File name: Pandora240s1_Thessaloniki_20230706_L2Fit_fout2c8d20220916p1-8.txt File generation date: 20230709T000858.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v8d20220916.txt Level 1 file used: Pandora240s1_Thessaloniki_20230706_L1_smca1c8d20220916p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20230706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0949 305.2358 305.3768 305.5177 305.6586 305.7995 305.9404 306.0813 306.2221 306.3630 306.5039 306.6447 306.7855 306.9264 307.0672 307.2080 307.3488 307.4895 307.6303 307.7711 307.9118 308.0526 308.1933 308.3340 308.4748 308.6155 308.7562 308.8968 309.0375 309.1782 309.3188 309.4595 309.6001 309.7407 309.8813 310.0219 310.1625 310.3031 310.4437 310.5842 310.7248 310.8653 311.0058 311.1464 311.2869 311.4274 311.5679 311.7083 311.8488 311.9892 312.1297 312.2701 312.4105 312.5510 312.6914 312.8317 312.9721 313.1125 313.2528 313.3932 313.5335 313.6739 313.8142 313.9545 314.0948 314.2350 314.3753 314.5156 314.6558 314.7961 314.9363 315.0765 315.2167 315.3569 315.4971 315.6373 315.7774 315.9176 316.0577 316.1978 316.3380 316.4781 316.6182 316.7582 316.8983 317.0384 317.1784 317.3185 317.4585 317.5985 317.7385 317.8785 318.0185 318.1585 318.2984 318.4384 318.5783 318.7182 318.8582 318.9981 319.1380 319.2778 319.4177 319.5576 319.6974 319.8373 319.9771 320.1169 320.2567 320.3965 320.5363 320.6760 320.8158 320.9555 321.0953 321.2350 321.3747 321.5144 321.6541 321.7938 321.9335 322.0731 322.2128 322.3524 322.4920 322.6316 322.7712 322.9108 323.0504 323.1899 323.3295 323.4690 323.6086 323.7481 323.8876 324.0271 324.1666 324.3060 324.4455 324.5849 324.7244 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230706T051028.4Z 8587.215606 227 1 54.11 2 68.56 77.91 81.11 234.95 0.00 1 0.00 1 0 17 3.808e-02 7.889e-03 7.522e-03 7.670e-04 4.001043e-01 4.091218e-04 4.700948e-03 -6.000000e+00 2.311290e-02 232.86 -2.00 3.50 -2.00 318.85 0.00e+00 1.380485e-03 9.511885e-05 1.886899e-04 -6.000000e+00 1.041030e-03 288.56 -2.00 20.00 -2.00 318.06 0.00e+00 2.710 0.000 302.00 328.00 3 1.4314e+00 1.1329e-03 3.4523e-02 -6.0000e+00 5.8048e-02 3.5490e-03 1.3047e-03 2.1278e-02 -6.0000e+00 6.2469e-02 -2.1337e-02 9.2484e-04 1.0398e-02 -6.0000e+00 3.7148e-02 1.7349e-04 4.8540e-04 3.1319e-03 -6.0000e+00 1.5801e-02 5.1744e-03 -6.1477e-04 2.2540e-05 3.2380e-05 -6.0000e+00 1.1003e-03 7.8151e-03 -9.8153e-05 11 8 0 10 0 0 0.34 23.74 0.89 0.00782 0.00320 573 62 1 8 0 94.073 20.01 23.74 30.82 27.75 28.00 23.5 1019.37 -13712 -14053 -11017 -15225 -10171 -13414 -11249 -11802 -11689 -11507 -11147 -7849 -4478 -4960 -2079 -2990 259 263 -631 253 -1497 -1362 1452 -2565 -2162 -2670 -3543 -3052 685 1323 978 86 218 -2681 -1989 1021 602 654 118 -1998 -1409 -843 -824 -1424 169 -549 -376 962 6 1507 1878 776 1217 905 435 1146 190 -8 848 1447 2050 1808 1175 418 -591 1212 1408 1249 2548 302 -797 -530 -1254 -153 -156 409 995 237 1066 -878 -1261 -1480 -2378 -1061 -796 -1223 -345 -692 -408 -60 726 1150 1414 1835 1431 684 155 -304 -1115 -644 -92 -181 1002 690 -1302 -1113 -662 -750 284 -44 -195 -679 238 425 1129 1523 1297 432 -266 -613 -658 -167 69 -416 1116 483 1215 1110 48 -247 -331 -451 -207 588 -296 -258 75 -371 -455 11 439 -262 -398 -444 -350 -474 -279 -383 -341 -407 -444 -461 -454 -343 -246 -326 -155 -252 22 25 -62 26 -160 -145 158 -311 -276 -354 -471 -385 82 163 135 13 37 -479 -335 173 115 148 32 -640 -487 -305 -309 -493 64 -211 -143 365 2 599 808 332 553 439 219 590 100 -4 434 742 1096 1059 756 290 -410 774 877 789 1764 222 -630 -431 -1004 -116 -118 277 630 151 746 -658 -1065 -1392 -2399 -1116 -831 -1360 -399 -815 -475 -66 795 1166 1350 1790 1544 769 196 -396 -1525 -846 -122 -218 1151 842 -1625 -1441 -905 -1080 436 -69 -321 -1125 377 630 1661 2153 1885 663 -411 -989 -1056 -259 105 -601 1635 683 1641 1586 71 -393 -562 -738 -351 1042 -531 -481 