File name: Pandora81s1_StocktonIL_20250425_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20250426T060548.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora81_OF_v4d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_StocktonIL_20250425_L1_smca1c2d20240325p1-8.txt Full location name: CASTNET Site STK138 Short location name: StocktonIL Country of location: United States Location latitude [deg]: 42.2872 Location longitude [deg]: -90.0000 Location altitude [m]: 281 Local noon date: 20250425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250425T112632.4Z 9246.476764 83 1 19.67 2 86.73 74.88 72.91 104.98 0.00 1 0.00 1 0 22 5.839e-03 5.782e-03 3.217e-04 3.209e-04 1.508519e+04 2.247377e+01 1.004168e+03 -6.000000e+00 3.221167e+02 279.00 -2.00 20.00 -2.00 505.41 0.00e+00 2.238190e-03 8.845020e-06 1.429711e-04 -6.000000e+00 1.623425e-04 279.00 -2.00 20.00 -2.00 500.97 0.00e+00 1.054655e+00 6.244063e-03 1.068938e-01 -6.000000e+00 1.162107e-01 229.13 -2.00 3.53 -2.00 502.49 0.00e+00 12.949 0.041 489.00 513.00 1 3.3748e+00 4.7718e-04 2.1179e-02 -6.0000e+00 8.9024e-03 -6.0936e-02 1.1943e-04 2.8052e-03 -6.0000e+00 2.3009e-03 9.8170e-03 1.7135e-03 2.9816e-05 1.3156e-04 -6.0000e+00 6.0544e-04 -1.0501e-02 1.0479e-04 12 9 9 12 1 1 54.91 26.54 3.72 -0.01050 0.00138 97 26 1 4 0 200.630 34.50 19.91 26.54 14.72 1.6 950.29 -865 -677 -195 511 790 1049 1326 1138 1046 737 438 92 -201 -388 -608 -468 -247 30 224 329 207 348 352 503 609 619 344 97 -218 -767 -957 -822 -551 -55 154 130 76 -35 -260 -293 -172 -37 177 408 529 640 612 344 -22 -402 -767 -1112 -1178 -1042 -613 -195 172 356 371 473 518 579 601 531 398 221 -73 -302 -508 -623 -721 -703 -530 -418 -262 -341 -536 -739 -882 -839 -817 -746 -625 -514 -433 -486 -541 -425 -438 -216 -122 58 420 558 578 472 198 -356 -737 -1050 -1243 -1103 -805 -493 -183 -199 -294 -325 -291 -284 -135 125 465 734 1018 1274 1301 1175 902 660 393 303 270 384 554 550 494 535 325 274 240 93 -214 -388 -435 -315 -119 86 253 398 516 395 470 420 317 179 -58 -376 -686 -846 -765 -779 -611 -178 481 750 1001 1285 1098 1008 704 422 88 -189 -369 -570 -442 -237 29 218 324 205 345 350 495 603 614 341 96 -213 -746 -921 -795 -535 -54 153 131 76 -35 -257 -292 -169 -37 178 409 536 651 621 346 -22 -398 -754 -1073 -1146 -1007 -606 -195 173 362 378 476 521 586 611 541 404 222 -73 -301 -503 -619 -713 -698 -523 -417 -263 -342 -531 -732 -865 -818 -797 -731 -618 -506 -432 -481 -538 -422 -439 -216 -121 58 422 558 576 464 191 -336 -692 -974 -1153 -1042 -776 -483 -184 -201 -300 -330 -294 -288 -136 128 479 758 1053 1306 1350 1220 944 688 410 311 277 394 563 563 508 553 337 284 247 95 -217 -391 -441 -323 -123 89 266 420 552 422 506 455 344 193 -62 -404 -729 -894 -815 SQ 20250425T113718.1Z 9246.484237 86 1 54.83 2 84.80 76.65 71.02 106.87 0.00 1 0.00 1 0 22 3.635e-03 3.608e-03 1.629e-04 1.627e-04 1.172616e+04 1.110640e+01 7.915757e+02 -6.000000e+00 2.005028e+02 279.00 -2.00 20.00 -2.00 505.37 0.00e+00 1.618449e-03 4.469685e-06 1.071816e-04 -6.000000e+00 1.010418e-04 279.00 -2.00 20.00 -2.00 500.83 0.00e+00 9.228074e-01 3.183281e-03 8.433314e-02 -6.000000e+00 7.229494e-02 229.13 -2.00 3.53 -2.00 502.37 0.00e+00 9.544 0.016 489.00 513.00 1 3.5555e+00 2.4337e-04 1.5421e-02 -6.0000e+00 5.5387e-03 -4.4872e-02 