File name: Pandora192s1_Tokyo-Sophia_20241013_L2Fit_fwvt1c5d20240824p1-8.txt File generation date: 20250716T130602.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20241013_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20241013 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0126 492.1343 492.2560 492.3777 492.4994 492.6210 492.7426 492.8643 492.9859 493.1074 493.2290 493.3506 493.4721 493.5936 493.7151 493.8366 493.9581 494.0795 494.2010 494.3224 494.4438 494.5652 494.6865 494.8079 494.9292 495.0505 495.1718 495.2931 495.4144 495.5357 495.6569 495.7781 495.8993 496.0205 496.1417 496.2628 496.3840 496.5051 496.6262 496.7473 496.8684 496.9894 497.1105 497.2315 497.3525 497.4735 497.5945 497.7154 497.8364 497.9573 498.0782 498.1991 498.3200 498.4408 498.5617 498.6825 498.8033 498.9241 499.0449 499.1656 499.2864 499.4071 499.5278 499.6485 499.7692 499.8898 500.0105 500.1311 500.2517 500.3723 500.4929 500.6135 500.7340 500.8545 500.9750 501.0955 501.2160 501.3365 501.4569 501.5774 501.6978 501.8182 501.9385 502.0589 502.1792 502.2996 502.4199 502.5402 502.6605 502.7807 502.9010 503.0212 503.1414 503.2616 503.3818 503.5020 503.6221 503.7422 503.8624 503.9824 504.1025 504.2226 504.3426 504.4627 504.5827 504.7027 504.8227 504.9426 505.0626 505.1825 505.3024 505.4223 505.5422 505.6621 505.7819 505.9017 506.0216 506.1414 506.2611 506.3809 506.5007 506.6204 506.7401 506.8598 506.9795 507.0991 507.2188 507.3384 507.4580 507.5776 507.6972 507.8168 507.9363 508.0559 508.1754 508.2949 508.4143 508.5338 508.6533 508.7727 508.8921 509.0115 509.1309 509.2502 509.3696 509.4889 509.6082 509.7275 509.8468 509.9661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241012T205139.8Z 9051.869210 55 1 50.53 2 89.68 99.89 153.02 298.53 0.00 1 0.00 1 0 29 2.397e-01 1.692e-01 1.150e-01 9.280e-02 2.673165e+04 8.572558e+03 1.251977e+03 -6.000000e+00 1.396528e+04 287.98 -2.00 20.00 -2.00 505.41 0.00e+00 -2.766760e-04 2.693487e-03 2.950246e-04 -6.000000e+00 6.944839e-03 287.98 -2.00 20.00 -2.00 500.08 0.00e+00 5.653391e+00 1.934060e+00 2.537470e-01 -6.000000e+00 4.812796e+00 226.88 -2.00 3.41 -2.00 501.74 0.00e+00 19.899 0.126 489.00 513.00 1 9.7469e+00 1.4773e-01 3.9767e-02 -6.0000e+00 3.6976e-01 -5.2847e-03 3.5744e-02 5.3143e-03 -6.0000e+00 9.5534e-02 4.0631e-06 4.2566e-03 7.9512e-03 7.0319e-05 -6.0000e+00 2.5843e-02 -2.3829e-02 4.6935e-04 12 8 8 10 0 0 99.43 15.68 23.47 -0.02383 0.00570 16 4 1 4 0 3157.280 20.46 15.00 15.68 24.09 11.1 952.06 -12422 -4779 11609 2078 -14151 -17891 -10696 6630 -12862 4298 8138 -238 -16369 -10612 35605 7059 17295 -15088 5236 4669 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13645 15188 2149 21417 -26810 -35315 -7590 -8011 1535 19550 -12325 -8710 9762 1902 -1712 7171 -14447 10452 9231 -18045 21726 4545 15492 7217 16884 13250 900000 37505 5235 19259 6033 -7806 -12025 10670 5425 8203 5737 -18742 -20941 -5543 -3645 6754 4894 7991 15823 1848 -24564 -5849 29137 4260 516 -6122 15187 -7172 -8923 24286 -108 -663 -3073 6616 -1503 -7088 795 7716 -722 -4010 -1303 18516 -22550 9706 -22440 -11850 11903 4903 20564 12791 12889 19175 -9380 19080 -2075 22585 -12888 10336 -18705 8311 4322 1925 26562 -1021 19324 5233 -1889 10824 345 22454 17210 11039 11760 -114387 24001 24249 15340 -14069 26847 4901 -3088 21941 900000 SQ 20241012T213345.3Z 9051.898441 86 1 6.12 2 81.36 106.20 