File name: Pandora240s1_Thessaloniki_20230223_L2Fit_fout2c10d20221220p1-8.txt File generation date: 20251121T091428.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v10d20221220.txt Level 1 file used: Pandora240s1_Thessaloniki_20230223_L1_smca1c10d20221220p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20230223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Session 1 for testing the CF, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.1067 305.2476 305.3886 305.5295 305.6704 305.8113 305.9522 306.0931 306.2340 306.3748 306.5157 306.6565 306.7974 306.9382 307.0790 307.2198 307.3606 307.5014 307.6422 307.7829 307.9237 308.0644 308.2051 308.3458 308.4865 308.6272 308.7679 308.9086 309.0492 309.1899 309.3305 309.4712 309.6118 309.7524 309.8930 310.0336 310.1741 310.3147 310.4552 310.5958 310.7363 310.8768 311.0173 311.1578 311.2983 311.4388 311.5793 311.7197 311.8602 312.0006 312.1410 312.2814 312.4218 312.5622 312.7026 312.8429 312.9833 313.1236 313.2640 313.4043 313.5446 313.6849 313.8252 313.9655 314.1057 314.2460 314.3862 314.5265 314.6667 314.8069 314.9471 315.0873 315.2275 315.3676 315.5078 315.6479 315.7881 315.9282 316.0683 316.2084 316.3485 316.4886 316.6286 316.7687 316.9087 317.0488 317.1888 317.3288 317.4688 317.6088 317.7487 317.8887 318.0287 318.1686 318.3085 318.4485 318.5884 318.7283 318.8682 319.0080 319.1479 319.2878 319.4276 319.5674 319.7073 319.8471 319.9869 320.1266 320.2664 320.4062 320.5459 320.6857 320.8254 320.9651 321.1048 321.2445 321.3842 321.5239 321.6636 321.8032 321.9428 322.0825 322.2221 322.3617 322.5013 322.6409 322.7805 322.9200 323.0596 323.1991 323.3386 323.4781 323.6176 323.7571 323.8966 324.0361 324.1755 324.3150 324.4544 324.5939 324.7333 324.8727 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230223T075215.5Z 8454.327957 134 1 54.37 2 63.84 132.34 81.39 92.15 0.00 1 0.00 1 0 17 2.898e-02 8.170e-03 2.743e-02 4.558e-03 3.195582e-01 2.291620e-03 3.807700e-03 -6.000000e+00 1.654932e-02 225.25 -2.00 3.50 -2.00 318.33 0.00e+00 4.530313e-04 4.381808e-04 3.027610e-04 -6.000000e+00 7.185721e-04 275.69 -2.00 20.00 -2.00 317.76 0.00e+00 2.255 0.000 302.00 328.00 3 4.9352e+00 6.1411e-03 2.7645e-02 -6.0000e+00 4.1003e-02 4.7311e-02 6.9845e-03 1.6267e-02 -6.0000e+00 4.4510e-02 -1.1070e-02 4.8059e-03 8.1668e-03 -6.0000e+00 2.6433e-02 -5.2770e-03 2.5363e-03 2.4079e-03 -6.0000e+00 1.1411e-02 2.6947e-04 -4.2068e-04 1.2833e-04 2.4318e-05 -6.0000e+00 7.6641e-04 -5.6797e-04 0.0000e+00 11 8 0 10 0 0 99.95 23.51 0.96 -0.00057 -0.00373 41 4 1 8 0 1325.595 20.00 23.51 20.49 27.75 27.75 17.9 1036.38 3301 2319 -15934 -2260 -8603 -3487 -10330 3082 -5953 -8865 5812 -7047 -7268 5583 -1467 2911 7356 -2579 2665 6541 -1024 -2764 -572 -1537 -4543 266 -3634 -4112 -3213 2204 1376 4214 1457 1587 -3293 1114 -1485 -3286 2227 -2714 -1308 -503 77 -2024 2722 -2288 -2924 420 -1742 -725 1913 1863 599 3388 641 1851 2064 1028 670 -78 933 572 245 703 -408 22 1082 356 3060 30 522 541 -903 766 423 41 -12 -2001 419 -294 -1121 -462 -3635 -973 -256 -1338 -259 121 171 -1 -150 756 508 1017 374 -305 533 351 -621 -220 156 -766 -138 812 -1477 -1319 -27 -891 -40 399 145 141 56 104 64 -285 327 267 619 -10 -97 1138 591 -576 1627 668 -86 505 437 -92 -835 -487 -98 116 -791 384 -48 331 -67 251 66 -1087 163 123 -1036 -117 -428 -165 -568 168 -392 -627 350 -521 -628 492 -160 334 838 -345 350 861 -162 -439 -93 -270 -864 50 -696 -738 -545 361 251 807 317 346 -691 231 -354 -943 729 -1074 -548 -218 34 -917 1178 -1044 -1313 181 -760 -322 894 936 321 1877 373 1092 1235 612 392 -46 570 383 178 543 -310 15 713 234 2182 25 462 494 -817 649 329 29 -8 -1292 291 -235 -1006 -457 -3545 -970 -275 -1536 -309 147 204 -1 -155 789 493 994 403 -335 645 472 -872 -294 194 -877 -151 943 -1902 -1755 -38 -1307 -62 661 233 225 93 159 91 -389 455 389 971 -15 -146 1807 921 -858 2270 899 -111 683 