File name: Pandora192s1_Tokyo-Sophia_20240920_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T125916.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240920_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240919T213335.1Z 9028.898323 251 1 35.40 2 77.45 97.90 78.52 273.67 0.00 1 0.00 1 0 25 2.165e-01 1.340e-02 2.518e-02 1.493e-03 4.682503e-01 8.268718e-04 6.686509e-03 -6.000000e+00 1.352439e-01 228.93 -2.00 3.41 -2.00 320.53 0.00e+00 2.999062e-03 3.297752e-04 6.672899e-03 -6.000000e+00 6.195195e-03 290.36 -2.00 20.00 -2.00 319.73 0.00e+00 4.474 0.001 302.00 328.00 3 8.6289e-01 2.6567e-03 5.9688e-02 -6.0000e+00 3.3530e-01 4.2369e-02 3.2754e-03 4.9232e-02 -6.0000e+00 3.6284e-01 -1.1042e-01 2.5226e-03 1.7873e-02 -6.0000e+00 2.1723e-01 3.7024e-02 1.2375e-03 3.3239e-03 -6.0000e+00 8.9597e-02 1.6650e-03 9.4094e-04 5.3094e-05 1.0862e-04 -6.0000e+00 7.4064e-03 1.2456e-02 0.0000e+00 12 9 9 12 1 1 75.05 16.27 0.45 0.01246 0.01953 255 78 1 5 0 138.210 20.77 15.00 16.27 34.41 8.8 974.89 -66596 -70035 -58212 -71904 -76881 -83833 -80080 -58345 -67470 -64756 -53477 -66440 -44691 -40765 -16751 -19454 -13380 -10147 -7059 -10134 -9904 -10788 -5659 -6908 -8979 -10059 -13328 -14623 -15448 -9201 -9948 -6067 -5658 -5709 -8705 -9675 -6970 -3269 811 3056 6978 7257 4706 5951 6526 5039 4331 3135 1758 815 3925 3707 4833 3261 3718 3444 1930 1641 751 681 2946 4055 4350 4082 2647 675 106 33 1429 2788 2671 2162 996 19 -2173 -4500 -5635 -6507 -5374 -3787 -3118 -2313 -2109 -650 -278 1264 1991 2306 1639 988 260 -1907 -2639 -2943 -2163 -735 179 691 198 -721 -2041 -2562 -1839 -1847 -1554 -962 -341 834 1752 2282 2034 1464 674 -338 -953 -835 -245 161 748 963 1103 1450 1047 489 -439 -1067 -996 -883 -636 -662 -872 -839 -648 -142 81 570 705 806 505 3 -301 -660 -192 -1102 -1354 -1048 -1456 -1557 -1787 -1728 -1112 -1545 -1543 -1210 -1900 -1213 -1284 -494 -677 -485 -385 -277 -428 -429 -528 -272 -355 -498 -584 -803 -879 -933 -548 -662 -438 -447 -471 -741 -851 -655 -345 97 415 1012 1124 781 1001 1109 880 770 572 334 165 830 856 1191 870 1036 994 576 491 225 206 912 1347 1578 1591 1070 273 42 14 628 1341 1392 1176 544 10 -1088 -2120 -2536 -2981 -2649 -2089 -1943 -1593 -1575 -512 -233 1111 1821 2152 1531 895 223 -1572 -2115 -2423 -1925 -725 179 760 231 -839 -2279 -2689 -2031 -2084 -1680 -1098 -411 1060 2385 3349 3181 2358 1077 -522 -1407 -1197 -353 241 1174 1562 1796 2310 1626 737 -642 -1517 -1403 -1296 -1010 -1145 -1617 -1636 -1324 -304 169 1228 1562 1805 1126 6 -688 -1465 -424 SS 20240919T213912.8Z 9028.902231 254 1 49.18 2 76.32 98.76 79.60 274.47 0.00 1 0.00 1 0 33 1.721e-01 1.307e-02 1.596e-02 1.013e-03 4.374925e-01 5.589339e-04 6.250366e-03 -6.000000e+00 1.075137e-01 228.93 -2.00 3.41 -2.00 320.36 0.00e+00 2.761881e-03 2.096702e-04 5.871504e-03 -6.000000e+00 4.925406e-03 290.36 -2.00 20.00 -2.00 319.55 0.00e+00 4.129 0.001 302.00 328.00 3 6.6378e-01 1.7449e-03 5.3990e-02 -6.0000e+00 2.6655e-01 1.5613e-02 2.1328e-03 4.3282e-02 -6.0000e+00 2.8845e-01 -7.1403e-02 1.6326e-03 1.6050e-02 -6.0000e+00 1.7269e-01 2.1887e-02 8.1090e-04 3.0902e-03 -6.0000e+00 7.1221e-02 2.9152e-03 8.1701e-04 3.6320e-05 7.8171e-05 -6.0000e+00 5.8885e-03 