File name: Pandora81s1_StocktonIL_20250917_L2Fit_fwvt1c2d20240325p1-8.txt
File generation date: 20250918T060711.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Kevin Mishoe
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 81
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora81_OF_v5d20230613.txt
Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt
Level 1 file used: Pandora81s1_StocktonIL_20250917_L1_smca1c2d20240325p1-8.txt
Full location name: CASTNET Site STK138
Short location name: StocktonIL
Country of location: United States
Location latitude [deg]: 42.2872
Location longitude [deg]: -90.0000
Location altitude [m]: 281
Local noon date: 20250917
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off of session 1 lab analysis
First and last pixel inside fitting window: 1623 1773
Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250917T120454.0Z 9391.503403 201 1 27.47 2 86.69 90.25 38.32 108.33 0.00 1 0.00 1 0 22 5.394e-03 5.335e-03 2.390e-04 2.385e-04 1.908259e+04 1.761324e+01 1.239761e+03 -6.000000e+00 3.046803e+02 285.21 -2.00 20.00 -2.00 505.41 0.00e+00 2.319150e-03 6.678111e-06 1.529693e-04 -6.000000e+00 1.523090e-04 285.21 -2.00 20.00 -2.00 500.93 0.00e+00 8.270569e-01 4.630779e-03 1.202718e-01 -6.000000e+00 1.068759e-01 228.82 -2.00 3.53 -2.00 502.45 0.00e+00 12.826 0.040 489.00 513.00 1 3.1540e+00 3.5479e-04 2.1545e-02 -6.0000e+00 8.2072e-03 -5.2877e-02 8.8438e-05 3.1484e-03 -6.0000e+00 2.1166e-03 1.2579e-02 1.6395e-03 2.1495e-05 1.3617e-04 -6.0000e+00 5.5945e-04 -1.2065e-03 5.8433e-05 12 9 9 12 1 1 52.94 26.20 3.09 -0.00121 0.01017 172 32 1 4 0 158.690 34.50 19.97 26.20 23.66 4.6 965.06 -750 -395 -15 497 874 1087 1225 1111 976 740 409 120 -189 -387 -489 -434 -189 -14 204 298 231 286 291 319 442 440 326 -23 -248 -705 -823 -773 -523 -126 163 125 6 -111 -260 -307 -248 -23 157 427 549 551 510 261 -8 -384 -818 -1071 -1114 -976 -531 -186 91 270 358 428 483 544 514 495 402 201 -44 -329 -506 -610 -689 -673 -542 -395 -240 -342 -518 -694 -763 -752 -691 -646 -541 -412 -374 -429 -470 -413 -304 -179 10 232 400 600 559 493 238 -268 -669 -963 -1240 -1046 -832 -516 -211 -177 -289 -279 -296 -203 -139 39 312 588 888 1141 1240 1093 821 490 274 214 218 324 511 511 473 450 313 135 168 0 -317 -390 -393 -264 -37 174 296 426 487 358 389 453 339 248 67 -290 -594 -767 -605 -676 -363 -14 470 834 1044 1197 1079 947 713 396 115 -179 -370 -467 -411 -182 -14 199 295 230 281 287 316 442 441 326 -23 -244 -688 -794 -750 -511 -125 164 126 6 -111 -258 -304 -246 -24 157 432 560 565 521 265 -8 -382 -808 -1038 -1087 -948 -520 -187 93 273 363 434 491 555 528 509 411 203 -45 -330 -503 -601 -685 -662 -538 -396 -239 -344 -515 -690 -748 -733 -673 -633 -534 -405 -372 -426 -469 -410 -304 -178 9 231 400 595 549 475 224 -249 -619 -883 -1139 -980 -788 -500 -211 -179 -294 -283 -299 -206 -140 40 320 604 914 1164 1281 1134 860 512 283 219 223 330 523 519 484 462 322 139 172 0 -318 -396 -396 -270 -38 179 310 448 520 382 418 489 367 267 71 -307 -629 -810 -642
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SQ 20250917T121454.6Z 9391.510355 204 2 17.47 2 84.84 91.94 36.63 110.78 0.00 1 0.00 1 0 22 3.411e-03 3.382e-03 1.158e-04 1.156e-04 1.489004e+04 8.277604e+00 9.824521e+02 -6.000000e+00 1.926873e+02 285.21 -2.00 20.00 -2.00 505.37 0.00e+00 1.653866e-03 3.229186e-06 1.126813e-04 -6.000000e+00 9.632278e-05 285.21 -2.00 20.00 -2.00 500.78 0.00e+00 7.311406e-01 2.258790e-03 9.455018e-02 -6.000000e+00 6.758691e-02 228.82 -2.00 3.53 -2.00 502.33 0.00e+00 9.589 0.017 489.00 513.00 1 1.7387e+00 1.7315e-04 1.5930e-02 -6.0000e+00 5.1902e-03 -3.6745e-02 4.3451e-05 2.4465e-03 -6.0000e+00 1.3385e-03 8.2794e-02 1.2405e-03 1.0754e-05 1.0959e-04 -6.0000e+00 3.5380e-04 4.3336e-03 2.8881e-05 10 0 0 10 0 0 9.29 26.19 1.77 0.00433 0.01294 628 59 1 4 0 27.800 34.50 20.04 26.19 24.16 4.4 967.61 -467 -287 -47 337 532 738 819 685 651 498 222 33 -161 -236 -315 -285 -145 -48 92 154 112 160 192 234 328 356 149 -11 -108 -379 -515 -445 -296 -66 73 64 -1 -75 -180 -184 -136 -28 77 262 319 363 338 180 -53 -288 -536 -683 -725 -609 -394 -154 2 114 230 269 306 322 341 268 242 150 -31 -242 -347 -386 -415 -407 -337 -262 -156 -194 -304 -429 -435 -411 -425 -408 -335 -256 -217 -264 -277 -242 -147 -63 58 133 236 369 382 330 156 -188 -405 -600 -747 -652 -531 -367 -201 -212 -246 -194 -161 -138 -86 -4 183 391 601 756 782 672 506 291 197 201 161 217 307 286 246 289 162 81 89 4 -181 -234 -216 -121 50 110 182 301 328 266 279 279 183 120 -5 -167 -367 -456 -406 -434 -269 -44 325 519 728 812 686 650 493 220 33 -158 -228 -305 -277 -142 -48 92 155 113 162 194 236 332 361 151 -11 -108 -373 -501 -435 -292 -67 74 65 -1 -76 -181 -185 -137 -29 78 266 327 374 346 183 -54 -287 -528 -666 -702 -593 -389 -155 2 116 234 274 313 327 347 274 245 152 -32 -241 -347 -382 -408 -401 -335 -261 -156 -194 -303 -420 -426 -400 -413 -399 -327 -253 -214 -263 -274 -242 -146 -62 58 133 236 368 377 319 150 -177 -377 -559 -695 -611 -505 -358 -200 -214 -247 -195 -161 -138 -87 -4 185 397 611 772 800 689 522 299 201 204 162 218 310 288 249 293 165 82 89 4 -180 -232 -214 -120 51 112 187 312 340 279 293 293 192 126 -6 -173 -377 -467 -418
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