File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260330_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260424T065956.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260330_L1_smca1c3d20250801p1-8.txt Full location name: Istituto di Metodologie per l'Analisi Ambientale (IMAA), CNR, Tito Scalo (PZ) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260330T065954.3Z 9585.291601 229 1 49.44 2 65.36 107.28 123.72 324.30 0.00 1 0.00 1 0 17 1.534e-01 1.514e-02 4.165e-02 3.969e-03 3.978348e-01 2.146417e-03 4.667391e-03 -6.000000e+00 9.474743e-02 226.92 -2.00 3.48 -2.00 318.69 0.00e+00 1.016482e-03 4.571659e-04 2.169888e-04 -6.000000e+00 4.091380e-03 274.45 -2.00 20.00 -2.00 318.12 0.00e+00 2.383 0.000 302.00 328.00 3 6.1134e+00 5.7928e-03 2.9895e-02 -6.0000e+00 2.3530e-01 1.0283e-01 6.6009e-03 2.0351e-02 -6.0000e+00 2.5530e-01 -4.1383e-02 4.5715e-03 1.0090e-02 -6.0000e+00 1.5147e-01 9.9480e-03 2.3549e-03 3.0262e-03 -6.0000e+00 6.2602e-02 7.5279e-05 -5.9376e-04 1.3145e-04 3.8550e-05 -6.0000e+00 4.9067e-03 1.6195e-03 0.0000e+00 12 9 8 11 8 0 99.98 23.03 -0.61 0.00162 -0.00284 38 4 2 8 0 1300.900 20.13 23.03 15.06 33.00 33.00 3.3 928.61 1229 -25033 -10080 5780 76778 -32521 35511 -55261 113985 35977 -12430 -20705 15505 282 3302 21694 -20944 -9940 40930 23432 -6344 18391 -16108 -4570 -7563 10224 -5494 -1851 -742 6378 -2729 -14437 9737 915 2771 2602 4066 350 -2571 -516 3617 -3379 -2151 1801 -241 -1982 7722 -2048 2308 1761 3567 3053 930 -811 221 2680 2635 2284 -1069 -3644 4070 286 2839 2345 1608 -3243 -2266 -1080 3311 1164 426 -2228 194 -932 2391 -3682 -517 -112 1847 615 -691 -23 -2014 -3467 -2199 -726 -632 -531 2173 -255 -493 2196 -525 4435 1140 1633 212 -753 -913 -2001 264 -14 -122 521 56 -2613 472 -935 -884 -98 -25 -190 -336 264 1859 576 2235 1051 -205 -472 -1081 -51 -669 587 -648 2661 27 826 1578 273 -778 516 -12 988 -1218 -278 15 -11 -1035 47 -645 797 -394 45 -1279 -456 210 1278 -1624 962 -4128 1721 1253 -722 -1434 876 22 286 1747 -2748 -1247 3232 2295 -852 1929 -2488 -667 -1191 1393 -874 -272 -105 866 -447 -2900 1681 178 507 490 836 87 -777 -176 1288 -1356 -885 721 -99 -832 2923 -856 932 738 1574 1460 438 -413 115 1398 1401 1213 -577 -2022 2159 169 1774 1573 1099 -2210 -1486 -703 2203 885 350 -1944 164 -761 1759 -2616 -332 -70 1208 459 -585 -22 -1890 -3471 -2325 -802 -729 -626 2485 -288 -521 2301 -532 4254 1206 1739 254 -1002 -1193 -2834 347 -17 -142 607 70 -3514 645 -1263 -1263 -150 -40 -315 -547 406 2638 853 3237 1466 -305 -736 -1712 -79 -1007 843 -972 3729 37 1140 2315 403 -1236 845 -20 1730 -2135 -506 29 -20 -1982 86 -1152 1458 -712 SS 20260330T070629.6Z 9585.296176 234 1 48.07 2 64.17 108.54 124.43 325.97 0.00 1 0.00 1 0 17 1.560e-02 8.053e-03 5.686e-04 1.896e-04 3.808182e-01 1.033611e-04 4.492517e-03 -6.000000e+00 9.640903e-03 226.92 -2.00 3.48 -2.00 317.13 0.00e+00 4.649304e-04 1.406447e-05 8.415355e-05 -6.000000e+00 4.160657e-04 274.45 -2.00 20.00 -2.00 316.55 0.00e+00 2.281 0.000 302.00 328.00 3 8.1991e-01 2.7015e-04 2.8447e-02 -6.0000e+00 2.3943e-02 4.9486e-02 3.0231e-04 1.9111e-02 -6.0000e+00 2.5972e-02 -3.2702e-02 1.7946e-04 9.4555e-03 -6.0000e+00 1.5410e-02 6.5336e-03 8.5236e-05 2.7055e-03 -6.0000e+00 6.3733e-03 1.7329e-02 -3.4204e-05 6.1159e-06 3.6378e-05 -6.0000e+00 4.9899e-04 -2.2766e-03 0.0000e+00 12 9 1 12 1 1 99.98 23.05 0.31 -0.00228 -0.00253 1779 210 2 8 0 27.000 19.99 23.05 15.27 33.00 33.00 3.3 929.81 -4240 -5152 -3788 -6307 -6021 -4678 -4375 -2751 -2543 -3122 -4889 -2906 -714 -905 259 170 -636 957 877 1697 1683 626 1399 746 -55 -10 -474 -977 20 319 1426 -262 928 -97 -2926 -703 -585 -214 -15 -418 -1206 -1189 -490 -551 -218 330 -273 456 331 549 1505 1318 774 1303 350 529 1053 672 915 1305 1214 1288 676 775 383 -669 994 377 890 1392 -549 -582 -1034 -584 25 25 883 257 305 96 -1439 -1366 -1766 -2325 -1112 -1059 -902 -711 -586 -171 71 1327 1149 1546 1778 901 -229 -447 -607 -1090 -452 -223 -170 589 697 -1069 -718 -558 -760 -192 -317 -272 -400 295 742 1195 1746 1116 480 163 -543 -591 -333 256 293 1618 440 841 1280 355 129 -111 -342 5 174 186 -710 -321 -291 -545 -230 104 -384 -456 -602 -449 -721 -639 -493 -494 -341 -346 -452 -738 -431 -121 -178 54 39 -157 248 221 441 446 168 389 222 -17 -3 -144 -305 6 98 443 -90 344 -35 -1045 -253 -232 -93 -7 -222 -667 -691 -279 -318 -126 190 -157 273 200 325 944 852 510 908 255 378 763 487 652 928 892 974 535 653 327 -548 808 309 747 1251 -521 -552 -976 -545 22 21 720 207 250 85 -1353 -1376 -1860 -2509 -1231 -1208 -1075 -841 -691 -199 80 1410 1188 1634 1933 1023 -274 -574 -806 -1442 -580 -273 -202 708 871 -1384 -945 -754 -1060 -278 -475 -407 -602 430 1036 1621 2342 1555 689 240 -795 -875 -479 362 406 2192 579 1110 1753 513 189 -171 -529 8 281 310 -1189 -546 -497 -931 -376 168 -622 SS 20260330T073908.1Z 9585.318844 251 1 4.88 2 58.41 115.11 127.50 334.75 0.00 1 0.00 1 0 17 2.330e-02 1.034e-02 1.834e-02 6.487e-03 3.197754e-01 3.531539e-03 3.814432e-03 -6.000000e+00 1.441061e-02 226.93 -2.00 3.48 -2.00 316.96 0.00e+00 4.598422e-04 4.619423e-04 8.092605e-05 -6.000000e+00 6.216973e-04 274.45 -2.00 20.00 -2.00 316.39 0.00e+00 1.902 0.000 302.00 328.00 3 5.1354e+00 9.2179e-03 2.3863e-02 -6.0000e+00 3.5790e-02 7.9535e-02 1.0306e-02 1.6141e-02 -6.0000e+00 3.8818e-02 -2.7082e-02 6.0920e-03 7.9934e-03 -6.0000e+00 2.3032e-02 5.3396e-03 2.8761e-03 2.2890e-03 -6.0000e+00 9.5288e-03 3.4902e-04 3.1500e-04 2.1247e-04 3.0893e-05 -6.0000e+00 7.4561e-04 -4.2023e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.36 -0.03 -0.00420 -0.00184 1 2 1 8 0 2437.760 20.01 23.36 17.92 33.25 33.25 3.2 938.44 -7153 -6328 -2685 -12029 -5687 -7362 4013 -1885 3095 6816 -8543 -2101 2088 1794 1732 182 -1518 2804 5478 4680 -601 2116 -993 -1163 142 3274 -34 -974 -494 1685 761 -2520 -3637 -210 -2702 323 38 -4460 -275 562 -1305 -2019 458 263 -1178 942 1539 -702 557 2172 1154 112 1042 -113 1061 -4 -222 -769 360 2012 2422 1575 150 1248 838 -1478 1160 0 1246 2425 -386 -784 332 -320 -987 -341 843 88 -668 861 -1907 -1743 -1775 -2440 -653 -1317 -911 -1040 -93 373 -272 1496 1514 1995 1941 1521 494 51 -36 -1451 -668 -234 246 120 -251 -1705 -699 -790 -543 -118 -153 -457 -242 59 671 1342 1658 2028 426 124 -553 -331 -804 372 62 1668 -416 878 1910 799 169 18 -527 -813 -409 -619 -97 151 -159 -334 -390 546 -489 -901 -841 -350 -1606 -658 -866 449 -248 423 940 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