File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260513_L2Fit_fwvt1c3d20250801p1-8.txt
File generation date: 20260513T225746.7Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Marco Rosoldi
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 295
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora295_OF_v3d20250430.txt
Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt
Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260513_L1_smca1c3d20250801p1-8.txt
Full location name: CNR-IMAA Atmospheric Observatory (CIAO)
Short location name: TitoScaloPZ-CNR-IMAA
Country of location: Italy
Location latitude [deg]: 40.6012
Location longitude [deg]: 15.7237
Location altitude [m]: 768
Local noon date: 20260513
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1620 1770
Nominal wavelengths inside fitting window [nm]: 492.0392 492.1596 492.2800 492.4004 492.5207 492.6411 492.7614 492.8817 493.0020 493.1223 493.2426 493.3628 493.4830 493.6033 493.7234 493.8436 493.9638 494.0839 494.2041 494.3242 494.4443 494.5643 494.6844 494.8045 494.9245 495.0445 495.1645 495.2845 495.4044 495.5244 495.6443 495.7642 495.8841 496.0040 496.1238 496.2437 496.3635 496.4833 496.6031 496.7229 496.8426 496.9624 497.0821 497.2018 497.3215 497.4412 497.5608 497.6805 497.8001 497.9197 498.0393 498.1588 498.2784 498.3979 498.5174 498.6369 498.7564 498.8759 498.9954 499.1148 499.2342 499.3536 499.4730 499.5924 499.7117 499.8310 499.9504 500.0697 500.1889 500.3082 500.4274 500.5467 500.6659 500.7851 500.9043 501.0234 501.1426 501.2617 501.3808 501.4999 501.6190 501.7380 501.8571 501.9761 502.0951 502.2141 502.3331 502.4520 502.5710 502.6899 502.8088 502.9277 503.0466 503.1654 503.2842 503.4031 503.5219 503.6407 503.7594 503.8782 503.9969 504.1156 504.2343 504.3530 504.4717 504.5903 504.7090 504.8276 504.9462 505.0647 505.1833 505.3018 505.4204 505.5389 505.6574 505.7759 505.8943 506.0128 506.1312 506.2496 506.3680 506.4863 506.6047 506.7230 506.8414 506.9597 507.0780 507.1962 507.3145 507.4327 507.5509 507.6691 507.7873 507.9055 508.0236 508.1418 508.2599 508.3780 508.4960 508.6141 508.7321 508.8502 508.9682 509.0862 509.2041 509.3221 509.4400 509.5580 509.6759 509.7938 509.9116
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20260513T064916.6Z 9629.284219 11 1 12.32 2 56.35 94.07 39.43 158.10 0.00 1 0.00 1 0 15 2.012e-03 2.009e-03 1.121e-04 1.120e-04 1.701888e+03 6.439507e+00 1.211107e+02 -6.000000e+00 1.100205e+02 279.52 -2.00 20.00 -2.00 505.25 0.00e+00 3.415609e-04 3.040050e-06 1.968764e-05 -6.000000e+00 5.576543e-05 279.52 -2.00 20.00 -2.00 500.45 0.00e+00 5.225522e-02 2.207443e-03 1.404531e-02 -6.000000e+00 3.998009e-02 230.43 -2.00 3.48 -2.00 502.04 0.00e+00 1.799 0.000 489.00 513.00 1 2.5016e+00 1.6885e-04 2.6746e-03 -6.0000e+00 3.0592e-03 -2.5717e-03 4.3881e-05 3.4725e-04 -6.0000e+00 7.9724e-04 1.2577e-01 5.9499e-04 1.0334e-05 1.5523e-05 -6.0000e+00 1.9068e-04 -2.2592e-03 -6.7738e-05 10 0 0 10 0 0 98.69 23.07 1.53 -0.00226 0.00187 537 208 4 2 0 22.930 20.00 23.07 25.77 33.00 32.75 2.9 964.75 -288 -232 -261 0 -90 -6 330 234 255 238 31 200 -98 -158 -100 -209 -144 -169 119 -38 -146 116 137 170 403 246 131 177 118 -232 -145 82 -227 52 223 -132 -177 34 67 -55 29 