File name: Pandora81s1_StocktonIL_20260521_L2Fit_fout2c2d20240325p1-8.txt File generation date: 20260522T060900.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora81_OF_v5d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_StocktonIL_20260521_L1_smca1c2d20240325p1-8.txt Full location name: CASTNET Site STK138 Short location name: StocktonIL Country of location: United States Location latitude [deg]: 42.2872 Location longitude [deg]: -90.0000 Location altitude [m]: 281 Local noon date: 20260521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1283 305.2686 305.4090 305.5494 305.6897 305.8300 305.9703 306.1106 306.2509 306.3912 306.5315 306.6717 306.8120 306.9522 307.0924 307.2327 307.3729 307.5131 307.6532 307.7934 307.9336 308.0737 308.2139 308.3540 308.4941 308.6342 308.7743 308.9144 309.0544 309.1945 309.3345 309.4746 309.6146 309.7546 309.8946 310.0346 310.1746 310.3146 310.4545 310.5945 310.7344 310.8743 311.0142 311.1541 311.2940 311.4339 311.5738 311.7136 311.8535 311.9933 312.1331 312.2729 312.4128 312.5525 312.6923 312.8321 312.9718 313.1116 313.2513 313.3910 313.5307 313.6704 313.8101 313.9498 314.0895 314.2291 314.3688 314.5084 314.6480 314.7876 314.9272 315.0668 315.2064 315.3460 315.4855 315.6250 315.7646 315.9041 316.0436 316.1831 316.3226 316.4621 316.6015 316.7410 316.8804 317.0198 317.1592 317.2986 317.4380 317.5774 317.7168 317.8561 317.9955 318.1348 318.2742 318.4135 318.5528 318.6921 318.8313 318.9706 319.1099 319.2491 319.3883 319.5276 319.6668 319.8060 319.9452 320.0843 320.2235 320.3626 320.5018 320.6409 320.7800 320.9191 321.0582 321.1973 321.3364 321.4755 321.6145 321.7535 321.8926 322.0316 322.1706 322.3096 322.4486 322.5875 322.7265 322.8654 323.0044 323.1433 323.2822 323.4211 323.5600 323.6989 323.8377 323.9766 324.1154 324.2542 324.3931 324.5319 324.6707 324.8094 324.9482 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260521T110947.7Z 9637.465136 59 1 55.86 2 84.73 67.31 116.62 8.92 0.00 1 0.00 1 0 65 1.357e+00 2.168e-01 3.484e-01 4.495e-02 1.304998e+00 3.009316e-02 2.956802e-02 -6.000000e+00 9.070880e-01 231.25 -2.00 3.53 -2.00 320.34 0.00e+00 -1.497251e-01 7.259113e-03 6.077964e-04 -6.000000e+00 4.662335e-02 281.90 -2.00 20.00 -2.00 319.30 0.00e+00 9.444 0.016 302.00 328.00 3 7.7722e-01 9.5466e-02 1.5731e-01 -6.0000e+00 2.2940e+00 3.5019e+00 1.0811e-01 2.3716e-01 -6.0000e+00 2.5207e+00 -2.3916e+00 5.6339e-02 3.3114e-02 -6.0000e+00 1.4541e+00 4.4862e-01 3.3296e-02 7.8545e-02 -6.0000e+00 5.9388e-01 2.8153e-06 -8.6068e-03 1.0955e-03 9.5969e-04 -6.0000e+00 4.4995e-02 1.3138e-02 -8.2222e-05 12 8 8 10 0 0 -4.89 26.43 1.52 0.01314 -0.05154 15 1 1 5 0 3723.270 34.50 19.95 26.43 13.64 7.8 973.25 