File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20250915_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260424T062407.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20250915_L1_smca1c3d20250801p1-8.txt Full location name: Istituto di Metodologie per l'Analisi Ambientale (IMAA), CNR, Tito Scalo (PZ) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20250915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250915T051451.5Z 9389.218651 208 1 54.31 2 83.83 91.44 12.79 162.61 0.00 1 0.00 1 0 25 5.402e-01 2.920e-02 2.224e-01 6.204e-03 8.900827e-01 3.833004e-03 9.695534e-03 -6.000000e+00 3.442815e-01 228.81 -2.00 3.48 -2.00 321.94 0.00e+00 1.707739e-02 2.265067e-03 2.941611e-03 -6.000000e+00 1.774984e-02 284.05 -2.00 20.00 -2.00 321.44 0.00e+00 8.355 0.010 302.00 328.00 3 1.0693e+00 1.4853e-02 9.6127e-02 -6.0000e+00 8.6086e-01 1.1399e+00 1.9415e-02 7.1125e-02 -6.0000e+00 9.3587e-01 -1.4123e+00 1.6188e-02 2.4695e-02 -6.0000e+00 5.5033e-01 5.5338e-01 7.4731e-03 1.9375e-02 -6.0000e+00 2.2720e-01 3.2800e-05 -8.7129e-04 1.8737e-04 2.5812e-04 -6.0000e+00 1.8213e-02 1.0820e-03 0.0000e+00 12 8 8 10 0 0 41.65 23.30 0.48 0.00108 -0.00547 62 7 4 8 0 875.700 20.05 23.30 21.04 33.25 33.00 3.2 953.60 -67756 4200 900000 -103845 900000 -107202 900000 -165073 900000 900000 -40814 -10653 900000 -12256 27562 900000 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4053 3099 3470 -3815 3470 4681 1019 3940 3916 3060 3030 5599 5426 517 1443 1336 5537 3374 2867 969 5736 425 3670 -1257 -2157 1083 1297 3289 1889 2793 -308 249 -2193 -1463 -5844 319 6484 419 607 1356 -3462 5845 -774 697 -1712 -3476 -3847 -1734 -463 149 -979 -1253 -1471 -8074 970 -2804 -2865 -3574 -1863 -848 -2407 -2185 3361 1004 -350 2709 -2122 -1503 852 3808 773 3407 435 6965 437 3223 2969 1187 259 3471 79 3896 -1528 -637 1576 -1720 -2273 351 -2402 1195 -4942 SS 20250915T052052.6Z 9389.222830 211 1 54.11 2 82.69 92.43 12.51 168.37 0.00 1 0.00 1 0 25 6.294e-01 1.322e-02 2.442e-01 2.829e-03 8.277654e-01 1.693755e-03 9.330457e-03 -6.000000e+00 3.983342e-01 228.81 -2.00 3.48 -2.00 321.44 0.00e+00 1.025701e-02 9.353536e-04 2.349673e-03 -6.000000e+00 1.850317e-02 284.05 -2.00 20.00 -2.00 320.90 0.00e+00 7.260 0.007 302.00 328.00 3 1.0428e+00 6.1386e-03 7.9909e-02 -6.0000e+00 9.9493e-01 3.2329e-01 8.8741e-03 4.5802e-02 -6.0000e+00 1.0799e+00 -3.3026e-01 9.1353e-03 2.8778e-02 -6.0000e+00 6.3618e-01 1.1160e-01 4.1784e-03 1.5144e-02 -6.0000e+00 2.6150e-01 1.0738e-04 -3.0752e-04 8.3625e-05 2.1918e-04 -6.0000e+00 2.0561e-02 8.7591e-04 0.0000e+00 12 8 8 10 0 0 28.70 23.31 0.58 0.00088 -0.00143 129 14 4 8 0 419.360 20.07 23.31 21.51 33.25 33.00 3.2 955.67 -298674 -83263 -157905 -274598 900000 -196298 900000 -246083 