File name: Pandora192s1_Tokyo-Sophia_20250127_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T135455.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250127_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250126T224940.5Z 9157.951163 113 1 49.21 2 79.13 122.33 69.85 154.70 0.00 1 0.00 1 0 17 3.782e-01 1.988e-02 1.672e-01 6.386e-03 5.257125e-01 3.525353e-03 8.139317e-03 -6.000000e+00 2.336663e-01 224.60 -2.00 3.41 -2.00 321.10 0.00e+00 4.725254e-03 1.585333e-03 9.563871e-03 -6.000000e+00 1.045980e-02 279.64 -2.00 20.00 -2.00 320.51 0.00e+00 5.110 0.002 302.00 328.00 3 2.6122e+00 1.1602e-02 7.2802e-02 -6.0000e+00 5.7699e-01 1.9702e-01 1.4602e-02 6.5051e-02 -6.0000e+00 6.2764e-01 -2.8691e-01 1.2504e-02 2.8400e-02 -6.0000e+00 3.7313e-01 1.1030e-01 6.0350e-03 5.2406e-03 -6.0000e+00 1.5328e-01 1.4449e-04 -1.7186e-04 2.2690e-04 2.0329e-04 -6.0000e+00 1.2977e-02 2.8158e-03 0.0000e+00 12 8 8 10 0 0 99.98 16.58 0.45 0.00282 0.00152 55 12 1 5 0 894.520 20.87 15.00 16.58 11.88 13.3 1016.81 -120576 -25784 -35025 164372 -71978 223535 -137923 -98508 900000 -116240 -94974 -123279 -57997 -61031 43343 -9530 -59514 5971 27299 44969 -25655 31668 -12349 -3588 16522 -27086 -6396 -48503 -4823 -9427 -28975 -2252 -2540 7073 -9446 -9863 1837 10381 40365 5891 -3586 25331 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-688 -506 1016 -101 52 -4955 -2847 -3694 -3658 -1960 -2853 -1164 -885 3574 4033 3836 2793 1107 717 -986 -1070 -1122 -566 1456 27 2056 2364 1684 3446 -55 -160 -2138 2022 -973 463 -663 -1338 116 -2087 -674 1067 221 1040 1946 1528 -1370 -1985 -1915 SS 20250126T225455.4Z 9157.954808 116 1 1.64 2 78.23 123.21 69.41 155.79 0.00 1 0.00 1 0 25 3.713e-01 2.356e-02 3.048e-01 1.742e-02 4.897826e-01 9.426990e-03 6.260005e-03 -6.000000e+00 2.287150e-01 224.60 -2.00 3.41 -2.00 320.20 0.00e+00 3.449928e-03 3.291179e-03 4.222973e-03 -6.000000e+00 1.016844e-02 279.64 -2.00 20.00 -2.00 319.58 0.00e+00 4.750 0.002 302.00 328.00 3 2.3526e+00 2.7926e-02 5.5262e-02 -6.0000e+00 5.6343e-01 9.8310e-02 3.3545e-02 3.1978e-02 -6.0000e+00 6.1234e-01 -2.0844e-01 2.7065e-02 1.6792e-02 -6.0000e+00 3.6546e-01 8.9112e-02 1.3588e-02 5.1859e-03 -6.0000e+00 1.5065e-01 2.8203e-04 1.2025e-03 5.9715e-04 1.2053e-04 -6.0000e+00 1.2677e-02 -1.3232e-03 0.0000e+00 12 9 9 12 1 1 999.00 16.60 0.46 -0.00132 0.00771 1 13 1 5 0 818.290 20.87 15.00 16.60 12.13 13.3 1017.82 65025 70292 -76170 -11967 -96621 34905 -17680 -32471 -6738 -92817 -21148 -68458 152289 301203 12965 2226 -47929 -40960 -52157 33553 22657 34271 58746 -1122 38215 3182 -23001 32258 -81961 4007 -16984 -7457 67387 542 19530 -1152 37447 -8889 4522 -6941 8335 24216 20457 18709 -8425 6837 2319 12544 9803 6483 4923 8485 