File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20250911_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260424T062301.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20250911_L1_smca1c3d20250801p1-8.txt Full location name: Istituto di Metodologie per l'Analisi Ambientale (IMAA), CNR, Tito Scalo (PZ) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20250911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250911T062911.0Z 9385.270266 246 1 11.92 2 69.12 102.60 65.36 271.44 0.00 1 0.00 1 0 25 1.668e-02 8.119e-03 1.828e-03 5.507e-04 3.766881e-01 3.014044e-04 4.434942e-03 -6.000000e+00 1.039006e-02 229.13 -2.00 3.48 -2.00 317.33 0.00e+00 2.669573e-04 4.464035e-05 9.174660e-05 -6.000000e+00 4.633908e-04 284.38 -2.00 20.00 -2.00 316.57 0.00e+00 2.778 0.000 302.00 328.00 3 1.1140e+00 7.9494e-04 3.1957e-02 -6.0000e+00 2.5853e-02 3.3188e-02 8.9115e-04 1.9216e-02 -6.0000e+00 2.7956e-02 -2.3492e-02 5.2973e-04 9.3804e-03 -6.0000e+00 1.6656e-02 4.2882e-03 2.5385e-04 2.6068e-03 -6.0000e+00 6.9194e-03 8.4940e-03 -8.2296e-05 1.7815e-05 3.4666e-05 -6.0000e+00 5.3416e-04 1.7976e-03 0.0000e+00 12 9 1 12 1 1 97.92 24.01 0.34 0.00180 0.00118 206 99 4 8 0 57.510 19.99 24.01 24.79 33.75 33.50 3.0 966.38 -5274 -5231 -4223 -7480 -6149 -5421 -4113 -3265 -1686 -3282 -5277 -3432 -1029 -1680 13 505 -554 837 640 1283 1119 260 789 925 -126 -121 -382 -1107 -177 555 1370 -471 773 -569 -3193 -556 -777 -103 -80 -474 -1049 -1189 -288 -446 -194 565 -218 460 584 635 1715 1158 862 1243 217 593 996 664 928 1320 1195 1124 651 947 544 -697 1205 507 1103 1379 -595 -702 -1145 -613 59 -58 872 334 427 89 -1475 -1350 -1880 -2218 -1069 -1102 -940 -664 -521 -128 45 1403 1050 1619 1769 944 -227 -409 -663 -1204 -452 -253 -253 404 609 -1187 -700 -568 -710 -126 -213 -232 -275 357 804 1251 1729 1003 342 -28 -644 -680 -355 244 326 1687 461 941 1296 457 153 -24 -265 33 196 84 -713 -346 -344 -536 -202 80 -382 -499 -533 -437 -752 -570 -505 -408 -359 -201 -421 -709 -496 -155 -296 3 103 -121 193 154 321 287 67 213 247 -36 -36 -112 -312 -48 154 413 -157 260 -200 -1104 -193 -301 -43 -37 -243 -559 -667 -158 -248 -108 314 -121 254 325 364 1043 728 576 840 153 411 702 468 644 916 859 833 524 778 452 -556 956 406 905 1215 -553 -652 -1059 -562 52 -49 703 266 347 79 -1372 -1342 -1957 -2361 -1169 -1241 -1107 -800 -624 -148 50 1480 1082 1650 1921 1069 -271 -523 -876 -1583 -577 -309 -302 489 765 -1546 -926 -771 -995 -184 -320 -348 -415 522 1127 1707 2340 1377 485 -41 -956 -995 -517 350 458 2326 618 1267 1812 657 229 -37 -418 53 324 143 -1218 -600 -601 -916 -340 133 -621 SS 20250911T063330.2Z 9385.273266 248 1 6.53 2 68.32 103.37 66.14 272.12 0.00 1 0.00 1 0 25 1.572e-02 7.951e-03 2.728e-03 8.263e-04 3.643385e-01 4.533044e-04 4.284394e-03 -6.000000e+00 9.794943e-03 229.13 -2.00 3.48 -2.00 317.26 0.00e+00 3.942079e-04 6.589882e-05 9.060419e-05 -6.000000e+00 4.368321e-04 284.38 -2.00 20.00 -2.00 316.50 0.00e+00 2.683 0.000 302.00 328.00 3 1.4071e+00 1.1953e-03 3.0871e-02 -6.0000e+00 2.4372e-02 3.2048e-02 1.3395e-03 1.8583e-02 -6.0000e+00 2.6355e-02 -1.9908e-02 7.9482e-04 9.0818e-03 -6.0000e+00 1.5702e-02 2.2984e-03 3.7964e-04 2.5442e-03 -6.0000e+00 6.5233e-03 7.0085e-03 1.1534e-05 