File name: Pandora192s1_Tokyo-Sophia_20250209_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T140527.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250209_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250208T221250.8Z 9170.925588 210 1 49.07 2 83.51 113.32 112.65 336.53 0.00 1 0.00 1 0 25 5.602e-01 2.850e-02 2.945e-01 1.190e-02 8.108085e-01 7.015607e-03 1.064598e-02 -6.000000e+00 3.455736e-01 225.00 -2.00 3.41 -2.00 322.24 0.00e+00 1.656540e-03 3.774679e-03 1.744465e-02 -6.000000e+00 1.539659e-02 279.52 -2.00 20.00 -2.00 321.74 0.00e+00 8.018 0.008 302.00 328.00 3 4.7883e-04 2.6295e-02 1.2934e-01 -6.0000e+00 8.5206e-01 1.2084e+00 3.2739e-02 1.2834e-01 -6.0000e+00 9.2638e-01 -1.6930e+00 2.3872e-02 5.4295e-02 -6.0000e+00 5.5224e-01 6.7060e-01 1.1457e-02 8.5427e-03 -6.0000e+00 2.2855e-01 8.7898e-05 5.7083e-04 3.8655e-04 3.7930e-04 -6.0000e+00 1.9228e-02 1.8612e-03 0.0000e+00 12 8 8 10 0 0 24.80 16.38 0.48 0.00186 0.00615 123 27 1 5 0 398.860 20.67 15.00 16.38 7.75 13.3 1003.25 900000 61952 26168 153869 8038 156390 -98191 43622 -15997 -112982 12779 28959 50400 -6112 138423 69037 106102 177265 17818 123807 10622 27996 44849 60053 239100 10561 20751 -13941 76952 -23509 -10524 50207 11260 208044 2684 6989 29489 -15510 6253 29100 62947 44259 24606 224247 28047 54502 212002 53552 22835 -4067 29701 -1110 37184 26564 29481 25026 54367 140176 -12530 13160 8063 12609 11547 8543 30494 -15941 18253 10282 15786 18070 11773 15335 7686 20697 -8527 -6771 -2585 -19004 32 -14911 10200 1171 333 8066 -301 16395 3642 5304 -421 -3552 501 -7897 -4451 -7246 -6619 805 345 2357 -4481 1852 -9316 -6665 -8104 -8697 -1093 -5730 4017 -846 -45 -2650 469 3171 -734 -1907 242 -1856 3301 -219 1184 1509 3830 2271 2213 3571 220 373 189 127 -182 604 638 -712 -805 -943 60 37 744 620 -246 993 -901 -1140 -765 900000 1797 1029 1786 302 1815 -8419 953 -633 -10999 375 771 1239 -309 2008 2074 2462 2057 949 2335 551 1218 1594 1829 2775 513 858 -758 1619 -1398 -611 1784 637 2414 160 385 1347 -1237 458 1900 3150 2761 1874 2602 2105 3078 2460 3066 1837 -453 2551 -141 3452 2898 3239 2924 4711 4988 -1958 1537 1004 1609 1644 1368 4105 -3441 2824 1806 2870 3551 2641 3393 1784 3923 -1959 -1388 -486 -4381 7 -4372 2715 388 122 2945 -127 6164 1617 2355 -196 -1640 211 -3470 -1894 -3397 -3513 464 233 1764 -3866 1510 -8057 -5172 -5994 -6466 -790 -4619 3161 -767 -46 -3114 594 4182 -1030 -2682 325 -2518 4336 -311 1734 2252 5517 3217 3034 4688 290 484 249 181 -294 1101 1292 -1586 -1929 -2427 162 106 2148 1800 -708 2701 -2350 -2825 -1869 SS 20250208T222340.7Z 9170.933110 213 1 49.24 2 81.50 115.01 113.45 338.84 0.00 1 0.00 1 0 17 3.065e-01 1.894e-02 1.020e-01 3.592e-03 7.114151e-01 2.056277e-03 1.132940e-02 -6.000000e+00 1.889794e-01 225.00 -2.00 3.41 -2.00 321.87 0.00e+00 1.423699e-02 1.151388e-03 1.629107e-02 -6.000000e+00 8.387893e-03 279.52 -2.00 20.00 -2.00 321.36 0.00e+00 6.373 0.004 302.00 328.00 3 -1.4375e-02 7.6839e-03 1.0469e-01 -6.0000e+00 4.6598e-01 5.9121e-01 9.7818e-03 9.3906e-02 -6.0000e+00 5.0638e-01 -8.7098e-01 8.4677e-03 4.0925e-02 -6.0000e+00 3.0210e-01 3.5229e-01 3.9725e-03 1.0025e-02 -6.0000e+00 1.2436e-01 4.7233e-04 2.4909e-04 1.1870e-04 