85 119 132 229 257 208 170 86 38 -228 -284 -259 -494 -292 -172 -260 -113 -109 41 118 247 279 127 247 101 57 -7 29 -60 -236 -44 -64 -185 26 -80 -272 -253 -160 -111 -318 -195 -202 -353 -101 -15 -146 -102 -40 20 105 66 317 285 153 49 176 24 -200 -127 -333 -285 -314 -305 -25 -432 -398 -203 -202 -96 110 51 40 205 216 236 367 466 435 284 274 301 154 218 406 105 65 238 33 29 239 -97 -194 -29 -93 -240 43 46 -196 -131 47 -10 29 126 41 31 7 -179 -256 -196 -149 -279 -227 -260 0 -92 -6 343 244 266 248 32 205 -99 -159 -100 -210 -147 -173 122 -39 -152 121 143 177 421 257 136 184 121 -234 -145 82 -228 53 231 -137 -185 35 69 -56 29 87 123 136 236 267 215 176 87 38 -228 -279 -253 -483 -288 -171 -262 -115 -111 41 119 250 285 130 251 102 58 -7 29 -59 -230 -42 -63 -182 26 -79 -268 -248 -154 -107 -307 -188 -197 -343 -99 -15 -145 -101 -40 20 104 66 316 288 154 49 173 24 -193 -121 -317 -270 -304 -298 -24 -432 -395 -201 -199 -94 108 50 40 206 218 239 372 470 438 286 274 298 152 214 401 104 63 234 32 29 234 -95 -188 -27 -89 -230 42 45 -193 -129 47 -10 29 126 41 32 7 -177 -249 -189 -143
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SQ 20260513T064941.5Z 9629.284508 11 3 12.32 2 56.27 94.15 39.40 158.25 0.00 1 0.00 1 0 15 2.020e-03 2.016e-03 1.161e-04 1.159e-04 1.701326e+03 6.662219e+00 1.213251e+02 -6.000000e+00 1.104861e+02 279.52 -2.00 20.00 -2.00 505.25 0.00e+00 3.497812e-04 3.145498e-06 2.010584e-05 -6.000000e+00 5.600168e-05 279.52 -2.00 20.00 -2.00 500.45 0.00e+00 5.371965e-02 2.283519e-03 1.398618e-02 -6.000000e+00 4.015015e-02 230.43 -2.00 3.48 -2.00 502.04 0.00e+00 1.795 0.000 489.00 513.00 1 2.5712e+00 1.7467e-04 2.6702e-03 -6.0000e+00 3.0722e-03 -2.7039e-03 4.5383e-05 3.4643e-04 -6.0000e+00 8.0065e-04 1.1734e-01 6.5743e-04 1.0692e-05 1.5702e-05 -6.0000e+00 1.9149e-04 -1.7046e-03 -7.3075e-05 10 0 0 10 0 0 99.66 23.07 1.53 -0.00170 0.00286 537 208 4 2 0 22.930 20.00 23.07 25.77 33.00 32.75 2.9 964.75 -274 -226 -276 -2 -85 16 354 237 232 239 50 176 -120 -147 -100 -207 -147 -161 91 -33 -155 151 119 183 405 231 112 176 132 -236 -149 80 -229 47 237 -126 -170 29 40 -66 53 92 95 141 233 234 197 159 93 54 -209 -267 -263 -473 -290 -174 -261 -138 -114 44 104 252 271 148 267 90 77 0 20 -69 -276 -59 -59 -213 7 -91 -255 -251 -185 -119 -311 -177 -222 -356 -102 16 -148 -95 -34 35 121 78 311 279 149 42 166 28 -199 -108 -341 -276 -336 -362 -31 -413 -407 -198 -208 -75 118 54 44 198 234 275 385 472 406 259 274 296 145 237 419 96 48 222 18 27 244 -75 -169 -30 -118 -240 67 68 -191 -129 24 -10 62 136 36 21 6 -175 -264 -202 -153 -267 -219 -272 -2 -86 17 370 248 243 247 51 181 -122 -149 -100 -208 -148 -164 94 -34 -161 158 124 191 424 243 117 183 136 -239 -150 80 -230 48 246 -132 -176 30 41 -67 55 94 97 146 240 243 204 165 95 55 -207 -263 -255 -458 -284 -173 -264 -140 -117 45 105 257 277 150 272 91 77 0 20 -67 -269 -57 -59 -210 7 -90 -252 -245 -179 -115 -299 -172 -215 -346 -100 15 -146 -95 -34 34 119 77 311 280 151 41 164 28 -192 -104 -322 -262 -322 -354 -31 -414 -405 -197 -205 -74 115 54 44 198 236 279 387 477 409 261 272 293 143 233 410 95 47 219 18 26 239 -74 -163 -29 -112 -231 64 67 -188 -127 24 -9 62 135 36 21 6 -173 -257 -196 -148
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