2.6878e-05 3.3924e-05 -6.0000e+00 5.0355e-04 1.4991e-03 0.0000e+00 12 9 1 12 1 1 99.98 24.02 0.32 0.00150 0.00159 119 105 2 8 0 54.360 20.00 24.02 24.98 33.75 33.50 3.0 968.13 -5274 -5348 -3822 -6326 -4997 -5049 -5116 -3329 -959 -3318 -4445 -2860 -1464 -1323 -97 -514 -700 645 761 1136 916 662 652 795 144 -29 -817 -1310 -67 348 1557 -350 967 -817 -2663 -685 -398 -448 93 -744 -956 -1012 -238 -567 -343 266 -553 382 421 717 1437 1203 909 1424 498 653 1082 691 959 1405 1443 1286 545 955 421 -453 1194 404 1052 1421 -553 -510 -1203 -643 -64 -61 967 150 411 11 -1378 -1437 -1835 -2211 -1100 -1021 -1029 -711 -610 -161 149 1276 851 1501 1745 826 -190 -355 -620 -1082 -408 -289 -237 594 664 -1187 -742 -449 -605 -121 -142 -174 -235 303 670 1175 1676 945 414 8 -651 -657 -407 242 331 1701 487 872 1244 367 251 64 -328 26 117 117 -778 -281 -388 -490 -238 145 -357 -504 -550 -397 -632 -460 -470 -513 -366 -113 -424 -588 -407 -239 -229 -19 -113 -163 157 179 278 229 166 171 222 42 -9 -250 -385 -19 100 484 -112 332 -294 -935 -243 -146 -192 44 -384 -509 -566 -137 -331 -201 156 -323 221 245 428 864 781 596 986 343 461 776 496 677 993 1055 965 426 791 352 -362 953 326 864 1246 -509 -487 -1147 -586 -56 -51 781 120 332 10 -1309 -1455 -1932 -2373 -1209 -1192 -1216 -858 -734 -186 165 1357 887 1543 1839 934 -232 -448 -806 -1397 -513 -349 -281 712 826 -1528 -968 -616 -853 -177 -213 -260 -353 441 939 1609 2276 1296 585 11 -962 -957 -592 348 453 2291 657 1182 1743 525 370 99 -509 41 189 199 -1330 -488 -678 -836 -401 235 -584 SS 20250911T064326.0Z 9385.280162 250 1 53.97 2 66.49 105.18 67.94 273.67 0.00 1 0.00 1 0 25 1.245e-02 8.102e-03 4.391e-04 1.659e-04 3.368130e-01 9.099568e-05 3.987988e-03 -6.000000e+00 7.755839e-03 229.13 -2.00 3.48 -2.00 316.88 0.00e+00 2.754421e-04 1.205018e-05 7.036447e-05 -6.000000e+00 3.458827e-04 284.38 -2.00 20.00 -2.00 316.13 0.00e+00 2.488 0.000 302.00 328.00 3 5.4153e-01 2.3855e-04 2.8612e-02 -6.0000e+00 1.9298e-02 2.6211e-02 2.6674e-04 1.7194e-02 -6.0000e+00 2.0868e-02 -1.7131e-02 1.5516e-04 8.3903e-03 -6.0000e+00 1.2433e-02 1.9665e-03 7.2268e-05 2.3274e-03 -6.0000e+00 5.1654e-03 2.0639e-02 5.5652e-05 5.4065e-06 3.2058e-05 -6.0000e+00 3.9872e-04 1.2713e-03 0.0000e+00 11 8 0 10 0 0 99.99 24.05 0.30 0.00127 0.00169 2663 280 2 8 0 20.260 20.01 24.05 25.61 33.75 33.50 3.0 970.85 -2608 -3860 -2811 -5250 -4320 -2837 -2727 -1640 -1017 -1776 -3620 -1603 -181 -484 359 246 -740 677 555 1396 1360 347 1239 785 33 265 -184 -871 457 684 1563 -331 965 -345 -2973 -630 -526 -263 -189 -622 -1342 -1305 -545 -713 -365 229 -402 388 317 545 1427 1161 684 1185 221 534 1027 654 934 1294 1266 1234 645 828 388 -604 1167 448 1069 1360 -581 -657 -1103 -581 -32 46 944 331 438 145 -1404 -1277 -1785 -2256 -1011 -1040 -890 -774 -600 -190 12 1284 1116 1648 1877 937 -241 -402 -671 -1146 -486 -273 -155 534 626 -1167 -725 -558 -689 -112 -225 -216 -322 328 753 1187 1725 965 374 19 -654 -694 -329 204 356 1642 463 933 1332 434 230 -35 -274 47 198 137 -752 -327 -348 -617 -224 82 -347 -339 -543 -400 -716 -543 -354 -365 -242 -150 -278 -587 -276 -35 -101 85 64 -205 182 156 405 401 104 383 258 11 88 -61 -297 149 226 519 -121 377 -131 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