File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260128_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260424T064458.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260128_L1_smca1c3d20250801p1-8.txt Full location name: Istituto di Metodologie per l'Analisi Ambientale (IMAA), CNR, Tito Scalo (PZ) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260128T080402.9Z 9524.336144 182 1 9.14 2 72.91 133.86 111.16 19.49 0.00 1 0.00 1 0 25 9.522e-02 9.755e-03 2.855e-02 3.074e-03 4.882615e-01 1.657431e-03 5.683975e-03 -6.000000e+00 5.819743e-02 223.92 -2.00 3.48 -2.00 318.75 0.00e+00 1.122127e-03 3.631308e-04 2.456209e-04 -6.000000e+00 2.504639e-03 270.92 -2.00 20.00 -2.00 318.26 0.00e+00 3.354 0.001 302.00 328.00 3 3.4608e+00 4.4749e-03 3.9058e-02 -6.0000e+00 1.4371e-01 7.3490e-02 5.1000e-03 2.4451e-02 -6.0000e+00 1.5632e-01 -4.0356e-02 3.6812e-03 1.2377e-02 -6.0000e+00 9.2771e-02 9.2422e-03 1.9248e-03 3.8474e-03 -6.0000e+00 3.8471e-02 4.2326e-04 -1.5850e-04 9.7455e-05 4.7057e-05 -6.0000e+00 3.0439e-03 -1.4067e-03 0.0000e+00 12 9 9 12 1 1 91.70 23.18 0.16 -0.00141 -0.00260 10 7 4 8 0 829.790 20.02 23.18 16.15 33.25 33.00 3.3 933.15 -44736 -37784 -34280 -15160 -16974 -42602 -20385 -48317 16077 -15450 -27005 -21475 -3865 -2077 -9281 -2492 -12264 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-2381 -1580 -1238 -1551 -1147 -417 -139 512 1115 621 2181 1526 770 104 -292 -1218 -1445 -1021 180 -198 513 834 -2401 -1056 -1202 -1081 -665 -547 -154 -747 297 1540 1552 2499 1555 328 151 -774 -319 267 531 153 2910 553 786 2250 675 341 119 -528 36 104 32 -1331 -749 -379 -1098 -631 322 -544 SS 20260128T112619.9Z 9524.476619 291 1 20.97 2 58.85 184.52 88.07 56.48 0.00 1 0.00 1 0 17 1.721e-02 9.015e-03 5.089e-03 1.970e-03 2.943329e-01 1.061625e-03 3.528614e-03 -6.000000e+00 1.052158e-02 223.93 -2.00 3.48 -2.00 316.74 0.00e+00 -4.780572e-05 1.320361e-04 5.982131e-05 -6.000000e+00 4.527025e-04 270.92 -2.00 20.00 -2.00 316.25 0.00e+00 1.926 0.000 302.00 328.00 3 4.9575e+00 2.7529e-03 2.2856e-02 -6.0000e+00 2.5983e-02 3.8651e-02 3.0814e-03 1.4630e-02 -6.0000e+00 2.8260e-02 -6.5639e-03 1.8081e-03 7.3115e-03 -6.0000e+00 1.6771e-02 -1.8301e-03 8.4665e-04 2.0930e-03 -6.0000e+00 6.9564e-03 4.3911e-04 2.0854e-04 6.4983e-05 2.8726e-05 -6.0000e+00 5.5017e-04 -2.6866e-03 0.0000e+00 12 9 1 12 9 1 99.99 23.18 -0.08 -0.00269 -0.00112 19 5 1 8 0 1048.000 19.90 23.18 15.93 33.25 33.00 3.3 932.98 -6471 -4319 -2995 -3046 133 -2548 -478 -6011 7497 864 -6113 -4887 1981 185 -262 3188 -2119 -1131 4063 2865 73 2081 -516 -161 -160 278 1 -2645 439 469 320 -2956 1326 -832 -2570 -602 -358 641 -940 -306 51 -1998 -544 -292 -791 -91 -388 -491 690 546 1716 1630 952 1272 456 -202 889 1189 555 1775 1599 1056 602 1356 739 -1610 180 21 1208 1122 -329 -731 -526 -508 791 -260 439 230 523 289 -1141 -892 -1892 -2485 -1201 -1265 -1145 -924 57 -296 260 1416 96 2543 1558 1180 417 -430 -558 -1294 -357 -269 -61 539 488 -1498 -415 -461 -821 -246 -145 -120 -192 91 1007 936 1832 1054 67 -17 -677 -398 -640 166 40 1764 630 958 1634 440 