File name: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260717_L2Fit_fout2c3d20250801p1-8.txt File generation date: 20260717T231337.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marco Rosoldi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 295 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora295_OF_v3d20250430.txt Instrument calibration file used: Pandora295s1_CF_v3d20250801.txt Level 1 file used: Pandora295s1_TitoScaloPZ-CNR-IMAA_20260717_L1_smca1c3d20250801p1-8.txt Full location name: CNR-IMAA Atmospheric Observatory (CIAO) Short location name: TitoScaloPZ-CNR-IMAA Country of location: Italy Location latitude [deg]: 40.6012 Location longitude [deg]: 15.7237 Location altitude [m]: 768 Local noon date: 20260717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2437 305.3841 305.5245 305.6649 305.8053 305.9457 306.0860 306.2264 306.3667 306.5071 306.6474 306.7877 306.9280 307.0683 307.2085 307.3488 307.4890 307.6293 307.7695 307.9097 308.0499 308.1901 308.3303 308.4705 308.6106 308.7508 308.8909 309.0310 309.1712 309.3113 309.4514 309.5914 309.7315 309.8716 310.0116 310.1516 310.2917 310.4317 310.5717 310.7117 310.8516 310.9916 311.1316 311.2715 311.4114 311.5514 311.6913 311.8312 311.9711 312.1109 312.2508 312.3906 312.5305 312.6703 312.8101 312.9499 313.0897 313.2295 313.3693 313.5091 313.6488 313.7885 313.9283 314.0680 314.2077 314.3474 314.4871 314.6267 314.7664 314.9060 315.0457 315.1853 315.3249 315.4645 315.6041 315.7437 315.8832 316.0228 316.1623 316.3019 316.4414 316.5809 316.7204 316.8599 316.9993 317.1388 317.2782 317.4177 317.5571 317.6965 317.8359 317.9753 318.1147 318.2541 318.3934 318.5328 318.6721 318.8114 318.9507 319.0900 319.2293 319.3686 319.5079 319.6471 319.7864 319.9256 320.0648 320.2040 320.3432 320.4824 320.6216 320.7607 320.8999 321.0390 321.1781 321.3172 321.4563 321.5954 321.7345 321.8736 322.0126 322.1517 322.2907 322.4297 322.5687 322.7077 322.8467 322.9857 323.1246 323.2636 323.4025 323.5414 323.6804 323.8193 323.9582 324.0970 324.2359 324.3748 324.5136 324.6524 324.7912 324.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260717T093206.5Z 9694.397297 53 1 54.31 2 27.43 128.30 64.71 100.95 0.00 1 0.00 1 0 17 9.264e-03 8.242e-03 9.795e-05 7.833e-05 1.539553e-01 4.445800e-05 1.865325e-03 -6.000000e+00 5.836951e-03 232.29 -2.00 3.48 -2.00 314.10 0.00e+00 9.158766e-05 3.252555e-06 1.120576e-05 -6.000000e+00 2.591187e-04 285.99 -2.00 20.00 -2.00 313.54 0.00e+00 1.126 0.000 302.00 328.00 3 5.9635e-01 1.1398e-04 1.3130e-02 -6.0000e+00 1.4629e-02 -4.3512e-04 1.2541e-04 7.9802e-03 -6.0000e+00 1.5779e-02 -2.2383e-03 7.1838e-05 3.8787e-03 -6.0000e+00 9.3849e-03 -3.1706e-03 2.9772e-05 1.0604e-03 -6.0000e+00 3.8798e-03 9.1576e-02 