163178 -2883 83036 -21178 -16542 -4724 900000 900000 321444 388693 900000 900000 277061 900000 195777 900000 900000 185982 900000 74720 900000 900000 133444 900000 900000 264664 900000 233870 900000 114219 900000 25038 900000 900000 46327 23407 217551 900000 900000 900000 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900000 19436 900000 900000 900000 34437 20147 18618 900000 900000 13727 900000 900000 -4837 900000 900000 900000 22148 22241 900000 900000 12078 14640 15260 12214 -4606 12840 900000 6812 15465 900000 23410 23398 900000 25554 18179 22697 20691 13673 12879 18029 17642 16081 18166 27328 9677 21988 26796 18987 -31215 8877 19747 -3402 6985 -10164 -4067 -21889 -11288 2295 18323 12567 13246 22023 14728 28252 -23113 -47116 28487 21738 17306 -8985 -29583 -10696 8428 -12995 15277 -10474 -24759 9364 -25927 -20709 -9969 -22005 -11902 404 13087 28397 31891 -85 30279 -8981 SS 20260521T115443.9Z 9637.496341 79 1 55.51 2 76.88 74.44 114.78 19.82 0.00 1 0.00 1 0 25 3.794e-01 1.163e-02 1.314e-01 2.830e-03 6.025155e-01 1.479163e-03 6.928125e-03 -6.000000e+00 2.182842e-01 231.25 -2.00 3.53 -2.00 320.37 0.00e+00 4.045196e-03 5.491482e-04 6.222842e-04 -6.000000e+00 9.506667e-03 281.91 -2.00 20.00 -2.00 319.75 0.00e+00 4.293 0.001 302.00 328.00 3 3.5858e+00 4.4684e-03 5.2724e-02 -6.0000e+00 5.4707e-01 9.2385e-02 5.5565e-03 3.2303e-02 -6.0000e+00 5.9314e-01 -1.1315e-01 5.1476e-03 1.6716e-02 -6.0000e+00 3.5206e-01 4.2119e-02 2.6054e-03 6.5022e-03 -6.0000e+00 1.4842e-01 1.1459e-04 -8.3513e-04 7.7157e-05 6.8235e-05 -6.0000e+00 1.0242e-02 1.1831e-02 -6.2609e-06 12 8 8 10 0 0 99.72 26.42 0.17 0.01183 0.00556 42 4 1 5 0 1321.270 34.50 19.95 26.42 14.29 7.8 980.62 -77387 -170652 -106519 -123901 -144770 -107258 -2602 244880 -39525 -39788 -31207 956 -32585 131629 -38176 -19465 37277 -25088 24953 -49208 9082 41583 -32711 62956 -17300 -29068 -8394 -21987 13773 -23164 -2615 -16456 9778 -580 -20882 -20460 -8849 8744 -2394 -231 15998 6762 -2195 19739 234 -2142 8711 6285 481 15541 3798 -8255 2849 695 3837 9411 1504 -1073 -1173 -4573 3671 4859 2551 5052 3187 -2266 2870 268 1690 590 661 1401 855 -1334 -1271 -2139 -2135 -3691 -786 -773 -1748 -1864 260 -1921 -1314 -218 292 -559 436 735 1384 -240 -25 -553 1187 -374 1083 311 145 589 -225 -1857 -1157 153 -1415 -854 -1340 -855 -865 81 329 71 518 -171 -283 583 553 -186 -788 578 795 801 318 -201 402 993 169 1166 324 448 643 195 -428 110 -219 -474 -76 -291 -168 20 -169 33 -294 -757 -4753 -1604 -2257 -3037 -1599 -15 676 -415 -439 -336 9 -549 545 -1064 -521 628 -866 558 -2418 251 838 -1481 1182 -769 -1516 -354 -1026 456 -1260 -139 -1172 607 -40 -1695 -1717 -755 753 -282 -31 2005 987 -367 2697 40 -380 1416 1082 92 