File name: Pandora240s1_Thessaloniki_20221107_L2Fit_fout2c11d20220916p1-8.txt File generation date: 20251121T085324.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v11d20220916.txt Level 1 file used: Pandora240s1_Thessaloniki_20221107_L1_smca1c11d20220916p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20221107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Session 1 and 10 for VP 20220916 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0504 305.1926 305.3347 305.4768 305.6189 305.7609 305.9029 306.0449 306.1869 306.3288 306.4707 306.6125 306.7544 306.8962 307.0380 307.1797 307.3215 307.4632 307.6048 307.7465 307.8881 308.0297 308.1712 308.3128 308.4543 308.5958 308.7372 308.8787 309.0201 309.1615 309.3028 309.4442 309.5855 309.7268 309.8680 310.0093 310.1505 310.2917 310.4329 310.5740 310.7151 310.8562 310.9973 311.1384 311.2794 311.4204 311.5614 311.7024 311.8433 311.9842 312.1251 312.2660 312.4069 312.5477 312.6885 312.8293 312.9701 313.1108 313.2516 313.3923 313.5330 313.6736 313.8143 313.9549 314.0955 314.2361 314.3767 314.5172 314.6578 314.7983 314.9388 315.0793 315.2197 315.3602 315.5006 315.6410 315.7814 315.9218 316.0621 316.2024 316.3427 316.4830 316.6233 316.7636 316.9038 317.0440 317.1843 317.3244 317.4646 317.6048 317.7449 317.8850 318.0252 318.1652 318.3053 318.4454 318.5854 318.7254 318.8655 319.0054 319.1454 319.2854 319.4253 319.5653 319.7052 319.8451 319.9850 320.1248 320.2647 320.4045 320.5443 320.6841 320.8239 320.9637 321.1035 321.2432 321.3829 321.5227 321.6624 321.8021 321.9417 322.0814 322.2210 322.3607 322.5003 322.6399 322.7795 322.9190 323.0586 323.1982 323.3377 323.4772 323.6167 323.7562 323.8957 324.0351 324.1746 324.3140 324.4534 324.5929 324.7323 324.8716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given 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583 2011 2580 1027 1774 867 872 88 -308 -1310 272 -2208 -1901 -2241 416 207 -1353 -1995 469 -1798 1388 1691 1232 -79 -993 1102 -1456 -1240 -557 566 410 -1926 1744 -2029 985 -958 34 421 -2071 -2433 -1522 -857 -2206 1535 2213 -576 -302 -296 -331 -646 -42 -239 1028 1056 603 2151 337 12 1797 983 -23 3456 148 -1465 -345 -1735 81 305 -215 163 617 1422 -260 -400 64 -2639 SS 20221107T062113.2Z 8346.264736 257 1 54.35 2 78.05 124.01 115.40 311.10 0.00 1 0.00 1 0 17 3.556e-01 1.059e-02 2.961e-01 7.416e-03 6.112873e-01 4.073128e-03 6.960733e-03 -6.000000e+00 2.065123e-01 223.99 -2.00 3.50 -2.00 321.01 0.00e+00 5.190137e-03 1.872408e-03 1.197091e-03 -6.000000e+00 9.459034e-03 281.43 -2.00 20.00 -2.00 320.48 0.00e+00 4.682 0.002 302.00 328.00 3 2.8210e+00 1.3539e-02 5.7185e-02 -6.0000e+00 5.1217e-01 2.5569e-02 1.8615e-02 3.5742e-02 -6.0000e+00 5.5848e-01 -6.6951e-02 1.9276e-02 1.8189e-02 -6.0000e+00 3.3010e-01 1.0184e-02 9.2955e-03 1.0219e-02 -6.0000e+00 1.4289e-01 1.6119e-04 -8.4044e-04 2.1382e-04 7.9969e-05 -6.0000e+00 9.6265e-03 1.3088e-03 0.0000e+00 12 8 8 10 0 0 -5.85 23.70 1.38 0.00131 -0.00501 