6.1295e-05 2.1772e-03 -6.0000e+00 1.4306e-03 1.3419e-02 4.5583e-04 1.5502e-05 1.0004e-04 -6.0000e+00 3.7672e-04 3.0036e-03 6.3155e-05 10 0 0 10 0 0 96.47 26.52 1.93 0.00300 0.00617 367 35 1 4 0 149.370 34.75 20.03 26.52 15.39 1.5 953.77 -548 -324 -50 311 557 739 841 694 679 509 268 33 -142 -280 -331 -307 -162 -56 85 146 155 177 229 259 377 385 182 13 -48 -336 -555 -443 -285 -69 113 89 55 -63 -170 -188 -156 8 89 257 367 398 333 207 -49 -269 -541 -690 -744 -705 -429 -223 -16 137 196 304 327 337 335 306 260 165 -36 -254 -354 -402 -431 -420 -385 -288 -145 -229 -332 -457 -481 -492 -502 -478 -359 -306 -229 -249 -312 -233 -247 -91 -10 59 197 332 343 283 102 -249 -386 -631 -772 -679 -546 -371 -215 -237 -294 -236 -166 -158 -86 40 258 477 657 792 816 717 615 408 288 244 260 259 328 311 293 353 220 135 177 102 -113 -227 -176 -150 29 48 143 265 338 272 285 301 174 33 -66 -219 -418 -497 -489 -504 -299 -47 298 539 721 834 686 670 504 263 32 -138 -269 -318 -297 -157 -55 85 146 156 179 231 259 380 389 184 13 -47 -327 -541 -434 -282 -69 114 90 56 -64 -171 -188 -157 8 90 263 373 407 339 212 -50 -269 -533 -674 -721 -689 -423 -224 -16 139 199 308 331 343 343 314 265 166 -36 -253 -353 -396 -423 -413 -382 -285 -145 -228 -326 -448 -466 -481 -491 -464 -351 -303 -226 -248 -309 -233 -246 -91 -10 59 198 333 339 276 97 -236 -362 -591 -722 -638 -523 -363 -215 -240 -298 -237 -165 -158 -87 40 264 484 668 810 843 741 637 421 296 247 263 261 333 314 297 359 224 137 178 103 -113 -226 -175 -151 30 49 147 277 353 286 299 318 184 35 -70 -228 -434 -513 -507 SQ 20250425T114919.7Z 9246.492590 89 1 31.07 2 82.62 78.62 68.92 109.04 0.00 1 0.00 1 0 22 2.636e-03 2.624e-03 3.895e-04 3.892e-04 8.679972e+03 2.571831e+01 5.963386e+02 -6.000000e+00 1.454104e+02 279.00 -2.00 20.00 -2.00 505.34 0.00e+00 1.220083e-03 1.066492e-05 8.029441e-05 -6.000000e+00 7.328017e-05 279.00 -2.00 20.00 -2.00 500.70 0.00e+00 7.526969e-01 7.660056e-03 6.314864e-02 -6.000000e+00 5.244633e-02 229.13 -2.00 3.53 -2.00 502.26 0.00e+00 7.206 0.007 489.00 513.00 1 5.0423e+00 5.8601e-04 1.1537e-02 -6.0000e+00 4.0178e-03 -2.3843e-02 1.4841e-04 1.6223e-03 -6.0000e+00 1.0382e-03 4.2867e-03 7.6120e-04 3.7781e-05 7.7339e-05 -6.0000e+00 2.7326e-04 4.4672e-03 3.1360e-05 12 1 1 12 1 1 69.46 26.51 1.44 0.00447 0.00975 46 8 1 4 0 660.690 34.75 20.06 26.51 15.48 1.5 956.10 -430 -295 -139 165 304 522 664 410 484 428 118 -75 -121 -267 -231 -270 -57 1 -2 150 69 185 174 212 346 313 191 7 -17 -228 -288 -286 -168 13 90 35 -22 -63 -148 -183 -60 72 87 200 273 364 256 116 -91 -246 -338 -480 -535 -560 -279 -208 -56 79 103 167 190 228 212 223 196 116 -48 -184 -317 -220 -336 -377 -199 -215 -98 -151 -240 -303 -245 -210 -294 -349 -239 -246 -172 -196 -142 -89 -101 -138 13 108 177 232 227 171 13 -272 -188 -344 -454 -538 -429 -281 -301 -309 -283 -156 -145 -55 -14 -35 292 280 495 644 580 432 390 284 253 199 198 230 153 219 227 288 221 72 158 148 -92 -110 -122 -33 -37 116 54 185 267 248 261 221 50 -44 -98 -253 -250 -414 -435 -405 -279 -133 161 301 521 673 414 487 432 118 -74 -119 -261 -225 -265 -56 1 -2 152 70 188 178 218 356 323 196 7 -17 -226 -281 -281 -166 13 92 36 -23 -64 -150 -185 -61 73 89 205 279 373 261 119 -92 -246 -333 -469 -519 -547 -274 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