6139 6018 4465 7971 5411 5134 2727 -1906 6966 3205 14912 -2696 869 -8379 4015 7249 2028 2810 -476 -1600 -425 1435 3733 -8811 -5666 -9434 -6744 -4455 -3002 -1872 -2934 -146 -661 135 2116 1211 4727 -1386 -812 -1835 -3171 -2976 -2155 1475 -197 -200 -1521 322 -21 1263 -2035 -2933 -58 300 -1797 1912 1858 1522 998 1930 -103 1004 -1440 -1806 -8 -515 1403 1450 659 409 1484 2353 -1508 -960 374 -2458 851 -695 -106 -971 -516 -1 -389 1614 145 -266 489 -1309 1140 -472 -418 1105 1194 -2378 -203 -3416 593 -300 -674 -118 -3964 -479 -2746 2587 5118 392 86 -3393 -2919 -4406 1287 990 1348 1908 -68 1632 199 -1876 1531 -11450 255 -1476 -666 3233 52 1581 -113 2788 -1182 621 -1202 1416 3762 3446 3288 -1917 1391 499 2472 2041 1467 1219 2208 1718 1798 1420 2528 1790 1701 916 -674 2347 1215 5518 -1246 399 -4163 1781 3188 989 1507 -279 -985 -257 816 1977 -4855 -2854 -4965 -3753 -2687 -2036 -1368 -2301 -119 -565 121 1965 1164 4369 -1315 -723 -1589 -2686 -2572 -1964 1461 -214 -236 -1918 398 -25 1400 -2285 -3295 -67 366 -2319 2488 2565 2244 1549 3057 -165 1558 -2178 -2717 -12 -786 2209 2316 1068 665 2321 3595 -2305 -1410 548 -3784 1348 -1195 -190 -1821 -990 -2 -801 3404 312 -583 1058 -2849 2365 -959 -845 SS 20250126T225923.5Z 9157.957911 119 1 49.42 2 77.48 123.97 69.06 156.74 0.00 1 0.00 1 0 33 2.533e-01 1.936e-02 2.081e-01 1.098e-02 4.689820e-01 6.052290e-03 6.774320e-03 -6.000000e+00 1.570394e-01 224.60 -2.00 3.41 -2.00 320.72 0.00e+00 3.174162e-03 2.404285e-03 6.675888e-03 -6.000000e+00 7.012815e-03 279.64 -2.00 20.00 -2.00 320.10 0.00e+00 4.484 0.001 302.00 328.00 3 3.9589e+00 1.8885e-02 5.8348e-02 -6.0000e+00 3.8694e-01 1.2134e-01 2.3339e-02 4.6156e-02 -6.0000e+00 4.2088e-01 -1.5307e-01 1.9641e-02 2.1873e-02 -6.0000e+00 2.5031e-01 5.6718e-02 9.6735e-03 4.9530e-03 -6.0000e+00 1.0276e-01 7.1963e-05 5.4615e-04 3.9609e-04 1.5322e-04 -6.0000e+00 8.7016e-03 1.4843e-03 0.0000e+00 12 8 8 10 0 0 99.94 16.61 -0.04 0.00148 0.00559 36 8 1 5 0 1372.610 20.96 15.01 16.61 12.31 13.4 1018.69 -43915 -34941 -77420 -75177 -46877 -59917 900000 187878 -39189 -71596 -35161 6523 7917 -62979 8125 49416 -9075 37693 -325 -22190 900000 -2069 -22399 37549 -26580 5289 -42664 614 -66012 4810 -3195 -14141 25325 5128 14570 -28845 4781 -17517 -2284 -4267 -602 16414 -2686 22557 15046 -6063 19089 -8233 5988 3609 -3055 6834 3522 7217 -1272 9022 3107 5334 4753 2958 10409 248 7537 4574 4714 6295 3036 261 1283 2738 943 3745 2376 384 -2828 -6573 -5971 -5638 -2647 -463 -7241 -700 -3056 -2089 2116 2920 2597 2007 2534 2753 -3155 -7 -3009 -3491 -4388 -1145 -3038 1049 1878 -1165 -1731 -4508 -1506 -1768 -2175 -1685 -561 50 511 3157 3040 2387 356 -371 -1133 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