142 -720 -875 20 820 -472 SS 20230706T051812.3Z 8587.220975 231 1 54.14 2 67.12 79.05 82.25 236.31 0.00 1 0.00 1 0 17 2.709e-02 7.900e-03 5.130e-03 6.294e-04 3.763956e-01 3.346877e-04 4.444871e-03 -6.000000e+00 1.644140e-02 232.86 -2.00 3.50 -2.00 318.62 0.00e+00 1.392482e-03 7.294940e-05 1.454323e-04 -6.000000e+00 7.405362e-04 288.56 -2.00 20.00 -2.00 317.83 0.00e+00 2.551 0.000 302.00 328.00 3 1.2333e+00 9.1879e-04 3.2514e-02 -6.0000e+00 4.1292e-02 -7.7085e-04 1.0503e-03 2.0053e-02 -6.0000e+00 4.4438e-02 -1.6714e-02 7.2067e-04 9.7633e-03 -6.0000e+00 2.6425e-02 -1.0733e-03 3.7692e-04 2.9579e-03 -6.0000e+00 1.1240e-02 7.5895e-03 -5.6746e-04 1.8576e-05 3.1519e-05 -6.0000e+00 7.8272e-04 7.6684e-03 -1.0173e-04 11 8 0 10 0 0 -0.98 23.75 0.89 0.00767 0.00340 791 86 1 8 0 68.087 20.00 23.75 31.28 28.00 28.00 23.5 1022.10 -9712 -10421 -8313 -12138 -7824 -7774 -7958 -7296 -8874 -4918 -7615 -4234 -3065 -2747 290 -1240 -1479 -213 -901 -119 -422 872 635 -535 -617 -2919 -3112 -2336 774 1128 1814 -235 -561 -2762 -1465 272 -709 1273 -1 -1442 -2218 -1205 -688 -1203 -138 -323 -284 756 34 1217 1466 814 1176 684 250 1048 261 269 761 1325 1952 1728 1096 403 -500 1175 1365 852 2623 464 -849 -530 -1186 -123 -311 678 844 488 1036 -861 -1268 -1406 -2383 -1042 -674 -1327 -339 -566 -391 -240 758 1023 1435 1890 1385 662 160 -173 -1169 -684 47 -225 1074 799 -1329 -1006 -687 -778 212 -108 -182 -697 378 398 1040 1591 1213 435 -207 -719 -632 -262 121 -291 1022 522 1281 1228 115 -247 -326 -319 -155 474 -305 -284 94 -390 -381 -53 383 -267 -343 -401 -323 -460 -263 -262 -291 -299 -406 -228 -405 -240 -202 -213 25 -123 -155 -24 -106 -15 -52 107 82 -74 -90 -452 -479 -339 106 160 284 -41 -109 -557 -276 52 -154 321 0 -513 -783 -442 -260 -461 -53 -125 -109 287 15 529 626 378 578 359 135 581 149 152 419 733 1124 1088 756 299 -369 796 898 568 1907 357 -705 -452 -996 -97 -247 482 562 324 755 -670 -1110 -1366 -2481 -1043 -725 -1524 -404 -688 -470 -273 791 1070 1406 1884 1406 757 205 -229 -1618 -909 58 -275 1251 990 -1686 -1322 -954 -1137 306 -169 -301 -1159 598 590 1527 2239 1757 621 -319 -1159 -1016 -409 183 -421 1499 737 1726 1747 168 -390 -511 -514 -258 826 -538 -521 174 -745 -721 -95 665 -477 SS 20230706T052415.6Z 8587.225180 234 1 54.12 2 65.99 79.95 83.16 237.36 0.00 1 0.00 1 0 17 2.451e-02 7.963e-03 4.004e-03 5.668e-04 3.611265e-01 3.022122e-04 4.283977e-03 -6.000000e+00 1.487258e-02 232.86 -2.00 3.50 -2.00 318.44 0.00e+00 9.941449e-04 6.250891e-05 1.646373e-04 -6.000000e+00 6.698905e-04 288.56 -2.00 20.00 -2.00 317.65 0.00e+00 2.440 0.000 302.00 328.00 3 1.1845e+00 8.2408e-04 3.1131e-02 -6.0000e+00 3.7352e-02 -1.8194e-03 9.3723e-04 1.9199e-02 -6.0000e+00 4.0197e-02 -1.6532e-02 6.2747e-04 9.3410e-03 -6.0000e+00 2.3904e-02 -5.2014e-04 3.2723e-04 2.6813e-03 -6.0000e+00 1.0168e-02 9.0727e-03 -6.0412e-04 1.6778e-05 2.9307e-05 -6.0000e+00 7.0806e-04 7.6593e-03 -1.0473e-04 11 8 0 10 0 0 7.49 23.76 0.82 0.00766 0.00312 880 96 1 8 0 61.150 20.00 23.76 31.71 28.00 28.00 23.6 1024.29 -7396 -8253 -7445 -9804 -9756 -5644 -6556 -7197 -6415 -9077 -5980 -3879 -2434 -1627 -1920 -2149 -335 -30 -749 -325 304 546 183 409 -867 -1545 -2877 -2188 699 955 1686 562 196 -2886 -1384 996 -486 387 48 -1630 -1928 -797 -606 -1295 83 -530 -266 460 283 1210 1675 751 1142 892 194 1008 100 305 686 1353 1881 1781 930 231 -783 1181 1376 1054 2517 222 -781 -635 -1138 -88 -219 657 1141 564 1035 -816 -1160 -1645 -2300 -1073 -823 -1223 -288 -734 -454 -246 663 1174 1433 2009 1333 605 162 -265 -1201 -707 48 -368 1146 711 -1193 -1075 -577 -785 146 -124 -198 -620 357 411 1115 1606 1301 473 -126 -651 -571 -109 154 -365 1076 493 1261 1229 81 -189 -330 -325 -119 503 -332 -291 26 -351 -443 -71 318 -244 -303 -367 -338 -427 -392 -218 -277 -345 -336 -513 -365 -254 -184 -143 -195 -243 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