5.3630e-04 -6.0000e+00 1.0465e-02 1.6271e-03 0.0000e+00 12 8 8 10 0 0 36.46 16.40 0.37 0.00163 0.00350 322 71 1 5 0 152.880 20.67 15.00 16.40 9.03 13.4 1007.73 -33788 -140807 -138826 -97166 -106332 -99844 -56402 -50702 19048 -74875 -30515 -97584 -23101 -42706 -32018 -64720 -12173 31204 11350 -4640 17013 -16573 -7123 17117 -15190 -35656 -6656 -35001 -55189 -63559 -13029 19870 -13731 -1961 -37317 -27241 13053 13404 20328 6212 29718 33608 9360 20886 17117 18126 16313 31931 8877 19925 28674 22796 26076 17906 19631 13496 21571 14270 5567 8049 2252 19892 11291 20406 19471 15751 14860 7400 6186 3366 6269 11942 3489 4180 -6120 -10652 -8739 -9417 -4549 -3998 -1234 37 -1417 -1704 -820 2772 -288 2318 -574 -1946 -1437 -3069 -3844 -7646 -4461 -2043 -1002 431 -1010 -131 -1237 -2215 -4191 -5123 -3339 -2187 -1151 755 2165 2593 2451 2317 506 -598 -1505 -1763 -1664 -490 1051 1602 2123 1694 1521 1593 819 -404 -1029 -1192 71 -273 -38 -282 -397 -122 63 -23 348 794 455 -17 -376 -966 -561 -365 -5060 -5074 -2234 -2429 -1946 -709 -597 112 -1132 -306 -2159 -302 -870 -734 -2442 -306 578 257 -125 380 -500 -190 354 -431 -1225 -168 -1156 -2292 -3170 -461 597 -648 -86 -2297 -1499 505 579 939 373 1541 1782 660 1352 1176 1264 1192 2175 763 1720 2471 2279 2726 2052 2292 1787 2629 1837 764 1077 334 2717 1884 3431 3485 2957 2831 1582 1459 905 1764 3269 1019 1140 -1694 -2826 -2179 -2456 -1273 -1306 -457 15 -653 -844 -428 1476 -165 1325 -336 -1115 -777 -1606 -2002 -4364 -2778 -1444 -814 390 -997 -129 -1167 -1945 -3528 -4346 -2914 -2005 -1118 784 2462 3285 3417 3416 733 -899 -2209 -2548 -2440 -742 1638 2548 3332 2592 2254 2280 1145 -558 -1439 -1782 118 -508 -78 -591 -887 -291 157 -60 933 2137 1214 -44 -919 -2374 -1358 SS 20250208T223841.5Z 9170.943536 218 1 49.21 2 78.76 117.43 114.43 342.12 0.00 1 0.00 1 0 25 3.704e-01 1.489e-02 2.924e-02 1.288e-03 5.940101e-01 7.168133e-04 9.045772e-03 -6.000000e+00 2.284684e-01 225.00 -2.00 3.41 -2.00 321.20 0.00e+00 7.033312e-03 3.417421e-04 1.034590e-02 -6.000000e+00 1.013868e-02 279.52 -2.00 20.00 -2.00 320.66 0.00e+00 4.956 0.002 302.00 328.00 3 -3.0818e-02 2.3966e-03 7.3748e-02 -6.0000e+00 5.6336e-01 1.8204e-01 3.0986e-03 6.6119e-02 -6.0000e+00 6.1215e-01 -3.1809e-01 2.8080e-03 3.2998e-02 -6.0000e+00 3.6520e-01 1.2818e-01 1.3391e-03 8.6272e-03 -6.0000e+00 1.5037e-01 2.1782e-03 8.5436e-04 4.3496e-05 2.8337e-04 -6.0000e+00 1.2649e-02 4.1421e-05 0.0000e+00 12 8 8 10 0 0 29.98 16.45 0.34 0.00004 0.00646 733 161 1 5 0 67.130 20.77 15.00 16.45 10.95 13.3 1014.82 -58820 -137912 -82022 -105596 -129967 -132761 -124078 -120188 -144214 -101233 -104923 -108060 -93194 -55388 -43646 -55613 -11745 -17512 -18448 -21780 -27227 37 -34270 -5072 -24775 -17965 -27124 -39106 -29700 -33664 -14984 -7128 1098 -6180 -18656 -10858 -10283 -3963 2659 8845 8874 6676 14300 10008 8614 9282 9382 4886 7196 10429 7170 7571 11627 10148 7971 6992 7386 3557 2607 4305 3222 5778 7251 8544 5648 4628 3791 1225 3514 4277 4954 3278 2058 613 -2123 -3886 -7311 -6788 -5597 -3926 -2213 -2287 -1257 -1111 -110 1186 1302 2007 1440 974 -720 -2219 -3492 -4333 -2927 -1672 -421 104 105 -149 -1891 -2752 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