56 6 1 8 0 970.093 20.00 23.70 21.25 27.75 28.00 11.1 979.75 900000 52134 900000 -140029 -118505 -169337 900000 -194490 900000 -89095 94431 -123316 41430 900000 3786 -41565 -20714 900000 900000 25652 -20427 12007 -68463 15976 13838 -48118 -19277 106460 7899 2955 -4910 -16105 2712 -1164 24552 -570 -4185 4461 -27324 5361 -4453 -881 5881 -570 -8809 -1841 279 -1767 2356 11885 -6113 2063 11642 9748 2459 -6131 5144 582 439 8907 -4534 882 1853 3074 -414 2531 2475 2039 198 5091 -697 1061 930 3557 1808 -3619 -456 1017 -3206 -5579 -1294 -1865 -755 -448 -1507 -2138 1511 -378 2672 1224 1535 1196 -395 1517 -520 -1504 1324 607 164 -41 -573 -727 -230 2133 -1425 -1749 -69 -1327 208 -151 -164 -888 -345 444 -861 783 779 -755 509 -576 172 1128 1906 -548 -45 -456 16 917 -80 97 -77 633 -994 287 62 245 395 269 -210 -492 403 -952 900000 376 900000 -1264 -856 -1834 900000 -3277 900000 -643 682 -1484 299 900000 30 -628 -286 900000 900000 286 -375 158 -2112 231 218 -1485 -456 769 140 60 -132 -571 93 -44 745 -23 -193 225 -2328 391 -399 -81 539 -57 -980 -198 30 -203 272 1339 -927 322 1791 1668 472 -1333 1025 120 88 1646 -1012 209 494 908 -130 738 729 623 70 1967 -306 473 403 1410 662 -1257 -148 336 -1276 -2707 -691 -1141 -490 -306 -1124 -1699 1214 -314 2140 944 1093 808 -263 1051 -420 -1421 1266 666 191 -47 -602 -683 -222 1930 -1446 -1849 -77 -1604 273 -223 -264 -1483 -563 685 -1267 1101 1129 -1167 829 -973 282 1755 2868 -807 -64 -627 21 1321 -133 163 -141 1202 -2019 613 142 582 951 661 -512 -1135 875 -1981 SS 20221107T062607.8Z 8346.268146 259 1 54.16 2 77.28 124.92 116.05 312.16 0.00 1 0.00 1 0 25 2.711e-01 8.863e-03 2.442e-01 5.482e-03 5.785697e-01 2.916221e-03 6.693991e-03 -6.000000e+00 1.559135e-01 223.99 -2.00 3.50 -2.00 320.75 0.00e+00 4.626734e-03 1.252860e-03 4.045638e-04 -6.000000e+00 7.061942e-03 281.43 -2.00 20.00 -2.00 320.20 0.00e+00 4.420 0.002 302.00 328.00 3 2.6408e+00 9.3353e-03 5.3186e-02 -6.0000e+00 3.8623e-01 2.1424e-02 1.2446e-02 3.1118e-02 -6.0000e+00 4.2019e-01 -6.6670e-02 1.2550e-02 1.7135e-02 -6.0000e+00 2.4821e-01 1.3300e-02 6.1717e-03 8.0698e-03 -6.0000e+00 1.0863e-01 2.5584e-04 -1.1468e-03 1.5578e-04 7.3178e-05 -6.0000e+00 7.3689e-03 1.3625e-03 0.0000e+00 11 8 0 10 0 0 -14.98 23.71 1.14 0.00136 -0.00725 74 8 1 8 0 731.519 20.00 23.71 21.69 27.75 28.00 11.1 982.25 900000 900000 -146190 -19896 51296 -148850 55735 900000 900000 -37011 -58395 -116537 71906 96577 -32470 7166 -14365 36834 -6399 15222 -29078 -26727 38204 33612 -40680 -19487 -26590 -35076 -23555 -21908 -12815 2725 13249 -14732 17260 -1445 -6012 -15829 -8659 -3240 7277 1921 2432 -3995 688 -4705 966 -2825 1687 1696 5228 4208 7109 5396 1380 1750 -2503 2141 -928 -775 5464 -418 1507 4526 1597 983 -141 -712 3369 2070 -671 -29 878 2136 131 214 -1039 -3721 -1675 -1936 -2101 -2323 -2591 -1851 443 68 1157 664 663 -137 1178 1179 638 1563 473 -781 814 1527 -324 -770 512 -1621 -252 268 -2417 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