File name: Pandora192s1_Tokyo-Sophia_20240925_L2Fit_fwvt1c5d20240824p1-8.txt File generation date: 20250716T125737.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240925_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0126 492.1343 492.2560 492.3777 492.4994 492.6210 492.7426 492.8643 492.9859 493.1074 493.2290 493.3506 493.4721 493.5936 493.7151 493.8366 493.9581 494.0795 494.2010 494.3224 494.4438 494.5652 494.6865 494.8079 494.9292 495.0505 495.1718 495.2931 495.4144 495.5357 495.6569 495.7781 495.8993 496.0205 496.1417 496.2628 496.3840 496.5051 496.6262 496.7473 496.8684 496.9894 497.1105 497.2315 497.3525 497.4735 497.5945 497.7154 497.8364 497.9573 498.0782 498.1991 498.3200 498.4408 498.5617 498.6825 498.8033 498.9241 499.0449 499.1656 499.2864 499.4071 499.5278 499.6485 499.7692 499.8898 500.0105 500.1311 500.2517 500.3723 500.4929 500.6135 500.7340 500.8545 500.9750 501.0955 501.2160 501.3365 501.4569 501.5774 501.6978 501.8182 501.9385 502.0589 502.1792 502.2996 502.4199 502.5402 502.6605 502.7807 502.9010 503.0212 503.1414 503.2616 503.3818 503.5020 503.6221 503.7422 503.8624 503.9824 504.1025 504.2226 504.3426 504.4627 504.5827 504.7027 504.8227 504.9426 505.0626 505.1825 505.3024 505.4223 505.5422 505.6621 505.7819 505.9017 506.0216 506.1414 506.2611 506.3809 506.5007 506.6204 506.7401 506.8598 506.9795 507.0991 507.2188 507.3384 507.4580 507.5776 507.6972 507.8168 507.9363 508.0559 508.1754 508.2949 508.4143 508.5338 508.6533 508.7727 508.8921 509.0115 509.1309 509.2502 509.3696 509.4889 509.6082 509.7275 509.8468 509.9661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240924T203624.3Z 9033.858615 225 1 50.06 2 89.80 91.26 7.13 175.33 0.00 1 0.00 1 0 82 3.793e-01 2.365e-01 2.117e-01 1.645e-01 -2.387319e+02 1.010243e+04 1.293076e+03 -6.000000e+00 2.228714e+04 289.84 -2.00 20.00 -2.00 505.19 0.00e+00 5.310365e-03 4.653395e-03 1.254030e-04 -6.000000e+00 1.101337e-02 289.84 -2.00 20.00 -2.00 499.88 0.00e+00 -8.330803e-01 3.397494e+00 2.097593e-01 -6.000000e+00 7.630332e+00 228.48 -2.00 3.41 -2.00 501.58 0.00e+00 20.028 0.128 489.00 513.00 1 1.0645e+01 2.6243e-01 3.7090e-02 -6.0000e+00 5.8622e-01 2.5158e-01 6.4796e-02 3.0158e-03 -6.0000e+00 1.5143e-01 2.4422e-06 1.4606e-02 1.6315e-02 1.9853e-04 -6.0000e+00 4.0934e-02 -4.8053e-02 6.1023e-04 12 8 8 10 0 0 99.86 16.10 21.40 -0.04805 0.05326 15 3 1 4 0 3336.830 20.46 15.00 16.10 24.22 9.4 941.87 9861 21858 -54211 31630 46240 26836 11868 4156 -22516 -7107 -35261 -4331 10525 -19430 27879 16080 26987 28868 -4543 20568 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26248 -5896 18887 2311 16543 5013 20705 36679 15812 38337 10511 14244 6313 -7900 26664 12655 23217 6546 13923 4374 13301 10195 33271 -9831 -59080 -8767 1563 17655 17541 -5620 -15183 -3471 39538 23574 24060 17763 -5000 900000 44654 20922 10825 1242 17792 -11195 