File name: Pandora192s1_Tokyo-Sophia_20250207_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T140258.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250207_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250206T221452.0Z 9168.926990 136 1 49.13 2 83.52 114.13 118.44 4.38 0.00 1 0.00 1 0 25 3.629e-01 3.274e-02 2.673e-01 1.496e-02 8.275944e-01 8.737096e-03 9.967608e-03 -6.000000e+00 2.239827e-01 224.93 -2.00 3.41 -2.00 322.19 0.00e+00 -1.112265e-03 4.482821e-03 1.404419e-02 -6.000000e+00 9.935050e-03 279.54 -2.00 20.00 -2.00 321.67 0.00e+00 8.031 0.008 302.00 328.00 3 2.7992e-01 3.2183e-02 1.1730e-01 -6.0000e+00 5.5219e-01 1.2760e+00 3.9583e-02 1.0525e-01 -6.0000e+00 6.0018e-01 -1.5897e+00 2.9789e-02 4.3312e-02 -6.0000e+00 3.5825e-01 5.9107e-01 1.4574e-02 7.4115e-03 -6.0000e+00 1.4746e-01 6.0463e-05 1.7298e-03 4.8007e-04 3.3437e-04 -6.0000e+00 1.2411e-02 -5.9592e-05 0.0000e+00 12 8 8 10 0 0 4.07 16.38 0.52 -0.00006 0.01294 83 18 1 5 0 591.820 20.67 15.00 16.38 8.03 13.3 1003.50 104635 40014 32168 -49692 209508 45077 76144 7146 -10063 44912 -51550 -65028 -3244 10040 900000 20790 58403 14059 -5722 79526 -26587 38978 -8094 35417 -15346 34152 -46960 -44050 54603 -26103 -25913 931 25371 62499 18749 27540 -20217 56945 -34964 5113 117604 29425 78733 26880 46133 45468 18772 53758 3163 51439 -29581 50030 -53666 10944 41285 15977 31409 -5031 7506 32649 14479 16246 19015 22677 14964 8047 25538 126068 25441 5698 23185 11951 13104 24024 -11044 -7048 -14585 -19953 -14398 -15010 4122 130 42859 -1949 671 6513 3919 16017 2195 403 -3861 1416 -5796 -1899 2849 -3427 715 -4185 -2312 354 -4077 -4017 -9742 -4562 -6018 -5362 10508 -681 1222 -1269 3682 2831 -1332 -1282 -1781 -2615 -2901 72 2601 17 3103 9149 1846 -2204 -2155 -986 -971 661 -1565 1285 -1170 827 -219 -69 686 145 281 577 -66 120 -83 -717 -1096 1527 1086 899 -2799 3056 789 1111 182 -310 805 -2471 -3849 -119 388 900000 910 1854 712 -351 2074 -1848 1379 -438 1300 -922 1268 -3607 -3155 1444 -1558 -1718 53 1223 2166 966 1268 -1528 2311 -3972 452 3763 2281 3733 2096 2881 2798 1498 3162 310 3413 -4639 3979 -12551 1422 4255 2098 3636 -787 1017 3319 1785 2110 2649 3319 2472 1435 3870 7602 4454 1344 4910 2885 3028 4613 -2718 -1512 -3233 -4873 -3761 -4627 1222 45 10751 -820 291 2805 1794 6581 1019 183 -1732 579 -2558 -867 1414 -2116 492 -3409 -1980 295 -3362 -3041 -7336 -3261 -4574 -4305 7992 -616 1217 -1468 4501 3725 -1867 -1775 -2418 -3539 -4013 101 3825 27 4548 12186 2556 -3083 -2931 -1302 -1304 947 -2604 2362 -2446 1840 -531 -174 1818 404 801 1644 -186 332 -217 -1791 -2729 SS 20250206T222541.9Z 9168.934512 139 1 49.15 2 81.53 115.83 118.21 6.99 0.00 1 0.00 1 0 25 3.400e-01 1.933e-02 1.045e-01 4.203e-03 6.856941e-01 2.415954e-03 9.696270e-03 -6.000000e+00 2.096428e-01 224.93 -2.00 3.41 -2.00 321.82 0.00e+00 8.184362e-03 1.321572e-03 1.206082e-02 -6.000000e+00 9.720383e-03 279.54 -2.00 20.00 -2.00 321.29 0.00e+00 6.390 0.004 302.00 328.00 3 3.4199e-01 8.8382e-03 9.1255e-02 -6.0000e+00 5.1718e-01 5.2419e-01 1.1295e-02 7.5572e-02 -6.0000e+00 5.6216e-01 -8.1600e-01 9.7225e-03 3.5272e-02 -6.0000e+00 3.3510e-01 3.3213e-01 4.5707e-03 9.0515e-03 -6.0000e+00 1.3824e-01 