File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260507_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260511T185540.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260507_L1_smca1c3d20250801p1-8.txt Full location name: CNR-IMAA Atmospheric Observatory (CIAO) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260507T064105.7Z 9623.278538 246 1 54.35 2 58.89 94.11 82.87 225.19 0.00 1 0.00 1 0 17 1.270e-02 8.180e-03 1.119e-03 4.722e-04 3.216875e-01 2.600733e-04 3.797244e-03 -6.000000e+00 7.938006e-03 229.94 -2.00 3.48 -2.00 316.62 0.00e+00 3.338782e-04 3.150330e-05 5.962462e-05 -6.000000e+00 3.449060e-04 278.82 -2.00 20.00 -2.00 315.97 0.00e+00 1.928 0.000 302.00 328.00 3 3.1226e+00 6.7999e-04 2.4294e-02 -6.0000e+00 1.9827e-02 3.1191e-02 7.5767e-04 1.6363e-02 -6.0000e+00 2.1446e-02 -2.1824e-02 4.3854e-04 8.0075e-03 -6.0000e+00 1.2726e-02 3.4989e-03 2.0069e-04 2.2351e-03 -6.0000e+00 5.2519e-03 2.5876e-03 6.7353e-05 1.5400e-05 3.0395e-05 -6.0000e+00 4.0684e-04 -9.6073e-04 0.0000e+00 11 8 0 10 0 0 99.91 23.70 0.30 -0.00096 -0.00045 246 26 4 8 0 220.880 19.99 23.70 21.77 33.50 33.25 3.1 951.76 -3573 -4210 -2935 -5034 -3887 -2659 -2182 -2582 269 -1727 -3532 -2450 -176 -395 61 365 -1013 634 1149 1512 1633 993 1175 1015 87 630 -329 -602 792 709 1664 -451 1313 -345 -2750 -350 -221 -35 -175 -511 -1281 -1497 -613 -742 -356 178 -337 216 311 380 1480 1237 731 1103 273 420 1071 724 938 1255 1238 1333 611 713 392 -846 912 407 952 1473 -556 -650 -1122 -547 27 -189 764 374 362 91 -1375 -1346 -1824 -2304 -1079 -1003 -899 -769 -485 -173 32 1211 1037 1698 1755 980 -192 -381 -580 -1120 -442 -243 -161 547 743 -1153 -708 -519 -794 -144 -226 -187 -345 276 762 1161 1766 1072 427 113 -547 -624 -275 259 364 1632 433 904 1318 374 137 -121 -346 35 209 145 -721 -307 -279 -602 -237 92 -450 -558 -646 -453 -808 -572 -388 -339 -447 45 -312 -657 -486 -39 -93 16 106 -291 189 355 483 530 324 398 364 31 227 -119 -222 277 252 589 -175 541 -148 -1151 -147 -96 -17 -92 -294 -805 -938 -393 -481 -230 115 -215 136 194 243 994 849 531 806 207 326 840 568 724 969 988 1087 517 637 352 -723 768 343 814 1341 -533 -645 -1111 -518 25 -164 638 304 310 84 -1315 -1368 -1926 -2567 -1229 -1172 -1063 -932 -584 -207 36 1329 1105 1770 1865 1110 -234 -477 -746 -1478 -551 -292 -190 653 918 -1474 -945 -705 -1105 -206 -331 -279 -501 387 1053 1518 2354 1441 591 161 -795 -897 -395 358 493 2169 558 1162 1793 515 200 -179 -511 54 327 232 -1193 -503 -459 -999 -378 146 -701 SS 20260507T065757.6Z 9623.290251 259 1 11.09 2 55.70 97.05 85.10 228.11 0.00 1 0.00 1 0 17 2.156e-02 9.842e-03 1.100e-02 4.004e-03 2.972905e-01 2.197918e-03 3.495812e-03 -6.000000e+00 1.349201e-02 229.94 -2.00 3.48 -2.00 316.93 0.00e+00 3.219268e-04 2.884995e-04 6.569881e-05 -6.000000e+00 5.852966e-04 278.82 -2.00 20.00 -2.00 316.28 0.00e+00 1.769 0.000 302.00 328.00 3 5.4989e+00 5.7720e-03 2.2390e-02 -6.0000e+00 3.3703e-02 4.4811e-02 6.4479e-03 1.5162e-02 -6.0000e+00 3.6435e-02 -2.3957e-02 3.7804e-03 7.4116e-03 -6.0000e+00 2.1625e-02 5.4064e-03 1.7642e-03 2.0987e-03 -6.0000e+00 8.9402e-03 2.8608e-04 1.2501e-03 1.3225e-04 2.7517e-05 -6.0000e+00 6.9069e-04 -1.0230e-02 0.0000e+00 12 9 9 12 9 1 69.06 23.62 -0.11 -0.01023 -0.00084 3 2 1 8 0 2768.010 20.00 23.62 22.03 33.50 33.25 3.1 953.43 -937 -4912 843 -566 -8860 -8649 1227 -9527 3937 5861 -4396 -7604 2961 -1227 1629 2404 -3465 -3337 5114 2153 1006 4121 -1582 -68 -3351 2108 -2425 -1377 295 166 1389 -1476 719 -1281 -2074 -952 631 152 38 1023 1035 -1246 8 10 -836 -387 544 -865 208 341 1865 1214 1253 2129 517 -1322 21 1945 -195 1420 1416 706 824 1039 855 -1685 900 -414 1566 2079 -418 -1496 -632 -986 920 -1563 714 267 446 563 -1547 -1261 -2158 -1967 -1257 -1453 -770 -372 76 41 181 1282 -80 2534 1682 1567 326 -251 -309 -1235 -368 -320 -539 1111 409 -1682 -724 -468 -1062 42 -178 352 -833 805 1114 784 1691 673 161 -200 -675 -449 -390 388 128 2163 496 986 1450 325 -197 -296 -285 115 -161 -244 -512 2 -338 -681 453 280 -840 -117 -679 112 -71 -1110 -1081 148 -1417 558 851 -712 -1360 541 -242 353 563 -898 -907 1325 595 286 1131 -476 -21 -1125 688 -820 -436 88 50 442 -515 264 -490 -760 -354 255 65 19 542 593 -762 5 6 -528 -244 333 -530 125 208 1188 831 836 1485 377 -1002 16 1445 -146 1050 1081 579 675 895 736 -1394 745 -344 1354 1859 -411 -1441 -600 -964 826 -1307 579 210 367 482 -1498 -1255 -2322 -2217 -1419 -1746 -962 -448 91 50 206 1423 -84 2538 1791 1823 396 -317 -412 -1642 -462 -398 -638 1322 525 -2184 -975 -626 -1499 62 -263 526 -1222 1154 1567 1050 2228 925 222 -293 -1009 -662 -561 535 177 2831 631 1248 1935 466 -284 -443 -436 173 -256 -407 -834 4 -565 -1119 747 449 -1331 SS 20260507T070326.8Z 9623.294061 262 1 54.07 2 54.67 98.04 85.85 229.04 0.00 1 0.00 1 0 17 1.310e-02 8.359e-03 2.170e-03 9.283e-04 2.906984e-01 5.121052e-04 3.440698e-03 -6.000000e+00 8.185901e-03 229.94 -2.00 3.48 -2.00 316.51 0.00e+00 1.760360e-04 6.064899e-05 5.596924e-05 -6.000000e+00 3.556419e-04 278.82 -2.00 20.00 -2.00 315.88 0.00e+00 1.724 0.000 302.00 328.00 3 4.6241e+00 1.3385e-03 2.1853e-02 -6.0000e+00 2.0447e-02 3.7266e-02 1.4915e-03 1.4802e-02 -6.0000e+00 2.2115e-02 -1.7456e-02 8.6051e-04 7.2477e-03 -6.0000e+00 1.3123e-02 1.0016e-03 3.9150e-04 2.0107e-03 -6.0000e+00 5.4164e-03 7.2415e-04 1.3806e-04 3.0466e-05 2.7465e-05 -6.0000e+00 4.1945e-04 -1.5661e-03 0.0000e+00 11 9 0 11 8 0 99.98 23.60 0.16 -0.00157 -0.00053 68 7 1 8 0 794.870 20.00 23.60 22.08 33.50 33.25 3.1 953.76 -3581 -4708 -1237 -5208 -2090 -3406 -1059 -3857 2709 -673 -2825 -2916 1417 433 -1 1157 -1911 -689 2285 2147 854 1369 399 827 -724 540 -550 -696 592 779 1540 -1540 1327 -559 -2677 6 -145 134 -264 -411 -1140 -1449 -873 -763 -697 215 -57 -127 385 159 1280 1135 792 1209 197 42 991 937 824 1460 1513 1173 552 800 397 -1088 842 459 1242 1313 -212 -896 -898 -722 472 -279 520 412 625 192 -1460 -1129 -1762 -2282 -1073 -966 -1189 -692 -272 -248 20 1292 914 1801 1833 958 -31 -462 -681 -1132 -415 -253 -215 539 632 -1438 -660 -525 -753 13 -118 -134 -455 272 817 1089 1725 1022 422 40 -700 -509 -381 309 285 1768 387 838 1414 333 176 -71 -317 82 61 91 -532 -340 -315 -516 -252 174 -542 -557 -784 -202 -822 -295 -487 -158 -655 470 -126 -545 -601 317 111 0 332 -589 -220 735 717 293 466 142 286 -265 200 -204 -244 213 281 589 -596 537 -235 -1093 3 -65 65 -141 -250 -710 -944 -584 -513 -467 143 -38 -82 245 103 868 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