2.1359e-04 2.5600e-06 1.7538e-05 -6.0000e+00 2.9695e-04 2.8663e-03 0.0000e+00 11 8 0 10 0 0 99.97 30.31 0.35 0.00287 0.00447 4676 491 2 8 0 11.610 20.07 30.31 39.64 37.75 37.50 2.7 1024.90 -97 -1858 -618 -2685 -1639 485 356 1327 1148 265 -1794 -199 703 -76 629 15 -854 608 345 1333 1282 105 1271 731 204 584 193 -504 705 1158 1809 -29 1433 -65 -3091 -502 -621 -530 -216 -767 -1783 -1692 -901 -1188 -859 -148 -857 20 -107 171 1275 999 461 1072 68 529 1067 672 844 1106 977 1059 453 764 288 -866 987 186 1067 1665 -429 -478 -961 -346 149 24 778 60 403 365 -1261 -1117 -1747 -2216 -818 -897 -767 -671 -469 -152 38 1177 792 1378 1915 982 -212 -183 -393 -1034 -393 -265 -403 492 740 -1192 -739 -581 -813 -130 -126 -70 -277 291 544 961 1611 866 417 201 -491 -639 -226 160 382 1759 352 822 1288 459 317 -33 -396 -78 261 177 -788 -273 -234 -616 -225 17 -526 -44 -879 -286 -1218 -672 202 149 602 535 127 -863 -97 355 -40 349 9 -493 356 206 812 788 65 793 457 132 383 124 -317 412 685 1095 -18 906 -42 -1926 -311 -406 -370 -163 -617 -1500 -1471 -796 -1054 -753 -127 -721 16 -89 141 1051 867 405 945 61 484 982 618 768 1010 895 1027 454 767 283 -839 907 168 1003 1626 -444 -500 -1005 -357 148 23 698 53 365 341 -1236 -1158 -1882 -2446 -932 -1062 -928 -813 -567 -181 44 1274 832 1424 1985 1075 -242 -215 -484 -1259 -464 -302 -455 555 874 -1470 -926 -740 -1053 -172 -171 -95 -369 367 663 1127 1912 1045 523 257 -636 -845 -292 203 470 2100 416 957 1557 571 400 -41 -511 -102 347 242 -1091 -386 -334 -869 -316 23 -727 SS 20260717T093855.7Z 9694.402033 56 1 54.32 2 26.43 131.04 63.49 102.18 0.00 1 0.00 1 0 17 9.286e-03 8.326e-03 9.536e-05 7.625e-05 1.529043e-01 4.323509e-05 1.854744e-03 -6.000000e+00 5.850825e-03 232.29 -2.00 3.48 -2.00 314.10 0.00e+00 8.377589e-05 3.175939e-06 1.162603e-05 -6.000000e+00 2.597356e-04 285.99 -2.00 20.00 -2.00 313.54 0.00e+00 1.116 0.000 302.00 328.00 3 5.5183e-01 1.1086e-04 1.3031e-02 -6.0000e+00 1.4664e-02 -5.4587e-04 1.2197e-04 7.9345e-03 -6.0000e+00 1.5816e-02 -2.4150e-03 6.9853e-05 3.8576e-03 -6.0000e+00 9.4072e-03 -3.0685e-03 2.8964e-05 1.0556e-03 -6.0000e+00 3.8890e-03 9.6834e-02 2.6079e-04 2.4894e-06 1.7626e-05 -6.0000e+00 2.9766e-04 2.8866e-03 0.0000e+00 11 8 0 10 0 0 37.11 28.69 0.35 0.00289 0.00485 4697 493 2 8 0 11.560 20.00 28.69 41.72 36.75 36.75 2.5 1028.35 -219 -1917 -704 -2704 -1507 533 437 1284 1103 228 -1689 -136 702 -52 608 -3 -823 590 357 1333 1248 162 1278 740 234 540 184 -475 748 1208 1766 13 1340 -160 -3017 -413 -558 -452 -239 -827 -1821 -1688 -924 -1209 -859 -175 -871 14 -102 225 1299 1013 482 1062 71 522 1046 659 870 1108 1014 1050 427 697 211 -844 1023 265 1157 1634 -465 -515 -997 -369 111 41 831 157 486 370 -1258 -1125 -1751 -2182 -819 -920 -777 -701 -507 -210 13 1180 842 1471 1955 1006 -187 -225 -453 -1075 -400 -245 -297 510 696 -1213 -736 -580 -810 -155 -158 -132 -321 279 579 1043 1646 901 421 148 -545 -659 -274 139 374 1746 400 893 1293 469 311 -43 -378 -34 252 173 -790 -286 -270 -618 -230 17 -490 -102 -893 -321 -1205 -636 217 188 572 530 108 -797 -65 349 -27 346 -2 -488 354 211 802 758 99 787 476 150 350 117 -295 448 704 1054 8 836 -101 -1851 -252 -361 -323 -186 -683 -1571 -1459 -812 -1067 -749 -150 -750 11 -84 185 1096 872 420 958 63 474 957 603 786 1005 951 1013 426 697 213 -811 932 244 1078 1586 -479 -536 -1037 -379 110 39 761 137 435 343 -1259 -1159 -1876 -2397 -929 -1085 -938 -848 -612 -249 15 1302 878 1508 2066 1094 -212 -269 -556 -1304 -470 -278 -333 587 820 -1490 -918 -737 -1047 -208 -215 -178 -425 359 702 1246 1941 1080 525 189 -719 -868 -352 175 458 2125 470 1059 1553 580 391 -54 -485 -43 333 235 -1114 -402 -384 -869 -321 23 -675 SS 20260717T094418.0Z 9694.405763 58 1 54.32 2 25.67 133.31 62.53 103.16 0.00 1 0.00 1 0 17 9.321e-03 8.364e-03 9.472e-05 7.586e-05 1.518086e-01 4.304774e-05 1.845108e-03 -6.000000e+00 5.872526e-03 232.29 -2.00 3.48 -2.00 314.09 0.00e+00 8.015625e-05 3.150396e-06 1.108401e-05 -6.000000e+00 2.606947e-04 285.99 -2.00 20.00 -2.00 313.53 0.00e+00 1.109 0.000 302.00 328.00 3 5.5220e-01 1.1038e-04 1.2948e-02 -6.0000e+00 1.4718e-02 -8.6224e-04 1.2145e-04 7.8862e-03 -6.0000e+00 1.5875e-02 -2.3572e-03 6.9548e-05 3.8336e-03 -6.0000e+00 9.4421e-03 -3.0003e-03 2.8815e-05 1.0477e-03 -6.0000e+00 3.9035e-03 9.7659e-02 2.2313e-04 2.4762e-06 1.7588e-05 -6.0000e+00 2.9876e-04 2.7673e-03 0.0000e+00 11 8 0 10 0 0 99.10 27.90 0.34 0.00277 0.00444 4701 493 2 8 0 11.550 20.00 27.90 42.72 36.25 36.00 2.4 1030.77 -185 -1921 -692 -2705 -1482 576 546 1301 1134 237 -1660 -98 720 -65 588 -7 -814 590 347 1276 1238 191 1302 731 222 524 125 -484 767 1268 1798 -11 1331 -179 -2975 -355 -555 -452 -263 -877 -1804 -1699 -939 -1198 -882 -204 -855 -4 -78 230 1282 989 483 1057 59 518 1042 656 873 1129 1030 1066 415 663 190 -812 1051 315 1182 1618 -462 -520 -1006 -391 137 56 865 201 524 374 -1262 -1142 -1773 -2167 -827 -920 -801 -719 -536 -227 9 1176 871 1510 1974 1012 -182 -231 -481 -1077 -411 -247 -254 531 691 -1192 -721 -570 -782 -137 -187 -133 -312 272 602 1062 1676 939 407 129 -556 -682 -285 132 366 1745 453 938 1312 472 308 -40 -361 -16 238 161 -787 -300 -301 -615 -230 20 -480 -83 -906 -319 -1219 -632 238 238 586 525 114 -792 -47 361 -35 325 -4 -487 344 207 775 758 117 808 456 143 342 80 -302 463 744 1080 -7 836 -114 -1836 -218 -361 -325 -199 -728 -1519 -1478 -830 -1062 -773 -176 -740 -4 -65 190 1087 856 423 957 54 472 958 603 792 1029 969 1032 415 666 192 -783 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