643 -133 -1284 -759 -158 195 -1429 712 -92 640 -128 461 117 -1872 SS 20230223T080932.7Z 8454.339961 144 1 36.74 2 61.49 136.34 78.16 94.86 0.00 1 0.00 1 0 17 2.729e-02 8.306e-03 1.875e-02 4.519e-03 2.919272e-01 2.292641e-03 3.535591e-03 -6.000000e+00 1.557430e-02 225.25 -2.00 3.50 -2.00 317.72 0.00e+00 1.930993e-04 3.657443e-04 2.423679e-04 -6.000000e+00 6.764327e-04 275.69 -2.00 20.00 -2.00 317.15 0.00e+00 2.085 0.000 302.00 328.00 3 5.0365e+00 6.0434e-03 2.5478e-02 -6.0000e+00 3.8587e-02 3.5009e-02 6.8071e-03 1.4904e-02 -6.0000e+00 4.1892e-02 -1.3830e-02 4.3305e-03 7.4305e-03 -6.0000e+00 2.4878e-02 3.4333e-04 2.2364e-03 2.1499e-03 -6.0000e+00 1.0736e-02 3.0179e-04 -2.0837e-04 1.2662e-04 2.2404e-05 -6.0000e+00 7.2164e-04 1.4575e-03 0.0000e+00 12 9 1 12 1 1 99.99 23.53 0.70 0.00146 -0.00011 21 4 1 8 0 1528.019 20.00 23.53 21.92 27.75 27.75 18.1 1044.20 -2794 -11306 1704 -4157 -5334 -7522 -8938 -14907 -4994 -11059 -6296 -5192 4683 -5186 1248 -4694 2935 922 3254 -373 3132 -1340 -93 4 -3092 758 -1469 1244 1928 -954 277 2430 3068 -1136 -426 -443 1683 -343 1235 205 -3005 628 529 491 1405 -3197 -1404 130 -948 -101 1877 571 1644 2699 -161 1791 362 -313 -175 -432 1726 2048 2137 809 -275 -839 528 -1688 1553 693 206 640 -62 507 -513 -485 1086 -1154 -1244 -1118 -1833 -1833 -2705 -463 -898 -1357 416 -650 -6 560 606 423 328 627 919 662 716 445 43 -165 -531 -1286 -441 45 -202 -1928 -332 -782 843 320 548 -158 207 639 68 477 589 -508 195 282 433 417 471 -224 855 718 489 702 -157 -210 -595 -843 -121 30 -293 175 489 -83 -109 110 324 -1188 -218 -1014 137 -320 -374 -539 -705 -1415 -472 -1152 -613 -537 557 -710 183 -797 524 178 631 -78 639 -282 -20 1 -774 188 -365 279 409 -211 66 609 839 -323 -110 -119 494 -122 518 99 -1465 307 266 246 769 -1665 -769 69 -504 -54 1071 321 963 1655 -103 1158 241 -207 -113 -280 1148 1478 1663 677 -225 -628 374 -1212 1202 613 195 622 -59 459 -430 -361 739 -784 -929 -950 -1743 -1926 -2757 -485 -1023 -1647 520 -836 -8 665 659 462 331 639 1019 750 899 620 57 -228 -685 -1529 -504 55 -268 -2691 -446 -1099 1239 507 905 -261 323 920 90 658 768 -702 289 439 671 631 695 -314 1137 913 641 893 -217 -311 -929 -1338 -182 47 -495 305 865 -151 -197 191 541 -1932 SS 20230223T081455.3Z 8454.343696 147 1 43.67 2 60.79 137.62 77.16 95.71 0.00 1 0.00 1 0 17 2.407e-02 8.107e-03 1.982e-02 4.559e-03 2.862804e-01 2.290888e-03 3.420078e-03 -6.000000e+00 1.373968e-02 225.25 -2.00 3.50 -2.00 317.71 0.00e+00 1.131661e-03 3.667020e-04 9.571559e-05 -6.000000e+00 5.966367e-04 275.69 -2.00 20.00 -2.00 317.14 0.00e+00 2.040 0.000 302.00 328.00 3 5.1510e+00 6.0522e-03 2.4900e-02 -6.0000e+00 3.4042e-02 4.2261e-02 6.8157e-03 1.4575e-02 -6.0000e+00 3.6955e-02 -9.8509e-03 4.3588e-03 7.2351e-03 -6.0000e+00 2.1946e-02 -3.3675e-03 2.2683e-03 2.2953e-03 -6.0000e+00 9.4732e-03 2.8114e-04 -3.6900e-04 1.2769e-04 2.2699e-05 -6.0000e+00 6.3641e-04 8.3746e-05 0.0000e+00 12 9 1 12 1 1 99.98 23.53 1.11 0.00008 -0.00269 21 3 1 8 0 1816.831 20.00 23.53 22.36 27.75 27.75 18.1 1046.86 7787 605 -4731 9632 7569 -9501 -9396 1101 -2416 -725 -3309 -2550 8268 -2636 3499 -648 -2103 -2001 -1564 -1208 635 1659 2503 4221 -3342 2035 -357 -3505 2395 4678 3679 2943 1770 -3261 -2325 1535 -4225 -1065 -1818 -165 -358 -1756 159 -2533 -637 1547 -2047 -1682 -1595 183 2498 -72 2128 3103 989 541 298 791 700 -366 466 1379 1708 663 250 -1091 -384 -1271 675 1210 58 1433 -1635 592 382 -1010 664 -1711 627 -641 -1706 -1470 -1488 -1075 -853 -192 1124 -850 397 135 1799 614 282 185 423 467 473 813 -488 26 267 -760 106 702 -1430 -1046 -407 -646 -340 120 555 -853 764 -378 506 253 181 0 372 -184 -595 1285 418 -785 1069 297 364 870 -182 -85 -408 -468 -422 317 35 159 296 -63 -68 -31 54 -611 554 49 -411 658 474 -703 -748 89 -222 -68 -310 -255 859 -351 503 -106 -360 -398 -320 -256 134 339 528 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