1.3047e-02 0.0000e+00 12 8 8 10 0 0 66.39 16.27 0.44 0.01305 0.01919 581 128 1 5 0 84.620 20.77 15.00 16.27 35.00 8.8 977.73 -67273 -62320 -47749 -55490 -51014 -69460 -61196 -58983 -53112 -45762 -46501 -29802 -35976 -18426 -18119 -12654 -5220 -5194 -3358 -7034 -3130 -5015 -6575 -3408 -7050 -5382 -11114 -10495 -13582 -13697 -6158 -6705 -4830 -7375 -8607 -9210 -7195 -1780 477 3184 3673 4048 5254 4820 5091 2886 3587 1675 1410 1839 2518 3428 3597 3579 2612 2106 1704 107 911 667 2420 3839 4429 4147 2339 1043 -514 -396 1196 1868 2490 1494 1031 -184 -1837 -4014 -6048 -5803 -5322 -3956 -3347 -2265 -1916 -980 551 1303 2060 2199 1745 1167 -56 -1490 -2751 -2642 -2014 -836 337 480 339 -744 -1680 -2257 -2034 -1635 -1398 -753 -347 896 1871 2496 2320 1369 773 -252 -928 -822 -291 286 663 1013 1193 1393 1036 365 -312 -1206 -1116 -1017 -758 -603 -886 -873 -718 -250 43 477 716 604 509 91 -239 -546 -276 -1366 -1355 -939 -1156 -967 -1554 -1325 -1372 -1279 -1093 -1186 -709 -1066 -549 -638 -482 -203 -218 -147 -334 -147 -245 -337 -178 -445 -346 -760 -701 -929 -977 -448 -550 -426 -695 -821 -904 -759 -207 64 483 614 722 966 913 976 572 711 342 296 402 588 861 972 1029 794 665 550 35 294 218 813 1376 1723 1727 1010 446 -218 -172 553 950 1362 857 591 -102 -964 -1978 -2865 -2753 -2720 -2258 -2152 -1602 -1465 -793 470 1172 1929 2106 1669 1082 -50 -1249 -2245 -2194 -1802 -828 371 527 392 -862 -2047 -2588 -2246 -1840 -1659 -942 -417 1132 2523 3611 3561 2166 1206 -379 -1332 -1143 -407 415 1010 1596 1891 2165 1570 536 -444 -1835 -1679 -1589 -1160 -1000 -1570 -1623 -1395 -511 91 1066 1640 1402 1175 204 -521 -1155 -582 SS 20240919T215000.3Z 9028.909726 257 1 49.20 2 74.17 100.43 81.69 276.00 0.00 1 0.00 1 0 25 1.031e-01 1.239e-02 8.370e-03 6.864e-04 3.919995e-01 3.737575e-04 5.254469e-03 -6.000000e+00 6.442142e-02 228.93 -2.00 3.41 -2.00 319.86 0.00e+00 2.463100e-03 1.183957e-04 3.904465e-03 -6.000000e+00 2.951223e-03 290.36 -2.00 20.00 -2.00 319.00 0.00e+00 3.600 0.001 302.00 328.00 3 5.9735e-01 1.1110e-03 4.4204e-02 -6.0000e+00 1.5971e-01 9.4730e-03 1.3240e-03 3.0505e-02 -6.0000e+00 1.7284e-01 -3.9102e-02 9.5380e-04 1.2607e-02 -6.0000e+00 1.0347e-01 5.7034e-03 4.7890e-04 2.5642e-03 -6.0000e+00 4.2675e-02 5.3809e-03 6.4416e-04 2.4589e-05 6.4358e-05 -6.0000e+00 3.5283e-03 1.2955e-02 0.0000e+00 12 8 8 10 0 0 99.06 16.27 0.44 0.01295 0.01780 780 171 1 5 0 63.060 20.87 15.01 16.27 36.19 8.7 981.67 -34867 -27025 -32366 -30947 -36020 -41492 -34002 -35634 -29593 -32852 -28137 -27170 -19696 -10751 -9783 -4943 -4642 -2865 -1584 -1825 -1024 -3538 -1913 -3866 -2792 -3713 -6495 -6656 -9991 -8087 -5904 -4725 -3156 -6263 -6773 -9118 -5433 -2156 755 2875 2457 3335 2645 3069 3328 2838 2295 891 452 471 1111 2112 2469 2830 2039 1917 995 440 592 977 2284 2908 3909 2957 1953 585 -520 -227 626 1721 1732 1596 1110 -195 -1478 -3755 -5115 -5502 -4724 -3443 -2905 -2203 -1954 -829 162 1351 1947 2034 1867 1133 0 -1344 -2389 -2467 -1639 -690 343 672 334 -455 -1447 -2165 -1873 -1620 -1403 -879 -370 806 1605 2222 2090 1461 654 -206 -801 -928 -368 257 598 896 1054 1266 751 301 -357 -1083 -1058 -1027 -837 -749 -882 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