File name: Pandora81s1_StocktonIL_20250922_L2Fit_fout2c2d20240325p1-8.txt
File generation date: 20250923T055851.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Kevin Mishoe
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 81
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora81_OF_v5d20230613.txt
Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt
Level 1 file used: Pandora81s1_StocktonIL_20250922_L1_smca1c2d20240325p1-8.txt
Full location name: CASTNET Site STK138
Short location name: StocktonIL
Country of location: United States
Location latitude [deg]: 42.2872
Location longitude [deg]: -90.0000
Location altitude [m]: 281
Local noon date: 20250922
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off of session 1 lab analysis
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1283 305.2686 305.4090 305.5494 305.6897 305.8300 305.9703 306.1106 306.2509 306.3912 306.5315 306.6717 306.8120 306.9522 307.0924 307.2327 307.3729 307.5131 307.6532 307.7934 307.9336 308.0737 308.2139 308.3540 308.4941 308.6342 308.7743 308.9144 309.0544 309.1945 309.3345 309.4746 309.6146 309.7546 309.8946 310.0346 310.1746 310.3146 310.4545 310.5945 310.7344 310.8743 311.0142 311.1541 311.2940 311.4339 311.5738 311.7136 311.8535 311.9933 312.1331 312.2729 312.4128 312.5525 312.6923 312.8321 312.9718 313.1116 313.2513 313.3910 313.5307 313.6704 313.8101 313.9498 314.0895 314.2291 314.3688 314.5084 314.6480 314.7876 314.9272 315.0668 315.2064 315.3460 315.4855 315.6250 315.7646 315.9041 316.0436 316.1831 316.3226 316.4621 316.6015 316.7410 316.8804 317.0198 317.1592 317.2986 317.4380 317.5774 317.7168 317.8561 317.9955 318.1348 318.2742 318.4135 318.5528 318.6921 318.8313 318.9706 319.1099 319.2491 319.3883 319.5276 319.6668 319.8060 319.9452 320.0843 320.2235 320.3626 320.5018 320.6409 320.7800 320.9191 321.0582 321.1973 321.3364 321.4755 321.6145 321.7535 321.8926 322.0316 322.1706 322.3096 322.4486 322.5875 322.7265 322.8654 323.0044 323.1433 323.2822 323.4211 323.5600 323.6989 323.8377 323.9766 324.1154 324.2542 324.3931 324.5319 324.6707 324.8094 324.9482
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250922T133407.7Z 9396.565367 95 1 10.21 2 71.46 107.64 80.77 106.21 0.00 1 0.00 1 0 17 7.775e-02 1.130e-02 4.634e-02 6.725e-03 3.779331e-01 3.385673e-03 4.557046e-03 -6.000000e+00 4.427544e-02 228.24 -2.00 3.53 -2.00 318.56 0.00e+00 1.279349e-03 7.038198e-04 7.113935e-04 -6.000000e+00 1.970477e-03 284.58 -2.00 20.00 -2.00 317.81 0.00e+00 3.106 0.001 302.00 328.00 3 4.6715e+00 9.2150e-03 3.5974e-02 -6.0000e+00 1.1006e-01 5.9790e-02 1.0542e-02 1.9898e-02 -6.0000e+00 1.1952e-01 -2.0140e-02 7.1484e-03 9.7778e-03 -6.0000e+00 7.1233e-02 6.4315e-03 3.7507e-03 2.7717e-03 -6.0000e+00 3.0321e-02 1.5364e-04 -3.7925e-04 1.9123e-04 3.0650e-05 -6.0000e+00 2.0975e-03 7.2147e-03 -1.8100e-05 12 9 9 12 1 1 999.00 26.57 -0.05 0.00721 0.00436 2 2 1 5 0 3400.530 34.75 20.08 26.57 25.36 4.4 962.72 -8423 -34200 -25487 -47173 5885 -10688 -2248 -9381 -25525 -12352 20697 17945 3329 34705 7964 -1153 14022 -6033 1827 -3254 -967 4261 -8751 6258 -3291 -7480 549 -3828 2389 1847 4310 -10473 2874 -7501 -5625 -7717 6495 565 -3923 -1935 362 273 4328 -1879 2536 1513 4001 -1082 -2660 4199 124 2051 2627 3226 2357 2816 -163 -2011 481 -2399 1942 1630 851 1104 445 -1180 