File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260608_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260608T230752.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260608_L1_smca1c3d20250801p1-8.txt Full location name: CNR-IMAA Atmospheric Observatory (CIAO) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260608T041032.3Z 9655.173985 165 1 54.81 2 83.44 65.42 47.47 165.73 0.00 1 0.00 1 0 49 7.163e-01 6.425e-02 2.589e-01 1.646e-02 9.573811e-01 1.057335e-02 1.030494e-02 -6.000000e+00 4.768163e-01 231.96 -2.00 3.48 -2.00 321.98 0.00e+00 -1.080593e-02 4.853491e-03 4.994599e-03 -6.000000e+00 2.367097e-02 282.28 -2.00 20.00 -2.00 321.45 0.00e+00 7.953 0.009 302.00 328.00 3 2.5256e+00 3.6662e-02 9.7545e-02 -6.0000e+00 1.1993e+00 1.7131e+00 4.4484e-02 7.9498e-02 -6.0000e+00 1.3014e+00 -2.1137e+00 2.8293e-02 2.5642e-02 -6.0000e+00 7.6808e-01 8.1159e-01 1.4290e-02 1.5463e-02 -6.0000e+00 3.1788e-01 9.1587e-06 2.4146e-04 5.0940e-04 2.0143e-04 -6.0000e+00 2.4377e-02 1.7436e-03 0.0000e+00 12 8 8 10 0 0 98.95 23.72 0.52 0.00174 0.00356 21 2 4 8 0 2609.170 20.00 23.72 22.89 33.50 33.50 3.1 956.86 900000 150310 129610 35998 900000 -15522 900000 -82640 900000 900000 52578 -2766 900000 900000 900000 900000 -1583 22052 900000 900000 2956 900000 -18465 39690 13124 900000 22874 31237 900000 900000 53606 -33925 104969 53941 900000 61169 151134 351142 849 198170 313419 20519 58175 900000 41602 47430 900000 7168 900000 106422 42447 179568 119627 50351 106500 -17602 50224 214002 -5308 167631 900000 40597 36024 157782 96467 8771 6301 3694 55703 41100 65802 11206 99242 37593 77918 -11396 -18188 -2750 30269 38631 12859 21247 -5585 3269 -7214 -2765 -24228 1318 36885 -1416 5888 11908 -15208 70914 -4103 11996 15347 -1198 -10106 -10115 -2696 -2109 2577 3104 -3180 -26849 6155 -8760 -7982 52 -2909 4856 -3570 4490 12475 -181 4279 2022 -4999 -4070 -1103 3937 3633 2325 -1123 9902 1309 8561 4294 1153 -1890 2077 1766 3797 -4666 -1932 3153 -893 -4792 1244 -1104 5139 -2494 900000 4005 3798 2206 900000 -1241 900000 -13651 900000 900000 2521 -245 900000 900000 900000 900000 -189 2051 900000 900000 275 900000 -2013 2538 1106 900000 1562 1725 900000 900000 2493 -4092 3356 2822 900000 2667 2855 5613 95 3456 5010 2236 4227 900000 3144 3240 900000 719 900000 4330 3578 4593 5928 5312 6640 -3883 5620 4447 -916 4823 900000 4348 4434 6306 7402 1598 1209 768 7569 7227 9572 2848 9994 6430 7972 -2550 -4187 -567 5081 7040 3515 6114 -2312 1312 -3413 -1308 -14639 622 11969 -645 2344 4321 -7293 15530 -2184 6347 9077 -954 -9564 -9605 -2254 -1594 1706 2030 -2349 -26353 4634 -8360 -8472 58 -3459 6380 -4799 5579 15415 -226 5712 2867 -7207 -5932 -1522 5419 4821 3043 -1475 11492 1638 10633 6411 1852 -3518 4072 3736 8476 -12157 -5153 8110 -2411 -13300 3091 -2616 10703 -5374 SS 20260608T041634.5Z 9655.178177 168 1 54.34 2 82.40 66.34 47.19 167.70 0.00 1 0.00 1 0 25 4.824e-01 3.157e-02 2.422e-01 7.706e-03 9.323847e-01 4.802664e-03 1.046069e-02 -6.000000e+00 3.101321e-01 231.96 -2.00 3.48 -2.00 321.94 0.00e+00 1.394188e-02 2.722720e-03 2.476723e-03 -6.000000e+00 1.491118e-02 282.28 -2.00 20.00 -2.00 321.45 0.00e+00 7.022 0.006 302.00 328.00 3 2.4220e+00 1.8257e-02 8.2349e-02 -6.0000e+00 7.8077e-01 1.1685e+00 2.3529e-02 5.2177e-02 -6.0000e+00 8.4580e-01 -1.4821e+00 1.9196e-02 2.7561e-02 -6.0000e+00 4.9983e-01 5.8441e-01 8.8678e-03 1.3245e-02 -6.0000e+00 2.0597e-01 2.4599e-05 -1.0767e-03 2.2842e-04 2.5484e-04 -6.0000e+00 1.6101e-02 1.4031e-03 0.0000e+00 12 9 8 11 8 0 99.10 23.71 0.34 0.00140 -0.00669 43 5 4 8 0 1263.380 20.00 23.71 23.33 33.50 33.50 3.1 958.30 -106210 -13365 -2320 -79504 900000 -90069 48348 -150069 900000 900000 -51361 -139308 900000 76160 900000 900000 -63013 -19816 900000 900000 21083 900000 -75984 -19054 -30817 149554 -55090 51470 83869 67775 29691 -66583 38839 53838 110928 65620 195038 900000 8225 66704 172880 -6500 22221 54161 11758 19353 900000 -2491 103597 38389 47298 71076 71635 17339 54984 -2828 23239 89737 5518 68305 63510 22132 34532 59695 42420 5005 4424 12806 44302 21845 19608 5250 26037 7556 22545 -2484 -5918 -3775 4319 9680 7121 7472 3627 -2250 -5144 -2766 -10804 -1208 10193 -227 -275 5179 -9457 18192 -6657 1604 -181 -3369 -3930 -4331 -927 -82 -1507 -307 -2762 -12221 -819 -2869 -4716 -1006 -616 376 -2352 -752 3022 -39 2321 1228 -347 -741 109 1696 1499 1926 1378 4255 2542 1427 3555 302 230 1556 1270 -920 -1073 -270 891 -409 -986 686 -1318 955 -2261 -4489 -237 -36 -2385 900000 -2333 363 -6548 900000 900000 -840 -6458 900000 675 900000 900000 -3480 -757 900000 900000 503 900000 -4299 -598 -1050 1122 -2253 702 858 924 729 -4993 1139 1534 1664 1525 1463 900000 456 2301 2204 -517 1366 2437 811 1263 900000 -219 3341 2562 3192 4157 4459 1976 4412 -407 2562 4912 670 4354 4382 2539 3962 5999 5408 931 853 2391 6611 4587 4485 1409 5467 1762 4091 -523 -1251 -827 1004 2562 2264 2718 1512 -1053 -2631 -1450 -6360 -656 4900 -117 -134 2295 -4851 7599 -4104 1074 -131 -2908 -3751 -4196 -826 -66 -1228 -242 -2146 -10955 -698 -2727 -5109 -1203 -828 544 -3610 -1136 4295 -56 3304 1840 -552 -1210 173 2521 2138 2660 1850 5466 3279 1972 5528 510 437 3202 2813 -2236 -2578 -678 2241 -1052 -2531 1655 -3281 2176 -5087 SS 20260608T042909.8Z 9655.186919 171 1 54.36 2 80.19 68.25 46.72 171.86 0.00 1 0.00 1 0 17 6.051e-01 1.078e-02 1.182e-01 1.844e-03 7.966617e-01 1.077490e-03 8.886788e-03 -6.000000e+00 3.835744e-01 231.96 -2.00 3.48 -2.00 320.99 0.00e+00 7.244413e-03 5.057088e-04 1.769195e-03 -6.000000e+00 1.668096e-02 282.28 -2.00 20.00 -2.00 320.42 0.00e+00 5.610 0.003 302.00 328.00 3 1.7710e+00 3.5268e-03 6.6979e-02 -6.0000e+00 9.6234e-01 1.9197e-01 4.8168e-03 4.3337e-02 -6.0000e+00 1.0393e+00 -2.2249e-01 4.8346e-03 2.5905e-02 -6.0000e+00 6.1470e-01 7.2939e-02 2.2889e-03 1.2383e-02 -6.0000e+00 2.5242e-01 2.2307e-04 -3.1887e-04 5.2973e-05 1.5784e-04 -6.0000e+00 1.9604e-02 -3.1728e-05 0.0000e+00 12 8 8 10 0 0 34.27 23.72 0.40 -0.00003 -0.00243 164 17 4 8 0 331.410 20.01 23.72 24.16 33.50 33.50 3.0 962.41 -283621 -185206 -155874 -233139 -153176 -204180 900000 -251131 -154015 -111815 -194718 -170791 -36869 -101392 -79108 88429 -54732 -56539 136822 4380 -28510 -1876 -81568 -28103 -40379 18665 -28945 -46841 -28141 -14739 -26157 -47641 9760 -5025 9566 -7736 152 15116 -6392 -5476 3577 -7927 -207 -4019 1223 5703 14772 -1463 7714 3693 6515 11816 5200 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