File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260511_L2Fit_fout2c2d20250523p1-8.txt File generation date: 20260511T225925.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v2d20250523.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260511_L1_smca1c2d20250523p1-8.txt Full location name: CNR-IMAA Atmospheric Observatory (CIAO) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260511 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1, but using lorentzian slit instead of gaussian First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0684 305.2089 305.3494 305.4898 305.6303 305.7707 305.9112 306.0516 306.1920 306.3324 306.4727 306.6131 306.7535 306.8938 307.0341 307.1745 307.3148 307.4551 307.5954 307.7356 307.8759 308.0162 308.1564 308.2966 308.4368 308.5771 308.7172 308.8574 308.9976 309.1378 309.2779 309.4181 309.5582 309.6983 309.8384 309.9785 310.1186 310.2586 310.3987 310.5388 310.6788 310.8188 310.9588 311.0988 311.2388 311.3788 311.5188 311.6587 311.7987 311.9386 312.0785 312.2184 312.3583 312.4982 312.6381 312.7779 312.9178 313.0576 313.1975 313.3373 313.4771 313.6169 313.7566 313.8964 314.0362 314.1759 314.3157 314.4554 314.5951 314.7348 314.8745 315.0142 315.1538 315.2935 315.4331 315.5727 315.7124 315.8520 315.9916 316.1311 316.2707 316.4103 316.5498 316.6894 316.8289 316.9684 317.1079 317.2474 317.3869 317.5263 317.6658 317.8052 317.9447 318.0841 318.2235 318.3629 318.5023 318.6416 318.7810 318.9204 319.0597 319.1990 319.3383 319.4776 319.6169 319.7562 319.8955 320.0347 320.1740 320.3132 320.4524 320.5916 320.7308 320.8700 321.0092 321.1483 321.2875 321.4266 321.5658 321.7049 321.8440 321.9831 322.1221 322.2612 322.4003 322.5393 322.6783 322.8173 322.9564 323.0954 323.2343 323.3733 323.5123 323.6512 323.7901 323.9291 324.0680 324.2069 324.3458 324.4847 324.6235 324.7624 324.9012 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260511T063444.9Z 9627.274131 195 1 19.85 2 59.41 92.09 50.44 186.30 0.00 1 0.00 1 0 17 3.223e-02 1.166e-02 9.818e-03 3.332e-03 2.891492e-01 1.824396e-03 3.403499e-03 -6.000000e+00 2.017484e-02 230.27 -2.00 3.48 -2.00 317.07 0.00e+00 2.967339e-04 2.486893e-04 8.062593e-05 -6.000000e+00 8.765006e-04 279.28 -2.00 20.00 -2.00 316.40 0.00e+00 1.957 0.000 302.00 328.00 3 5.4994e+00 4.8125e-03 2.3391e-02 -6.0000e+00 5.0427e-02 4.2712e-02 5.3809e-03 1.4833e-02 -6.0000e+00 5.4518e-02 -1.5599e-02 3.1793e-03 7.2349e-03 -6.0000e+00 3.2355e-02 2.1709e-03 1.4906e-03 2.0491e-03 -6.0000e+00 1.3353e-02 2.4643e-04 9.4956e-04 1.1027e-04 2.7240e-05 -6.0000e+00 1.0327e-03 2.5928e-02 0.0000e+00 12 9 9 12 1 1 99.73 23.80 -0.26 0.02593 0.03306 5 2 1 8 0 3305.560 20.00 23.80 23.44 33.50 33.25 3.0 958.66 2979 -8388 -3732 -9078 3859 -9480 4949 -15651 13368 9498 -5236 -3901 -1654 4743 3848 5759 -6230 -1920 10646 6500 2245 3339 -5268 -1868 -3324 1559 -2396 -2490 2159 2328 -1019 -5717 1569 -1475 -1128 -1337 1646 84 -2529 606 133 -2486 -1139 1443 -906 45 1632 -2234 1324 -109 2507 1160 1484 259 725 -2719 843 2507 543 2067 2883 826 704 2012 596 -2270 -384 -1142 1924 1442 456 -1501 145 348 1679 -1332 -90 -568 629 181 -1103 -823 -1745 -1879 -1240 -778 -1744 -1080 705 -410 230 1455 81 2925 1520 1241 373 -388 -1149 -1277 -496 -298 -191 433 856 -2018 -160 -425 -1094 -436 296 387 -1019 455 1526 1315 1544 1202 -297 -598 -825 -84 -487 151 -502 2300 -158 1453 1404 483 198 248 -33 437 -439 -127 -222 -16 -566 -316 -446 396 -810 336 -1123 -484 -1156 399 -1118 539 -2319 1616 1247 -801 -629 -296 903 759 1215 -1544 -479 2428 1601 586 860 -1533 -553 -1040 477 -755 -743 590 638 -309 -1932 530 -524 -380 -463 611 36 -1223 324 77 -1548 -667 898 -532 29 994 -1395 791 -67 1593 736 986 184 525 -2084 634 1848 403 1517 2168 677 574 1705 510 -1871 -321 -952 1534 1287 440 -1427 145 333 1482 -1101 -73 -450 515 154 -1054 -806 -1844 -2088 -1375 -913 -2165 -1365 873 -496 257 1590 83 2879 1600 1430 446 -511 -1510 -1658 -646 -362 -221 511 1079 -2581 -211 -588 -1600 -634 449 593 -1534 674 2085 1707 1991 1607 -425 -856 -1206 -121 -724 215 -685 3129 -211 1908 1840 678 293 360 -49 672 -719 -205 -368 -27 -969 -529 -722 652 -1322 SS 20260511T064044.4Z 9627.278292 198 1 53.99 2 58.28 93.09 50.56 188.18 0.00 1 0.00 1 0 25 1.252e-02 8.517e-03 1.845e-03 8.398e-04 2.811948e-01 4.631818e-04 3.317697e-03 -6.000000e+00 7.836834e-03 230.27 -2.00 3.48 -2.00 316.40 0.00e+00 1.182664e-04 5.307416e-05 4.980815e-05 -6.000000e+00 3.404230e-04 279.28 -2.00 20.00 -2.00 315.74 0.00e+00 1.895 0.000 302.00 328.00 3 4.1991e+00 1.2090e-03 2.2644e-02 -6.0000e+00 1.9589e-02 3.4996e-02 1.3455e-03 1.4333e-02 -6.0000e+00 2.1176e-02 -1.5098e-02 7.7570e-04 7.0045e-03 -6.0000e+00 1.2568e-02 7.1204e-04 3.5006e-04 1.9470e-03 -6.0000e+00 5.1879e-03 9.7388e-04 8.5730e-04 2.7713e-05 2.7251e-05 -6.0000e+00 4.0110e-04 2.4910e-02 0.0000e+00 11 9 0 11 8 0 99.94 23.80 0.22 0.02491 0.03135 72 8 1 8 0 749.650 20.00 23.80 23.47 33.50 33.25 3.1 958.55 -3861 -3644 -1513 -4209 228 -1728 -228 -4086 3271 1185 -3833 -1675 932 -74 -143 1007 -1967 -212 2480 2333 1215 1393 -101 67 -283 543 -173 -939 1444 581 1360 -1722 1144 -224 -2196 -468 -49 -148 -621 -497 -928 -1720 -938 -657 -585 94 -79 -412 382 500 1428 1066 662 1001 161 -80 1110 1189 766 1302 1510 981 665 945 346 -1157 732 228 1222 1622 -480 -801 -737 -568 410 -41 636 352 618 324 -1349 -1167 -1832 -2380 -1165 -1027 -1106 -816 -356 -243 115 1328 897 2007 1928 1052 -6 -460 -645 -1260 -391 -305 -126 632 696 -1377 -478 -538 -756 -201 -207 -92 -428 172 832 1180 1813 1088 298 41 -744 -529 -380 139 222 1658 338 1054 1373 410 16 43 -268 252 119 156 -622 -312 -381 -485 -302 65 -442 -668 -666 -275 -731 35 -269 -37 -770 625 241 -825 -375 211 -19 -42 316 -611 -68 801 782 419 478 -36 25 -112 219 -70 -359 517 210 520 -722 465 -94 -894 -192 -22 -72 -358 -307 -585 -1139 -636 -448 -397 64 -53 -270 245 326 975 778 482 764 128 -65 904 964 616 1045 1248 824 569 849 312 -1040 618 191 1077 1506 -464 -806 -736 -546 384 -37 525 297 515 287 -1280 -1215 -1960 -2571 -1334 -1196 -1350 -1018 -442 -291 133 1473 930 2111 2039 1170 -7 -573 -848 -1644 -481 -366 -150 765 867 -1761 -635 -722 -1066 -287 -299 -134 -631 238 1104 1538 2336 1459 409 58 -1069 -752 -546 193 302 2148 441 1369 1805 556 23 61 -392 380 183 244 -1000 -511 -630 -785 -473 101 -683 SS 20260511T064549.3Z 9627.281821 200 1 54.46 2 57.31 93.96 50.68 189.76 0.00 1 0.00 1 0 25 1.093e-02 8.315e-03 1.100e-03 5.689e-04 2.735559e-01 3.154357e-04 3.235933e-03 -6.000000e+00 6.842998e-03 230.27 -2.00 3.48 -2.00 316.04 0.00e+00 1.322137e-04 3.317797e-05 4.340797e-05 -6.000000e+00 2.972487e-04 279.29 -2.00 20.00 -2.00 315.40 0.00e+00 1.845 0.000 302.00 328.00 3 3.5352e+00 8.1964e-04 2.2036e-02 -6.0000e+00 1.7104e-02 3.1006e-02 9.1134e-04 1.3928e-02 -6.0000e+00 1.8491e-02 -1.6150e-02 5.2127e-04 6.8070e-03 -6.0000e+00 1.0974e-02 1.3863e-03 2.3034e-04 1.8927e-03 -6.0000e+00 4.5300e-03 2.0075e-03 8.3953e-04 1.8670e-05 2.6833e-05 -6.0000e+00 3.5023e-04 2.4828e-02 0.0000e+00 11 8 0 10 0 0 99.61 23.80 0.22 0.02483 0.03114 131 14 1 8 0 415.590 20.00 23.80 23.51 33.50 33.25 3.1 958.93 -3071 -3278 -1426 -3801 -738 -1602 -1016 -1707 1262 -265 -2904 -1727 764 -234 50 852 -1396 553 1952 1924 1344 840 744 860 220 546 35 -490 1080 939 1606 -887 972 -157 -2850 -262 -579 -324 -351 -365 -1351 -1728 -632 -857 -589 -38 -337 10 329 335 1276 1000 564 1061 98 247 1185 847 902 1362 1300 1175 402 785 260 -976 891 319 1106 1478 -524 -790 -918 -485 309 -137 829 294 581 324 -1365 -1184 -1814 -2274 -1102 -981 -983 -689 -402 -277 25 1270 936 1773 1809 942 -85 -423 -696 -1190 -411 -219 -134 594 754 -1230 -668 -629 -705 -202 -201 -122 -484 169 691 1147 1832 1085 426 69 -599 -584 -425 127 367 1654 480 962 1350 483 214 9 -259 135 224 117 -663 -308 -378 -583 -331 39 -470 -634 -717 -310 -788 -137 -298 -200 -375 293 -65 -736 -424 206 -72 16 295 -513 209 703 718 512 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