File name: Pandora192s1_Tokyo-Sophia_20241120_L2Fit_fwvt1c5d20240824p1-8.txt File generation date: 20250716T132214.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20241120_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20241120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0126 492.1343 492.2560 492.3777 492.4994 492.6210 492.7426 492.8643 492.9859 493.1074 493.2290 493.3506 493.4721 493.5936 493.7151 493.8366 493.9581 494.0795 494.2010 494.3224 494.4438 494.5652 494.6865 494.8079 494.9292 495.0505 495.1718 495.2931 495.4144 495.5357 495.6569 495.7781 495.8993 496.0205 496.1417 496.2628 496.3840 496.5051 496.6262 496.7473 496.8684 496.9894 497.1105 497.2315 497.3525 497.4735 497.5945 497.7154 497.8364 497.9573 498.0782 498.1991 498.3200 498.4408 498.5617 498.6825 498.8033 498.9241 499.0449 499.1656 499.2864 499.4071 499.5278 499.6485 499.7692 499.8898 500.0105 500.1311 500.2517 500.3723 500.4929 500.6135 500.7340 500.8545 500.9750 501.0955 501.2160 501.3365 501.4569 501.5774 501.6978 501.8182 501.9385 502.0589 502.1792 502.2996 502.4199 502.5402 502.6605 502.7807 502.9010 503.0212 503.1414 503.2616 503.3818 503.5020 503.6221 503.7422 503.8624 503.9824 504.1025 504.2226 504.3426 504.4627 504.5827 504.7027 504.8227 504.9426 505.0626 505.1825 505.3024 505.4223 505.5422 505.6621 505.7819 505.9017 506.0216 506.1414 506.2611 506.3809 506.5007 506.6204 506.7401 506.8598 506.9795 507.0991 507.2188 507.3384 507.4580 507.5776 507.6972 507.8168 507.9363 508.0559 508.1754 508.2949 508.4143 508.5338 508.6533 508.7727 508.8921 509.0115 509.1309 509.2502 509.3696 509.4889 509.6082 509.7275 509.8468 509.9661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241119T214347.2Z 9089.905407 274 1 49.16 2 86.82 117.14 45.06 273.17 0.00 1 0.00 1 0 50 3.009e-01 2.454e-01 2.292e-01 1.983e-01 -2.109278e+03 1.148178e+04 3.164229e+02 -6.000000e+00 1.722622e+04 283.80 -2.00 20.00 -2.00 505.04 0.00e+00 -4.184396e-03 5.439420e-03 8.398386e-05 -6.000000e+00 8.568017e-03 283.80 -2.00 20.00 -2.00 499.88 0.00e+00 4.976216e-01 4.036830e+00 6.060055e-02 -6.000000e+00 6.039868e+00 224.22 -2.00 3.41 -2.00 501.49 0.00e+00 13.126 0.036 489.00 513.00 1 1.1923e+01 3.1078e-01 2.0037e-02 -6.0000e+00 4.6373e-01 1.5448e-01 8.0934e-02 1.5704e-03 -6.0000e+00 1.1993e-01 1.9005e-06 6.3999e-03 1.9754e-02 6.2090e-05 -6.0000e+00 3.2358e-02 -8.7708e-02 7.6299e-04 12 9 8 11 8 0 99.74 15.75 -1.73 -0.08771 -0.04332 14 3 1 4 0 3510.850 20.96 14.97 15.75 13.22 12.6 940.03 9294 29972 -9417 27538 21775 20634 34134 8614 16030 -35148 11846 13795 79558 -24427 81595 -15759 2436 42728 1532 19897 -5222 23177 7880 -1566 42054 9921 59290 16436 24607 -37762 -8771 20517 1896 22840 -46394 24510 35126 -10908 8559 104980 6257 23603 11267 6550 13657 23411 7250 12961 -5684 -2493 -11223 -4661 31011 -24575 5224 -42483 9689 712 -20059 31189 58584 4000 25460 18785 -6071 -9611 55531 14881 18236 -1389 -25402 34764 -32324 58718 2501 -7222 8915 -19544 38457 -9295 40819 6656 -31828 -19528 3591 30499 46207 71039 21098 -18173 -14409 17879 19187 33245 6423 -27065 2886 70932 -8880 -20307 4091 49141 -27294 15031 31852 -32754 30069 72356 5150 -12484 36670 24494 6455 1066 40973 -10664 4358 -21542 29628 -9127 36848 -2262 47428 6018 9571 19035 -9269 -12389 9266 6043 32886 35587 56018 64524 23264 -22042 -1127 16538 53513 41805 -391 -6405 11876 -18540 -3038 -26584 