3.4960e-04 7.3849e-04 1.4112e-04 3.8707e-04 -6.0000e+00 1.1640e-02 4.7486e-04 0.0000e+00 12 8 8 10 0 0 54.39 16.40 0.41 0.00047 0.00602 233 51 1 5 0 210.890 20.67 15.01 16.40 9.16 13.4 1007.29 -48918 -35349 -77713 41047 -129254 -102613 -122435 -83425 -100042 -140056 900000 -97989 -50022 -91687 -40457 26243 -48365 48027 -60125 -17474 -36380 -35363 -5778 -18398 -516 -30507 -37389 -48348 -56932 -14172 -34061 -35287 -19660 -1442 -6299 -14102 20984 -3462 26795 44083 82724 36384 22756 43287 9135 23175 10469 17102 22822 20813 22970 16040 27771 18097 16515 15082 16592 23495 5831 10570 1530 6227 12335 8218 14047 9073 8657 6098 5778 2951 4680 9920 5321 4528 -156 -4964 -5865 -9136 -10357 -3178 -3514 -668 -239 2024 -336 1924 3015 2578 2213 826 1774 -2939 -2996 -6651 -5492 -1791 -1850 -540 -1289 333 -2130 -3918 -4241 -4775 -2192 -2634 -398 -1090 1054 2726 1419 2121 -407 -1183 -1586 -2145 -318 -674 626 1109 1359 3308 1783 2345 178 -257 -1064 -1050 162 570 719 -122 -149 -236 101 646 198 725 223 87 -419 -1141 -1042 -644 -455 -1570 240 -3783 -2133 -3046 -1441 -2108 -4509 900000 -2595 -993 -3439 -1109 430 -1860 757 -2919 -562 -1399 -1315 -158 -580 -14 -1106 -1426 -2012 -2602 -456 -1535 -1869 -992 -63 -286 -689 831 -183 1216 2077 2910 2162 1485 2542 705 1709 894 1407 1855 1841 2165 1775 2959 2262 2188 2076 2261 2945 852 1465 241 1023 2123 1617 2734 1868 1797 1354 1405 819 1379 2862 1581 1279 -42 -1295 -1476 -2455 -3155 -1052 -1355 -283 -111 984 -178 1056 1712 1503 1288 471 949 -1570 -1581 -3832 -3509 -1276 -1523 -494 -1273 325 -2022 -3499 -3589 -4077 -1914 -2458 -389 -1166 1222 3466 2002 3131 -622 -1781 -2316 -3091 -457 -1014 974 1763 2143 4975 2634 3335 251 -354 -1486 -1563 266 1042 1438 -264 -343 -579 242 1612 508 1868 571 231 -1064 -2788 -2522 SS 20250206T224052.6Z 9168.945053 144 1 49.23 2 78.78 118.29 117.74 10.61 0.00 1 0.00 1 0 25 3.465e-01 1.398e-02 4.174e-02 1.778e-03 5.802502e-01 9.871315e-04 8.550617e-03 -6.000000e+00 2.136731e-01 224.93 -2.00 3.41 -2.00 321.16 0.00e+00 8.508374e-03 4.686234e-04 9.106735e-03 -6.000000e+00 9.484660e-03 279.54 -2.00 20.00 -2.00 320.62 0.00e+00 4.962 0.002 302.00 328.00 3 5.7814e-01 3.2990e-03 6.9262e-02 -6.0000e+00 5.2680e-01 1.6605e-01 4.2499e-03 5.6933e-02 -6.0000e+00 5.7244e-01 -2.7203e-01 3.8875e-03 3.0505e-02 -6.0000e+00 3.4153e-01 1.0451e-01 1.8618e-03 9.4181e-03 -6.0000e+00 1.4065e-01 1.1880e-03 6.0937e-04 6.0371e-05 2.8585e-04 -6.0000e+00 1.1831e-02 -2.7986e-04 0.0000e+00 12 8 8 10 0 0 60.06 16.43 0.51 -0.00028 0.00430 396 87 1 5 0 124.210 20.67 15.00 16.43 10.12 13.4 1010.87 -104283 -117478 -80256 -131631 -118435 -99506 -104811 -103194 -112962 -107616 -115525 -61367 -83546 -62511 -55594 -48962 -25827 -35814 -22249 -12006 -17020 -21543 -9997 -30457 -31795 -19441 -22783 -25376 -15124 -30037 -18571 -24409 -2723 -9608 -12610 -14075 -14838 -1681 -4780 11963 8042 7813 10670 5435 10827 7110 6127 12885 3670 10149 6400 5444 5334 6904 8121 5668 7660 1019 2352 2302 4223 6057 5456 5961 7186 4903 3539 1854 2202 1296 3520 2390 2494 688 -1542 -3320 -7023 -7124 -6361 -4572 -2763 -1156 -1020 -1637 -200 790 609 2867 1592 1197 -737 -1481 -3133 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