6836 506.8028 506.9221 507.0413 507.1605 507.2796 507.3988 507.5179 507.6371 507.7562 507.8753 507.9943 508.1134 508.2324 508.3514 508.4705 508.5894 508.7084 508.8274 508.9463 509.0652 509.1841 509.3030 509.4219 509.5407 509.6595 509.7783 509.8971
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250622T102523.2Z 9304.434296 151 1 49.63 2 83.19 63.93 53.33 94.90 0.00 1 0.00 1 0 22 6.165e-03 6.057e-03 1.524e-03 1.520e-03 1.796643e+04 1.080351e+02 1.200384e+03 -6.000000e+00 3.287303e+02 284.82 -2.00 20.00 -2.00 505.35 0.00e+00 1.553107e-03 4.135547e-05 1.066420e-04 -6.000000e+00 1.708468e-04 284.82 -2.00 20.00 -2.00 500.57 0.00e+00 7.323778e-01 2.954988e-02 1.023555e-01 -6.000000e+00 1.204166e-01 232.93 -2.00 3.57 -2.00 502.14 0.00e+00 7.693 0.009 489.00 513.00 1 7.1025e+00 2.2532e-03 1.4210e-02 -6.0000e+00 9.2035e-03 -2.8894e-02 5.8148e-04 2.6921e-03 -6.0000e+00 2.4346e-03 4.9437e-04 -8.8859e-05 1.1313e-04 1.3318e-04 -6.0000e+00 5.1983e-04 -6.3843e-03 8.0823e-05 12 8 8 10 0 0 99.99 23.27 1.56 -0.00638 -0.00700 24 5 1 4 0 2067.400 27.15 20.00 23.27 30.12 16.9 1036.27 -1574 -1142 -614 27 -163 895 1055 928 886 280 205 -32 89 -592 -207 -905 -703 210 202 207 713 262 -77 833 346 433 584 307 -143 -706 -1047 -1257 -618 425 914 430 335 -136 58 -165 -532 -244 -531 83 284 625 566 392 976 135 -547 -511 -1340 -1486 -621 -232 311 559 61 289 54 243 870 612 506 -4 43 189 -307 -287 -698 -433 -590 -268 -63 178 -674 -987 -370 -786 -660 -406 -462 -213 -119 355 -308 -430 -285 923 397 405 1579 757 921 588 626 159 -370 -1101 -1570 -1534 -627 -382 -183 -498 -37 -746 -81 -112 -350 -295 53 620 152 877 801 1168 395 667 -221 -363 109 294 48 472 119 219 252 84 -236 -69 -30 -665 -793 35 276 32 508 292 454 211 535 565 285 556 -701 -597 -1163 -793 -1440 -1051 -581 27 -159 885 1065 954 914 287 207 -32 88 -578 -199 -878 -689 209 208 218 747 276 -78 875 356 446 600 314 -145 -715 -1033 -1240 -617 436 940 452 349 -140 59 -167 -539 -248 -549 87 300 662 598 411 1000 136 -539 -507 -1316 -1465 -625 -234 320 582 64 300 56 254 912 644 530 -4 44 189 -306 -282 -680 -422 -582 -268 -64 179 -670 -961 -353 -748 -626 -388 -445 -207 -117 353 -308 -429 -281 894 388 402 1575 758 893 548 578 143 -327 -965 -1373 -1370 -582 -365 -184 -496 -37 -731 -81 -113 -346 -296 53 618 153 874 815 1211 415 689 -225 -359 106 286 48 467 118 218 250 83 -235 -67 -29 -637 -764 34 276 33 524 297 468 219 559 591 299 577 -725 -603 -1161 -788
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SQ 20250622T105119.8Z 9304.452312 159 1 6.72 2 78.90 68.11 48.75 99.59 0.00 1 0.00 1 0 22 4.764e-03 4.698e-03 3.227e-04 3.223e-04 1.271188e+04 2.149414e+01 8.686598e+02 -6.000000e+00 2.539688e+02 284.82 -2.00 20.00 -2.00 505.31 0.00e+00 1.206695e-03 8.783396e-06 8.359468e-05 -6.000000e+00 1.320283e-04 284.82 -2.00 20.00 -2.00 500.56 0.00e+00 4.064218e-01 6.250685e-03 7.487636e-02 -6.000000e+00 9.309230e-02 232.93 -2.00 3.57 -2.00 502.13 0.00e+00 5.009 0.002 489.00 513.00 1 2.6619e+00 4.7710e-04 9.7528e-03 -6.0000e+00 7.1141e-03 -2.9980e-02 1.2388e-04 1.9298e-03 -6.0000e+00 1.8835e-03 6.3387e-02 7.7035e-04 2.4993e-05 1.0753e-04 -6.0000e+00 4.0141e-04 3.9125e-03 -3.1433e-05 12 9 9 12 1 1 99.67 23.27 1.17 0.00391 0.00926 76 115 1 4 0 87.180 27.15 19.99 23.27 30.82 17.0 1039.89 -1091 -896 -326 29 226 591 827 809 781 550 379 174 -177 -264 -460 -527 -420 11 252 146 278 234 87 271 406 389 478 471 -133 -517 -720 -878 -635 218 340 391 293 110 -147 -316 -187 -167 106 181 403 432 472 340 222 -194 -506 -903 -1240 -1065 -564 -82 182 335 205 164 256 379 468 523 479 249 47 -34 -247 -485 -605 -537 -388 12 172 -32 -258 -419 -664 -616 -532 -431 -460 -298 -182 -149 -140 -193 -188 -153 -24 432 730 726 788 691 295 94 -425 -943 -1157 -1148 -749 -72 3 46 -72 -483 -445 -311 -180 -18 169 329 424 678 881 943 597 394 170 -162 50 229 166 299 347 53 273 469 44 -57 -184 -607 -578 -142 -117 49 303 269 208 228 327 369 481 364 -80 -509 -814 -799 -1038 -860 -316 29 225 590 842 822 797 557 384 174 -176 -262 -455 -521 -420 11 255 151 288 243 89 277 418 402 493 483 -137 -522 -707 -862 -633 220 352 404 305 113 -150 -319 -189 -170 108 188 416 449 489 349 228 -195 -504 -891 -1206 -1036 -552 -82 186 341 209 167 260 387 480 537 490 252 48 -34 -244 -482 -595 -528 -385 12 172 -32 -254 -411 -644 -593 -512 -418 -450 -294 -179 -148 -140 -192 -186 -151 -24 432 728 723 779 671 282 89 -395 -864 -1056 -1067 -712 -70 3 46 -72 -481 -438 -308 -181 -18 170 332 428 685 887 965 614 401 172 -160 49 228 165 297 345 52 270 466 43 -56 -178 -588 -561 -140 -117 49 306 271 212 234 338 376 490 375 -81 -515 -810 -792
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