File name: Pandora240s1_Thessaloniki_20221027_L2Fit_fwvt1c11d20220916p1-8.txt File generation date: 20251121T085127.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v11d20220916.txt Level 1 file used: Pandora240s1_Thessaloniki_20221027_L1_smca1c11d20220916p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20221027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Session 1 and 10 for VP 20220916 First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0696 492.1904 492.3113 492.4321 492.5529 492.6736 492.7944 492.9151 493.0358 493.1565 493.2772 493.3979 493.5186 493.6392 493.7598 493.8804 494.0010 494.1216 494.2421 494.3627 494.4832 494.6037 494.7241 494.8446 494.9651 495.0855 495.2059 495.3263 495.4467 495.5670 495.6874 495.8077 495.9280 496.0483 496.1686 496.2888 496.4090 496.5293 496.6495 496.7696 496.8898 497.0100 497.1301 497.2502 497.3703 497.4904 497.6104 497.7305 497.8505 497.9705 498.0905 498.2105 498.3304 498.4504 498.5703 498.6902 498.8101 498.9300 499.0498 499.1696 499.2895 499.4093 499.5290 499.6488 499.7685 499.8883 500.0080 500.1277 500.2474 500.3670 500.4866 500.6063 500.7259 500.8455 500.9650 501.0846 501.2041 501.3236 501.4431 501.5626 501.6821 501.8015 501.9209 502.0403 502.1597 502.2791 502.3984 502.5178 502.6371 502.7564 502.8757 502.9949 503.1142 503.2334 503.3526 503.4718 503.5910 503.7102 503.8293 503.9484 504.0675 504.1866 504.3057 504.4247 504.5437 504.6628 504.7818 504.9007 505.0197 505.1386 505.2576 505.3765 505.4953 505.6142 505.7331 505.8519 505.9707 506.0895 506.2083 506.3270 506.4458 506.5645 506.6832 506.8019 506.9206 507.0392 507.1578 507.2765 507.3951 507.5136 507.6322 507.7507 507.8693 507.9878 508.1062 508.2247 508.3432 508.4616 508.5800 508.6984 508.8168 508.9351 509.0535 509.1718 509.2901 509.4084 509.5266 509.6449 509.7631 509.8813 509.9995 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221027T055421.4Z 8335.246081 80 1 26.62 2 79.91 116.68 102.36 107.63 0.00 1 0.00 1 0 15 5.177e-03 5.145e-03 1.116e-03 1.114e-03 7.093713e+03 6.800268e+01 5.095779e+02 -6.000000e+00 2.665076e+02 282.79 -2.00 20.00 -2.00 505.25 0.00e+00 1.641144e-03 2.981880e-05 9.597587e-05 -6.000000e+00 1.415059e-04 282.79 -2.00 20.00 -2.00 500.37 0.00e+00 2.803338e-01 2.139301e-02 4.415462e-02 -6.000000e+00 9.910112e-02 224.95 -2.00 3.50 -2.00 501.96 0.00e+00 5.464 0.003 489.00 513.00 1 5.9773e+00 1.6310e-03 8.9595e-03 -6.0000e+00 7.5607e-03 -3.9151e-03 4.3193e-04 1.1667e-03 -6.0000e+00 2.0211e-03 2.1668e-03 -3.2007e-04 7.3739e-05 5.4206e-05 -6.0000e+00 3.5901e-04 -9.2716e-03 7.2786e-05 12 9 9 12 1 1 -2.52 24.03 1.66 -0.00927 -0.01149 13 4 1 2 0 1660.174 20.00 24.03 23.73 27.75 28.00 10.2 987.05 -1053 -909 -360 -172 204 548 756 1278 740 953 393 387 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742 746 622 431 -100 -552 -1080 -1106 -925 -641 289 -8 95 24 -563 -526 -499 -83 -155 91 367 333 614 812 1091 485 449 298 76 75 317 183 134 586 243 353 598 -67 4 -149 -454 -889 -478 -57 78 56 188 50 112 499 572 490 569 176 -483 -659 -843 900000 SQ 20221027T060314.8Z 8335.252254 84 1 5.94 2 78.41 118.27 100.84 108.95 0.00 1 0.00 1 0 15 4.871e-03 4.808e-03 1.922e-04 1.918e-04 6.730950e+03 1.164775e+01 4.888726e+02 -6.000000e+00 2.507013e+02 282.79 -2.00 20.00 -2.00 505.26 0.00e+00 1.573614e-03 5.136151e-06 9.170554e-05 -6.000000e+00 1.331270e-04 282.79 -2.00 20.00 -2.00 500.41 0.00e+00 2.290507e-01 3.673709e-03 4.172887e-02 -6.000000e+00 9.323989e-02 224.95 -2.00 3.50 -2.00 502.00 0.00e+00 4.816 0.002 489.00 513.00 1 1.2247e+00 2.8008e-04 8.0486e-03 -6.0000e+00 7.1132e-03 -1.3579e-02 7.4065e-05 1.1006e-03 -6.0000e+00 1.9019e-03 2.7678e-01 -2.7718e-04 1.2730e-05 5.2712e-05 -6.0000e+00 3.3775e-04 2.3012e-03 -8.9649e-06 12 8 8 10 0 0 -0.69 24.04 1.72 0.00230 0.00038 515 56 1 2 0 11.183 20.00 24.04 23.85 28.00 28.25 10.3 988.62 -1007 -886 -121 -77 279 580 831 733 790 635 595 334 -224 -178 -372 -368 -333 18 184 164 266 128 77 362 333 524 636 565 -423 -392 -742 -814 -960 183 130 171 139 -59 -281 -394 -220 -192 131 318 498 380 646 404 505 -195 -536 -935 -1095 -1019 -562 -214 -72 47 64 13 -44 463 280 558 288 128 189 -24 -279 -610 -452 -317 -307 96 167 25 -138 -314 -509 -815 -493 -263 -424 -342 1 -13 -148 -172 -262 -94 -202 331 648 574 809 553 479 124 -611 -1091 -1204 -1049 -895 158 37 114 42 -497 -603 -374 -149 -254 108 399 338 556 764 921 441 534 294 75 59 495 83 173 462 329 427 800 15 -79 -74 -420 -1063 -473 -194 -101 29 246 27 216 331 479 580 559 203 -529 -622 -758 900000 -990 -859 -121 -79 290 596 873 778 836 659 609 340 -231 -179 -376 -375 -343 18 191 171 276 133 80 376 352 551 665 590 -433 -388 -734 -814 -969 187 136 178 146 -62 -291 -402 -225 -199 137 328 518 399 670 414 510 -199 -540 -923 -1068 -1000 -555 -219 -74 49 66 13 -45 475 290 576 296 129 188 -25 -281 -601 -439 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3.3640e-04 1.8439e-03 -5.1979e-06 12 8 8 10 0 0 -4.18 24.04 1.72 0.00184 -0.00018 515 56 1 2 0 11.183 20.00 24.04 23.85 28.00 28.25 10.3 988.62 -1020 -879 -158 -95 262 616 838 693 775 601 577 389 -275 -197 -374 -356 -328 6 190 100 292 169 75 358 357 517 629 607 -453 -384 -755 -813 -922 152 159 173 138 -77 -281 -415 -195 -153 144 327 484 350 672 462 488 -223 -506 -853 -1076 -994 -637 -261 -63 71 10 -15 -32 460 323 527 325 72 147 6 -263 -630 -416 -328 -322 130 132 7 -118 -232 -532 -800 -491 -357 -376 -281 -25 12 -160 -183 -200 -87 -237 348 658 607 817 553 500 136 -605 -1119 -1188 -995 -842 171 2 116 32 -489 -639 -379 -153 -276 92 371 366 532 736 902 452 586 274 71 66 505 157 190 499 302 393 768 78 -136 -116 -431 -1072 -465 -175 -83 63 203 61 215 316 521 611 528 157 -527 -610 -759 900000 -989 -865 -156 -99 268 639 890 723 805 630 596 400 -279 -201 -372 -357 -332 6 199 106 305 179 79 376 381 549 665 641 -468 -384 -755 -823 -941 157 168 182 143 -79 -293 -428 -202 -160 148 339 509 370 702 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