900000 6856 -207552 -164633 900000 -152200 -23777 106741 -128717 -113083 900000 900000 11173 72730 -124388 -49147 -31687 118364 -52935 -86441 130237 7423 35841 -87816 -12447 -724 6123 7678 -7907 68288 -13488 -24820 26390 -9705 3006 -2722 -4 14173 17920 -7401 2945 16968 30628 18807 10288 4879 6065 -4910 1724 17081 -2454 8243 8634 7225 6363 14869 10608 1359 -490 -2107 8331 4068 1631 -942 6152 -1560 4392 -3324 -5926 -1529 459 3931 117 867 -1816 -2308 -1591 -1876 -3523 -10 3129 652 809 600 -1729 3600 408 613 168 55 -1008 -1686 -74 -114 22 -778 -410 -3309 -308 -1089 -937 -593 -313 -126 -295 -135 1189 735 1278 997 -192 -135 -223 51 -442 662 195 2100 -78 546 1111 191 318 273 -74 151 -359 -231 -381 -139 -489 -52 -197 790 -452 -3891 -229 -633 -3439 900000 -1082 900000 -2589 900000 19 -1976 -1278 900000 -1906 -107 294 -2354 -2212 900000 900000 74 261 -3359 -664 -375 326 -831 -1929 359 82 375 -3823 -298 -17 128 165 -222 1054 -565 -1361 967 -551 161 -160 0 769 988 -565 220 1216 2169 1689 1106 605 784 -735 247 2085 -358 1088 1197 1135 1154 2811 2245 319 -122 -564 2231 1295 522 -319 2092 -538 1313 -983 -1754 -457 154 1532 50 426 -1013 -1376 -1009 -1261 -2512 -7 2125 440 515 368 -1081 2273 303 487 156 59 -1089 -1847 -76 -116 21 -723 -403 -3512 -338 -1208 -1150 -822 -449 -193 -462 -210 1765 1069 1871 1521 -309 -224 -363 79 -666 959 274 3061 -107 779 1794 330 612 536 -156 339 -815 -552 -927 -342 -1205 -122 -438 1754 -981 SS 20250915T053311.9Z 9389.231388 214 1 54.25 2 80.35 94.46 12.30 180.64 0.00 1 0.00 1 0 17 3.443e-01 8.425e-03 3.559e-02 1.015e-03 6.785334e-01 5.706389e-04 7.645071e-03 -6.000000e+00 2.143083e-01 228.81 -2.00 3.48 -2.00 320.37 0.00e+00 4.530642e-03 2.230952e-04 9.844192e-04 -6.000000e+00 9.554434e-03 284.05 -2.00 20.00 -2.00 319.73 0.00e+00 5.695 0.003 302.00 328.00 3 7.8833e-01 1.7431e-03 6.2878e-02 -6.0000e+00 5.3290e-01 1.1954e-01 2.2099e-03 3.5630e-02 -6.0000e+00 5.7638e-01 -1.0984e-01 2.0123e-03 1.9457e-02 -6.0000e+00 3.4343e-01 3.0356e-02 9.9485e-04 8.3370e-03 -6.0000e+00 1.4275e-01 6.4676e-04 -1.5024e-04 3.0485e-05 9.9305e-05 -6.0000e+00 1.1028e-02 2.6822e-04 0.0000e+00 11 8 0 10 0 0 12.15 23.37 0.38 0.00027 -0.00086 372 39 2 8 0 145.800 20.02 23.37 22.55 33.25 33.25 3.1 960.02 -178507 -135082 -81601 -143613 -75518 -111901 -88526 -120328 -37316 -83662 -99137 -80700 -55847 -66121 -49516 -13469 -32207 -24558 20160 -443 -26200 -10556 -38189 -17014 -26318 -18216 -26970 -30548 -8946 -18775 -7455 -18724 -162 -2828 -2033 -6913 -3188 1104 -4085 -5768 -1633 -3450 -1892 -653 629 1784 2828 -810 1618 2453 5992 4621 3517 3069 3136 -32 1916 1917 766 2176 3312 2741 1808 3390 2555 956 2018 923 2270 2162 17 -965 -215 -880 335 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