159.40 315.83 0.00 1 0.00 1 0 22 5.682e-03 5.652e-03 1.387e-04 1.385e-04 6.920277e+03 9.333176e+00 4.631774e+02 -6.000000e+00 3.304526e+02 287.98 -2.00 20.00 -2.00 505.34 0.00e+00 1.267567e-03 3.905744e-06 7.108950e-05 -6.000000e+00 1.631055e-04 287.98 -2.00 20.00 -2.00 500.74 0.00e+00 4.567710e-01 2.705601e-03 4.889531e-02 -6.000000e+00 1.129886e-01 226.88 -2.00 3.41 -2.00 502.29 0.00e+00 6.274 0.004 489.00 513.00 1 1.2643e+00 2.0774e-04 1.0018e-02 -6.0000e+00 8.7044e-03 -2.3052e-02 5.2047e-05 1.2500e-03 -6.0000e+00 2.2174e-03 2.1318e-01 1.5491e-03 1.4113e-05 4.8411e-05 -6.0000e+00 6.0814e-04 -6.2298e-03 1.0361e-04 12 8 8 10 0 0 46.36 15.68 1.36 -0.00623 0.00452 506 111 1 4 0 11.550 20.46 15.00 15.68 24.30 11.0 952.72 -1411 -1181 -728 -267 -114 578 866 896 751 551 245 -45 -539 -636 -745 -849 -518 14 301 159 305 533 486 778 852 693 639 343 -414 -836 -815 -865 -476 460 262 -25 165 155 -106 -105 125 147 396 593 750 779 705 536 197 -399 -842 -1148 -1277 -838 -259 -72 27 97 198 370 657 690 622 614 480 221 58 -96 -365 -512 -433 -374 -170 203 -16 -464 -646 -599 -671 -709 -679 -727 -611 -224 -197 -385 -244 -138 -61 100 425 895 889 657 644 365 -60 -263 -782 -1120 -1114 -652 -38 82 -350 -510 -639 -586 -229 6 -33 197 456 662 853 1156 1140 801 507 350 125 278 626 516 295 355 258 161 405 159 -334 -463 -658 -816 -378 -143 -359 -176 177 170 256 399 423 392 198 -119 -514 -674 -709 -539 -1319 -1116 -705 -254 -112 575 875 915 769 560 246 -45 -531 -619 -722 -828 -511 14 309 159 306 533 488 781 859 700 643 342 -425 -838 -803 -856 -480 454 266 -26 168 156 -106 -104 125 147 400 606 772 803 723 544 197 -392 -845 -1131 -1251 -827 -261 -71 27 99 202 377 668 705 638 628 487 223 57 -94 -355 -494 -415 -360 -166 199 -16 -456 -625 -571 -665 -702 -645 -697 -591 -219 -194 -382 -242 -136 -61 99 425 902 901 664 639 353 -57 -256 -751 -1068 -1070 -612 -37 82 -359 -525 -652 -594 -231 6 -33 198 459 669 866 1180 1170 825 520 354 124 274 641 510 293 353 256 161 402 157 -328 -469 -661 -821 -383 -141 -361 -180 183 177 269 421 448 415 209 -125 -529 -683 -715 -547 SQ 20241012T213351.7Z 9051.898515 86 2 6.18 2 81.34 106.22 159.42 315.89 0.00 1 0.00 1 0 22 5.696e-03 5.667e-03 1.380e-04 1.378e-04 6.903427e+03 9.271047e+00 4.623171e+02 -6.000000e+00 3.312410e+02 287.98 -2.00 20.00 -2.00 505.34 0.00e+00 1.266633e-03 3.885316e-06 7.103574e-05 -6.000000e+00 1.634967e-04 287.98 -2.00 20.00 -2.00 500.73 0.00e+00 4.570909e-01 2.689992e-03 4.879571e-02 -6.000000e+00 1.132635e-01 226.88 -2.00 3.41 -2.00 502.29 0.00e+00 6.261 0.004 489.00 513.00 1 1.2585e+00 2.0653e-04 9.9964e-03 -6.0000e+00 8.7255e-03 -2.3152e-02 5.1750e-05 1.2476e-03 -6.0000e+00 2.2229e-03 2.1484e-01 1.5953e-03 1.4066e-05 4.8544e-05 -6.0000e+00 6.0961e-04 -3.6217e-03 8.4716e-05 12 8 8 10 0 0 52.94 15.68 1.33 -0.00362 0.00744 506 111 1 4 0 11.550 20.46 15.00 15.68 24.30 11.0 952.72 -1424 -1184 -715 -272 -143 551 875 903 741 519 265 -89 -531 -620 -765 -803 -551 35 294 154 299 533 491 765 862 686 629 359 -425 -874 -809 -893 -482 426 277 -24 188 187 -97 -124 75 191 412 641 764 792 718 559 200 -376 -852 -1157 -1279 -839 -259 -42 30 71 206 393 626 680 633 594 457 214 56 -129 -392 -535 -466 -370 -179 177 6 -482 -616 -585 -655 -702 -662 -682 -634 -232 -217 -389 -246 -112 -72 105 454 868 889 637 657 373 -41 -257 -771 -1151 -1112 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