25832 20953 -88250 17155 16989 8100 -23210 -2400 -13521 25352 38809 19895 31825 -913 5929 -10764 -6153 22957 15098 -13792 17987 -1586 -29757 1799 23640 5003 482 33581 -22350 22152 8363 17239 20068 -15457 -37628 33104 2829 -4193 3981 3708 20478 15583 35762 20724 -4674 15580 6255 22314 19169 -8264 16950 -27769 -13146 20246 22304 15909 -33620 453 -12853 21963 19214 -14844 -10110 -6262 -10741 -11553 7023 -39866 -13982 -19467 900000 SQ 20240924T204513.7Z 9033.864742 237 1 49.60 2 88.01 92.55 7.22 190.49 0.00 1 0.00 1 0 15 1.246e-01 1.119e-01 8.926e-02 8.600e-02 4.576256e+03 6.043560e+03 4.308959e+02 -6.000000e+00 7.297431e+03 289.84 -2.00 20.00 -2.00 505.28 0.00e+00 1.706514e-04 2.493894e-03 7.907464e-06 -6.000000e+00 3.629728e-03 289.84 -2.00 20.00 -2.00 500.03 0.00e+00 1.451557e+00 1.773123e+00 2.739872e-03 -6.000000e+00 2.481937e+00 228.48 -2.00 3.41 -2.00 501.71 0.00e+00 16.001 0.065 489.00 513.00 1 1.0526e+01 1.3740e-01 2.4660e-02 -6.0000e+00 1.9166e-01 1.2163e-01 3.4523e-02 1.3846e-03 -6.0000e+00 4.8753e-02 4.6878e-06 -1.0478e-02 8.7914e-03 4.6250e-05 -6.0000e+00 1.3337e-02 -3.7137e-02 2.2741e-04 12 8 8 10 0 0 99.86 16.11 28.13 -0.03714 -0.10982 14 3 1 4 0 3542.000 20.46 15.00 16.11 24.26 9.3 941.89 -5114 -11500 -3596 -9778 34456 -82 282 3935 5069 -1575 14568 206 19474 -9690 5350 -6326 2531 22483 -4620 -919 1248 -6548 10268 17116 19469 -6972 -1215 1838 -9365 2922 5316 -10840 -14804 1523 -10209 2674 1980 -1452 2610 -7411 3583 -5953 -14839 7705 -3556 -1995 -5170 7371 1130 -3037 87 5909 20041 -2108 261 -3886 5734 5023 16283 51197 900000 32876 1139 -297 92 3216 8723 -23574 -4277 3995 -1041 6462 -7113 19505 -14003 -10453 2108 -2462 713 -9530 3044 6216 4332 8047 2280 -6396 -36 2249 7499 766 -3954 46465 -2195 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-5797 -29348 15627 1799 -14727 -13292 -740 2494 8886 723 -507 -4545 1310 -2473 1958 8658 -3913 21986 1249 -2488 -14506 -3098 -12693 4674 9634 9737 11296 10075 SQ 20240924T205101.6Z 9033.868769 247 1 49.25 2 86.84 93.40 7.52 199.89 0.00 1 0.00 1 0 29 6.404e-02 6.945e-02 5.177e-02 5.084e-02 1.264347e+04 3.941148e+03 8.954271e+02 -6.000000e+00 3.753212e+03 289.84 -2.00 20.00 -2.00 505.27 0.00e+00 1.097988e-03 1.436250e-03 1.083992e-04 -6.000000e+00 1.850148e-03 289.84 -2.00 20.00 -2.00 499.97 0.00e+00 2.232458e-01 1.050584e+00 7.620678e-02 -6.000000e+00 1.287410e+00 228.48 -2.00 3.41 -2.00 501.63 0.00e+00 13.118 0.036 489.00 513.00 1 1.0516e+01 8.0386e-02 2.0576e-02 -6.0000e+00 9.9027e-02 1.2160e-01 2.0596e-02 2.1357e-03 -6.0000e+00 2.5584e-02 7.7672e-06 -7.4769e-03 4.9840e-03 6.9895e-05 -6.0000e+00 6.8913e-03 -3.5749e-02 4.6658e-04 12 8 8 10 0 0 99.35 16.11 0.41 -0.03575 -0.08761 13 3 1 4 0 3787.790 20.46 15.00 16.11 24.38 9.3 942.47 3315 -2126 1640 2218 2702 -600 4236 3390 -30497 -11418 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