2754 846 -2292 771 207 1160 2785 446 -322 -343 -1384 1191 1580 963 2051 1338 -968 1157 115 806 326 395 855 512 -765 -661 -1010 -955 -1729 -408 -473 -1146 -1381 203 -1626 -1186 -191 267 -527 404 647 1215 -200 -20 -464 1102 -376 1234 376 188 742 -266 -2168 -1245 168 -1694 -1069 -1655 -1126 -1244 120 531 120 859 -273 -425 834 801 -285 -1290 971 1317 1280 495 -302 615 1453 241 1726 506 779 1138 367 -846 215 -460 -1047 -160 -629 -361 44 -347 64 -593 SS 20260521T143403.3Z 9637.606983 171 1 17.49 2 47.69 101.23 98.40 52.90 0.00 1 0.00 1 0 17 7.444e-03 5.487e-03 1.195e-03 7.775e-04 2.226110e-01 4.008162e-04 2.693706e-03 -6.000000e+00 4.285718e-03 231.26 -2.00 3.53 -2.00 315.26 0.00e+00 3.489220e-04 3.581621e-05 2.625198e-05 -6.000000e+00 1.865710e-04 281.92 -2.00 20.00 -2.00 314.65 0.00e+00 1.483 0.000 302.00 328.00 3 3.4256e+00 1.0373e-03 1.8592e-02 -6.0000e+00 1.0741e-02 1.1037e-02 1.1525e-03 1.1586e-02 -6.0000e+00 1.1643e-02 -1.7528e-03 6.5813e-04 5.6347e-03 -6.0000e+00 6.9109e-03 -1.2003e-03 2.9145e-04 1.5649e-03 -6.0000e+00 2.9152e-03 3.1485e-03 1.4893e-04 2.1777e-05 1.9964e-05 -6.0000e+00 2.0093e-04 9.6678e-03 7.4599e-05 12 1 1 12 1 1 99.89 26.39 0.37 0.00967 0.01079 54 16 1 5 0 317.850 34.50 20.06 26.39 16.13 7.8 999.49 -773 -1308 -1915 -2890 -1797 -1565 -139 651 203 -858 -807 -466 -199 587 286 562 387 532 1072 1072 954 978 964 445 279 -7 -67 -346 339 857 993 1415 965 -1068 -1993 -1692 -1270 -176 -108 -526 -567 -507 -583 -1078 -457 -553 -385 -596 -650 520 628 903 922 764 799 964 619 484 399 535 1112 1078 1322 821 -49 -226 -306 16 434 327 337 -84 13 -129 -83 -245 -387 -677 -395 -866 -1029 -1345 -1751 -1214 -910 -679 -450 -75 153 311 335 345 421 634 479 367 595 517 24 -135 -280 -468 -265 -129 -642 -618 -619 -516 -41 101 354 234 267 -54 -24 174 80 178 179 6 130 149 412 381 401 365 573 814 523 455 177 47 -67 -12 -83 -241 -22 55 -205 -301 -329 -334 -475 -241 -400 -616 -836 -501 -440 -39 204 65 -278 -256 -157 -76 235 121 251 177 252 493 508 452 460 472 231 143 -4 -34 -172 166 399 491 746 517 -571 -1052 -914 -728 -106 -74 -379 -434 -385 -452 -840 -353 -423 -298 -447 -478 384 491 718 770 642 686 840 548 423 343 461 959 1004 1276 802 -47 -209 -265 14 403 320 343 -88 14 -129 -81 -223 -334 -586 -350 -805 -1031 -1429 -1908 -1337 -1043 -806 -543 -93 187 373 380 379 437 643 501 411 694 644 30 -171 -341 -543 -304 -150 -794 -780 -794 -673 -55 142 504 334 372 -72 -31 217 100 226 238 8 179 201 556 505 517 462 708 982 654 588 240 63 -92 -17 -120 -355 -33 83 -310 -456 -482 -485 -676 SS 20260521T143847.7Z 9637.610274 175 1 16.12 2 46.84 102.19 97.73 53.74 0.00 1 0.00 1 0 17 7.748e-03 5.557e-03 1.210e-03 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