File name: Pandora192s1_Tokyo-Sophia_20241206_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T133551.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20241206_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20241206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241205T220859.4Z 9105.922909 59 1 48.55 2 85.15 122.28 132.23 88.36 0.00 1 0.00 1 0 57 1.311e+00 1.042e+00 9.207e-01 7.582e-01 -7.141766e-01 5.936056e-01 1.515434e-02 -6.000000e+00 1.109440e+00 223.93 -2.00 3.41 -2.00 312.73 0.00e+00 6.615650e-02 3.302149e-02 2.976921e-03 -6.000000e+00 5.288947e-02 282.23 -2.00 20.00 -2.00 312.19 0.00e+00 10.042 0.016 302.00 328.00 3 5.6669e+00 1.4958e+00 1.2931e-01 -6.0000e+00 2.7309e+00 -6.3427e-01 1.6690e+00 1.2257e-01 -6.0000e+00 2.9899e+00 5.1954e-01 9.5854e-01 1.6735e-02 -6.0000e+00 1.7685e+00 -3.8131e-01 3.6997e-01 3.2539e-02 -6.0000e+00 7.3252e-01 1.2730e-07 -1.8417e-02 2.3430e-02 5.8051e-04 -6.0000e+00 6.6770e-02 5.7810e-02 0.0000e+00 12 8 8 10 0 0 94.08 16.26 34.70 0.05781 -0.08058 13 3 1 5 0 3733.480 21.17 14.98 16.26 13.72 12.9 953.17 900000 33374 900000 -36701 900000 900000 900000 -73513 900000 -72906 -80691 288527 900000 900000 900000 900000 900000 -37673 900000 168268 900000 900000 185988 900000 900000 900000 -86486 900000 900000 900000 900000 900000 900000 60532 900000 900000 900000 900000 -4167 900000 900000 23575 900000 266263 900000 900000 900000 -88484 900000 900000 900000 43377 900000 31418 900000 900000 900000 -13583 -144761 900000 232153 86434 900000 3425 900000 -20196 114991 900000 209662 900000 900000 900000 900000 900000 900000 900000 -53200 -17069 900000 900000 900000 33672 -5068 95536 900000 900000 52099 -81936 900000 900000 900000 20479 85551 900000 19030 900000 900000 900000 900000 -78421 87473 900000 192626 900000 -27520 110691 80337 900000 900000 900000 -67432 319881 25627 900000 900000 143064 -39823 -66632 -61939 118175 59709 2739 -39709 413218 900000 -10047 293765 -36870 -41607 900000 900000 -14472 -65416 285739 91499 -6005 900000 -5242 128843 14733 -27910 5055 900000 900000 23945 900000 -50225 900000 900000 900000 -74044 900000 -52308 -57893 207009 900000 900000 900000 900000 900000 -31354 900000 120727 900000 900000 133441 900000 900000 900000 -62051 900000 900000 900000 900000 900000 900000 43430 900000 900000 900000 900000 -2989 900000 900000 16914 900000 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-2.00 319.56 0.00e+00 4.009 0.001 302.00 328.00 3 1.5401e-02 1.0629e-03 4.8403e-02 -6.0000e+00 2.4194e-01 1.1167e-02 1.2809e-03 3.1561e-02 -6.0000e+00 2.6303e-01 -5.5606e-02 1.0162e-03 1.5636e-02 -6.0000e+00 1.5730e-01 1.5347e-02 5.0885e-04 4.1736e-03 -6.0000e+00 6.5028e-02 6.2759e-03 7.0353e-04 2.3215e-05 1.0207e-04 -6.0000e+00 5.4759e-03 5.6846e-03 0.0000e+00 12 8 8 10 0 0 98.14 16.32 0.37 0.00568 0.01097 1166 256 1 5 0 42.130 21.27 15.01 16.32 15.79 13.0 962.25 -51210 -46361 -27984 -49321 -47113 -58259 -64241 -63500 -57932 -47239 -43819 -41655 -31214 -27424 -21678 -10138 -14138 -3782 -4595 -5611 -4364 -7780 -7757 -4304 -8209 -6620 -11606 -7892 -12348 -9257 -4574 -5379 -3965 -5664 -7669 -9662 -4394 -1266 1268 2874 2836 3183 3886 3082 4885 2606 2639 2203 1081 2067 1615 3411 3137 2634 2963 2149 1237 1428 388 1272 1527 4347 4181 4435 2951 1520 58 -511 779 1699 2006 1703 582 -186 -1908 -4329 -4985 -6135 -4635 -3611 -2911 -2389 -1992 -1118 33 803 1791 1848 1859 1257 245 -1140 -2551 -2582 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119.16 97.17 0.00 1 0.00 1 0 25 1.173e-01 1.163e-02 6.410e-03 5.005e-04 3.999081e-01 2.689680e-04 5.264159e-03 -6.000000e+00 7.200962e-02 223.93 -2.00 3.41 -2.00 319.91 0.00e+00 3.114136e-03 8.595541e-05 3.500858e-03 -6.000000e+00 3.245750e-03 282.22 -2.00 20.00 -2.00 319.21 0.00e+00 3.657 0.001 302.00 328.00 3 -4.5397e-02 7.8669e-04 4.3462e-02 -6.0000e+00 1.7696e-01 1.6671e-04 9.3457e-04 2.6715e-02 -6.0000e+00 1.9238e-01 -3.4005e-02 7.1244e-04 1.3412e-02 -6.0000e+00 1.1505e-01 6.0905e-03 3.5958e-04 3.7517e-03 -6.0000e+00 4.7571e-02 9.6276e-03 7.4783e-04 1.7877e-05 8.7594e-05 -6.0000e+00 4.0046e-03 4.5981e-03 0.0000e+00 12 8 8 10 0 0 46.00 16.35 0.42 0.00460 0.01022 1482 325 1 5 0 33.150 21.27 15.01 16.35 17.72 13.2 969.40 -34848 -35664 -32150 -40648 -43710 -41051 -44038 -35215 -37730 -32286 -36008 -29406 -24789 -18660 -8951 -6483 -377 -3093 -3778 -636 -1007 -2859 -2755 -5469 -4899 -5079 -5354 -8495 -11045 -9637 -6799 -5089 -2548 -5809 -6758 -8113 -7131 -2787 13 2545 2166 2773 2786 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