26072 11027 15793 900000 9027 24084 -11559 24074 20670 20225 29689 9736 16774 -59329 12605 14191 42773 -35116 42393 -20886 2745 33769 1825 19928 -6740 22513 8913 -1947 34535 10921 40314 16462 22096 -61622 -10602 18689 2137 21495 -86798 23067 29419 -14268 9090 44109 6726 21398 11625 7126 13856 21426 7699 12757 -6576 -2712 -12936 -4930 22893 -31447 5210 -68356 9579 772 -26092 24775 36213 4179 21433 16787 -6717 -10837 33590 13041 15273 -1372 -31861 24613 -44367 33461 2440 -7656 7906 -22781 25567 -9774 26785 6072 -43148 -23669 3488 23305 30321 36495 17553 -22564 -17404 15781 16774 25131 6266 -35463 2803 34909 -9338 -23335 3819 30761 -36214 13585 24348 -46167 22731 36235 4937 -14087 26173 19965 6351 1089 28724 -12254 4287 -27158 22522 -9846 25365 -2244 29243 5497 8426 15515 -9770 -13416 8043 5370 22500 23295 29572 32034 17292 -25692 -1085 13535 31188 27542 -386 -6751 10456 -22070 -3064 -32600 18859 9115 12403 900000 SQ 20241119T225041.7Z 9089.951871 300 1 48.37 2 75.38 128.10 58.20 281.13 0.00 1 0.00 1 0 15 1.952e-02 1.943e-02 1.595e-02 1.586e-02 4.077912e+03 1.042696e+03 1.858448e+02 -6.000000e+00 1.116803e+03 283.80 -2.00 20.00 -2.00 505.25 0.00e+00 1.162688e-03 4.427811e-04 7.994678e-05 -6.000000e+00 5.546396e-04 283.80 -2.00 20.00 -2.00 500.26 0.00e+00 3.713185e-01 3.185681e-01 5.024615e-02 -6.000000e+00 3.880140e-01 224.22 -2.00 3.41 -2.00 501.89 0.00e+00 3.881 0.001 489.00 513.00 1 1.0653e+01 2.4528e-02 7.0688e-03 -6.0000e+00 2.9850e-02 2.8097e-02 6.1882e-03 9.7986e-04 -6.0000e+00 7.6141e-03 2.5347e-05 1.0409e-03 1.6402e-03 2.8591e-05 -6.0000e+00 2.0886e-03 1.3010e-02 -4.6062e-05 12 9 8 11 8 0 98.96 15.72 2.68 0.01301 0.02023 13 3 1 4 0 3719.780 20.96 14.99 15.72 12.23 12.4 935.56 -1796 -182 -1456 2126 -72 -176 -1024 1118 1909 2002 3684 779 -779 -1597 923 -656 -1823 1457 642 834 -2353 2779 1039 1597 -330 -326 2012 -321 846 1215 -1516 -226 -5146 369 -772 -1325 -1438 1111 -1838 1063 -1613 -1310 289 3104 -2078 1879 410 477 1766 -248 -1931 491 -4991 -3474 113 391 -1249 2345 -1232 3048 792 1924 2337 1427 2152 -1975 -316 -742 464 337 -1245 1834 -1566 -947 743 -2236 -1101 1430 -554 -4250 2088 -592 1538 985 -1884 659 -4316 1224 2549 -1936 568 -447 -326 -3016 794 -839 -673 1076 -4809 1461 2119 1327 3751 792 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1750 1296 SQ 20241119T232325.5Z 9089.974601 326 1 49.37 2 70.38 134.23 64.51 284.86 0.00 1 0.00 1 0 15 6.584e-03 6.597e-03 3.128e-03 3.119e-03 3.285619e+03 1.988826e+02 2.043387e+02 -6.000000e+00 3.766742e+02 283.80 -2.00 20.00 -2.00 505.27 0.00e+00 9.210897e-04 8.692969e-05 4.861798e-05 -6.000000e+00 1.870698e-04 283.80 -2.00 20.00 -2.00 500.39 0.00e+00 1.788406e-01 6.212592e-02 3.024505e-02 -6.000000e+00 1.308824e-01 224.22 -2.00 3.41 -2.00 501.99 0.00e+00 2.945 0.000 489.00 513.00 1 9.0210e+00 4.7759e-03 5.0164e-03 -6.0000e+00 1.0069e-02 1.4080e-02 1.2072e-03 6.7954e-04 -6.0000e+00 2.5686e-03 1.5105e-04 8.4426e-04 3.2345e-04 2.3878e-05 -6.0000e+00 7.0445e-04 1.4455e-02 -6.2361e-05 12 8 8 10 0 0 99.29 15.67 0.93 0.01445 0.02031 14 3 1 4 0 3525.090 20.87 14.95 15.67 10.90 12.6 932.26 -1037 -1115 -752 -859 -708 364 887 1129 222 -117 397 -20 -400 -277 -1116 -811 -492 -131 1244 255 4 386 397 238 1067 803 51 1119 -484 -1140 -136 -844 -89 344 710 126 730 -544 -401 -30 -267 280 263 1046 231 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