83 140 -147 216 -223 -15 -394 -438 -439 -425 -203 168 -567 -931 -645 -448 -424 17 -327 -64 -946 1126 145 -1010 -853 366 40 -64 817 -598 -332 1174 868 23 644 -156 -51 -53 95 0 -867 146 157 105 -1067 494 -323 -967 -228 -149 282 -496 -170 31 -1279 -354 -191 -518 -59 -249 -311 429 346 1137 1077 666 936 348 -158 702 932 432 1368 1273 846 520 1224 670 -1400 147 17 1029 1003 -319 -739 -526 -489 704 -225 374 190 422 261 -1089 -935 -2026 -2808 -1359 -1523 -1368 -1130 69 -364 297 1564 100 2689 1656 1301 509 -549 -717 -1737 -451 -335 -72 646 597 -1955 -561 -623 -1170 -354 -218 -183 -285 127 1361 1261 2427 1452 93 -24 -976 -566 -933 232 53 2332 805 1221 2191 605 120 201 -217 329 -345 -25 -654 -712 -718 -710 -327 261 -871 SS 20260128T125458.2Z 9524.538173 335 1 47.37 2 63.57 207.98 73.62 68.95 0.00 1 0.00 1 0 25 2.883e-01 2.728e-02 9.432e-02 5.682e-03 3.550817e-01 3.038087e-03 4.239364e-03 -6.000000e+00 1.763245e-01 223.93 -2.00 3.48 -2.00 318.32 0.00e+00 6.796781e-04 5.700616e-04 4.774198e-04 -6.000000e+00 7.579879e-03 270.92 -2.00 20.00 -2.00 317.80 0.00e+00 2.234 0.000 302.00 328.00 3 6.8286e+00 8.0843e-03 2.7032e-02 -6.0000e+00 4.3545e-01 1.2375e-01 9.1545e-03 1.7762e-02 -6.0000e+00 4.7347e-01 -7.4768e-02 5.9892e-03 9.0206e-03 -6.0000e+00 2.8102e-01 3.4289e-02 3.0422e-03 2.7393e-03 -6.0000e+00 1.1667e-01 4.5289e-05 9.6409e-04 1.8991e-04 3.5724e-05 -6.0000e+00 9.2163e-03 -7.4686e-03 0.0000e+00 12 8 8 10 0 0 99.96 23.07 -2.36 -0.00747 -0.00022 12 1 1 8 0 3946.590 19.94 23.07 14.16 33.25 33.00 3.3 926.48 69979 -11613 -19521 -22421 80884 -52781 9116 -48163 266405 105696 -41120 -14641 1295 21551 31843 22567 -16668 -7609 61791 23323 -1322 42246 -17091 -12132 -3868 8662 -2688 -19161 -1215 8999 -8005 -17950 408 -5118 4735 9857 -1555 4182 -2833 6369 8737 -2845 -3573 10493 -1098 3836 6861 -6541 6450 3423 9820 3686 4863 1178 1068 -7203 2431 8032 -4030 6008 7221 -97 2017 6015 4065 -6358 -2542 -3336 3233 -459 1124 -2691 3161 -174 4373 -4999 -4369 -3068 -98 2325 -403 -108 -2061 -4227 -3088 -2424 -3257 -1258 4841 -786 359 1752 -4564 7494 -819 1362 2315 -546 -1270 -3153 -1530 -301 -1383 264 248 -5713 2245 -151 -1328 241 1294 2774 -75 1518 2733 1106 1985 818 -2005 -1270 -298 1324 -520 1292 -1646 2877 607 3111 1772 -128 -1094 858 117 1765 -1749 -1018 1037 -183 -2333 376 -280 837 -1359 2094 -837 -1547 -1702 2017 -5001 495 -5124 1476 2753 -4717 -1395 121 1899 2894 2476 -2845 -1252 5273 3024 -222 4565 -3466 -2467 -755 1531 -527 -4205 -215 1466 -1677 -4476 92 -1245 994 2015 -393 1154 -989 2319 3365 -1287 -1681 4320 -507 1690 2893 -3135 2716 1523 4364 1867 2568 682 637 -4340 1487 4616 -2568 3466 4246 -66 1310 3982 2754 -4513 -1678 -2215 2356 -352 907 -2332 2556 -139 3119 -3911 -3160 -2137 -70 1820 -328 -97 -2024 -4452 -3440 -2843 -4026 -1559 5621 -931 391 1754 -4566 6576 -830 1484 2753 -734 -1666 -4165 -2059 -372 -1638 313 314 -8040 3057 -203 -1908 365 2044 4402 -120 2255 3750 1597 2823 1213 -2947 -1946 -457 1967 -766 1804 -2455 3957 818 4108 2529 -182 -1668 1334 189 2905 -3140 -1902 1937 -353 -4601 703 -507 1448 -2343