1124 619 1953 1031 522 1585 -2 -555 3045 -1153 249 -3220 -569 -1308 -3749 -1504 -740 -673 -989 -173 316 -1265 -602 -39 219 -1190 -621 -623 1046 -1447 391 1688 727 -162 -1489 -642 -1476 401 -882 -1011 -543 -348 -154 1108 282 768 158 702 -136 -165 676 151 -273 564 366 1079 -508 1546 165 311 -24 1316 478 473 -865 -188 297 -507 -398 -796 -147 329 157 195 -1086 588 -471 -376 -2131 -1454 -3032 205 -449 -96 -486 -1707 -745 909 906 231 2094 731 -128 1416 -791 232 -452 -132 553 -1366 899 -548 -1344 89 -610 346 285 724 -2266 598 -1722 -1188 -1716 1418 156 -1244 -693 137 108 1698 -790 1025 621 1586 -449 -1129 1735 58 1016 1381 1788 1361 1524 -92 -1145 261 -1344 1093 1007 583 806 323 -810 723 404 1388 840 427 1322 -1 -442 2316 -820 162 -2138 -403 -1072 -3288 -1431 -745 -713 -1048 -194 369 -1542 -726 -45 230 -1166 -609 -613 1024 -1630 454 2160 988 -216 -1879 -787 -1724 478 -1078 -1302 -730 -493 -218 1673 458 1262 252 1048 -202 -233 951 224 -408 880 577 1651 -769 2339 241 434 -32 1776 708 712 -1402 -315 507 -859 -717 -1426 -269 610 291 351 -2002 1023 -806
SS 20250922T134330.4Z 9396.571879 98 1 54.35 2 69.82 109.42 79.18 107.87 0.00 1 0.00 1 0 17 7.493e-02 1.100e-02 1.790e-02 2.963e-03 3.487301e-01 1.491188e-03 4.133331e-03 -6.000000e+00 4.273546e-02 228.24 -2.00 3.53 -2.00 318.45 0.00e+00 1.763865e-03 2.990980e-04 2.546838e-04 -6.000000e+00 1.900317e-03 284.58 -2.00 20.00 -2.00 317.69 0.00e+00 2.868 0.000 302.00 328.00 3 5.2395e+00 4.0478e-03 3.3129e-02 -6.0000e+00 1.0623e-01 5.6547e-02 4.6182e-03 1.8179e-02 -6.0000e+00 1.1530e-01 -1.7492e-02 3.0706e-03 8.9813e-03 -6.0000e+00 6.8716e-02 5.6851e-03 1.5978e-03 3.0594e-03 -6.0000e+00 2.9295e-02 1.1305e-04 1.5762e-03 8.4666e-05 3.1064e-05 -6.0000e+00 2.0199e-03 3.4129e-03 2.9007e-04 12 9 8 11 8 0 99.95 26.59 0.14 0.00341 0.01526 17 2 1 5 0 3195.830 34.75 19.91 26.59 25.89 4.4 967.43 -16715 -26568 -8057 -38812 -16963 -19772 13468 30186 -27601 -14020 493 8885 3454 34308 8225 2107 14217 -2061 3345 -6856 -171 2517 -4383 7749 -1961 -7692 -974 -8804 3721 -1115 4135 -978 6838 -4953 -9166 -10420 4296 368 -2718 -2344 2641 3970 1273 -2106 2302 222 2503 -1315 -28 5381 151 2265 1474 522 1922 2841 1215 -230 -1008 -3853 976 2959 546 2185 503 -1936 1156 -531 1601 274 135 838 371 550 1165 -842 -409 -2004 -680 -612 -3953 -1730 -157 -1477 -1260 567 172 -1383 -264 864 648 306 -606 129 1716 -437 1194 570 385 67 -716 -1133 -945 268 -1516 -322 -1223 -965 -518 329 232 840 338 81 193 -666 138 -381 -285 796 523 994 -86 220 183 401 1002 1249 1093 497 265 -223 -163 -34 -248 -562 -268 162 74 149 -1193 487 -596 -975 -1842 -463 -2747 -882 -1074 576 1230 -2193 -996 31 560 271 2339 844 252 1590 -287 462 -1088 -25 364 -713 1187 -347 -1489 -173 -1582 569 -188 732 -202 1424 -1153 -2082 -2462 989 104 -960 -861 994 1540 523 -901 947 94 1019 -551 -11 2189 70 1107 773 292 1092 1638 722 -137 -592 -2337 592 1921 398 1531 351 -1404 775 -364 1182 214 113 723 316 445 858 -619 -276 -1352 -494 -466 -3514 -1664 -158 -1463 -1339 631 201 -1689 -317 978 677 319 -594 126 1782 -480 1447 719 511 87 -936 -1363 -1076 315 -1963 -432 -1618 -1342 -762 517 362 1319 552 123 272 -899 186 -541 -432 1264 841 1557 -132 323 256 533 1365 1733 1528 755 428 -349 -261 -56 -443 -1055 -513 297 135 282 -2192 845 -1021
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