File name: Pandora192s1_Tokyo-Sophia_20250402_L2Fit_fwvt1c5d20240824p1-8.txt File generation date: 20250716T142932.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250402_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0126 492.1343 492.2560 492.3777 492.4994 492.6210 492.7426 492.8643 492.9859 493.1074 493.2290 493.3506 493.4721 493.5936 493.7151 493.8366 493.9581 494.0795 494.2010 494.3224 494.4438 494.5652 494.6865 494.8079 494.9292 495.0505 495.1718 495.2931 495.4144 495.5357 495.6569 495.7781 495.8993 496.0205 496.1417 496.2628 496.3840 496.5051 496.6262 496.7473 496.8684 496.9894 497.1105 497.2315 497.3525 497.4735 497.5945 497.7154 497.8364 497.9573 498.0782 498.1991 498.3200 498.4408 498.5617 498.6825 498.8033 498.9241 499.0449 499.1656 499.2864 499.4071 499.5278 499.6485 499.7692 499.8898 500.0105 500.1311 500.2517 500.3723 500.4929 500.6135 500.7340 500.8545 500.9750 501.0955 501.2160 501.3365 501.4569 501.5774 501.6978 501.8182 501.9385 502.0589 502.1792 502.2996 502.4199 502.5402 502.6605 502.7807 502.9010 503.0212 503.1414 503.2616 503.3818 503.5020 503.6221 503.7422 503.8624 503.9824 504.1025 504.2226 504.3426 504.4627 504.5827 504.7027 504.8227 504.9426 505.0626 505.1825 505.3024 505.4223 505.5422 505.6621 505.7819 505.9017 506.0216 506.1414 506.2611 506.3809 506.5007 506.6204 506.7401 506.8598 506.9795 507.0991 507.2188 507.3384 507.4580 507.5776 507.6972 507.8168 507.9363 508.0559 508.1754 508.2949 508.4143 508.5338 508.6533 508.7727 508.8921 509.0115 509.1309 509.2502 509.3696 509.4889 509.6082 509.7275 509.8468 509.9661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250402T012548.7Z 9223.059592 207 1 48.24 2 35.69 144.80 59.28 79.62 0.00 1 0.00 1 0 15 4.554e-03 4.536e-03 9.614e-04 9.587e-04 2.509534e+03 5.937174e+01 1.663455e+02 -6.000000e+00 2.594262e+02 282.46 -2.00 20.00 -2.00 505.24 0.00e+00 5.303261e-04 2.654466e-05 2.918911e-05 -6.000000e+00 1.289215e-04 282.46 -2.00 20.00 -2.00 500.36 0.00e+00 -8.381961e-02 1.922364e-02 2.159616e-02 -6.000000e+00 9.118006e-02 228.12 -2.00 3.41 -2.00 501.96 0.00e+00 1.230 0.000 489.00 513.00 1 7.7099e+00 1.4762e-03 2.6015e-03 -6.0000e+00 7.0054e-03 9.9168e-03 3.7651e-04 4.8580e-04 -6.0000e+00 1.7927e-03 7.3434e-04 -8.9134e-05 9.9582e-05 1.9129e-05 -6.0000e+00 4.8717e-04 7.4319e-03 -1.2976e-04 11 8 0 10 0 0 99.90 16.97 0.75 0.00743 0.00681 15 3 1 4 0 3215.650 21.17 15.00 16.97 13.89 26.2 1017.48 -979 -846 -687 -343 -228 107 759 527 721 305 396 -94 -306 -394 -385 -537 -625 -220 261 118 26 238 448 392 694 524 530 439 -376 -871 -474 -878 -532 307 331 60 12 280 241 -167 380 -39 354 404 711 451 782 382 67 -118 -632 -910 -1148 -919 -363 -265 142 9 -104 148 481 544 510 477 274 303 289 190 -276 -506 102 -162 57 63 94 -304 -461 -261 -515 -761 -538 -749 -549 -138 -209 -408 -181 -7 -15 19 220 773 544 414 498 303 8 -324 -73 -663 -865 -601 -168 170 -273 -429 -449 -447 -264 123 -51 98 187 264 354 709 1094 854 547 254 264 229 438 361 86 301 138 146 493 135 -203 -342 -447 -675 -213 2 -397 -423 75 12 134 492 191 317 213 -131 -468 -606 -483 -589 -954 -828 -689 -338 -231 110 795 560 766 323 413 -97 -311 -395 -383 -535 -631 -226 274 126 28 255 479 420 744 563 566 465 -393 -888 -471 -873 -536 316 351 62 13 296 251 -174 393 -41 371 427 757 462 829 402 69 -119 -626 -882 -1101 -884 -355 -267 145 9 -108 153 497 565 531 496 283 309 291 188 -271 -494 98 -157 56 62 94 -301 -450 -250 -491 -725 -513 -720 -532 -135 -206 -405 -180 -7 -15 19 222 783 533 407 484 302 8 -311 -69 -616 -805 -568 -164 170 -267 -420 -435 -429 -263 117 -50 97 185 264 356 713 1099 858 547 251 256 220 419 347 83 290 133 141 471 129 -192 -320 -430 -648 -205 2 -378 -410 73 12 133 487 190 316 212 -129 -453 -575 -453 -553 SQ 20250402T022559.1Z 9223.101379 250 1 48.09 2 31.00 170.92 47.47 86.84 0.00 1 0.00 1 0 15 4.464e-03 4.464e-03 1.039e-03 1.037e-03 2.089129e+03 6.374147e+01 1.389227e+02 -6.000000e+00 2.543183e+02 282.46 -2.00 20.00 -2.00 505.29 0.00e+00 4.719712e-04 2.875839e-05 2.625725e-05 -6.000000e+00 1.263786e-04 282.46 -2.00 20.00 -2.00 500.46 0.00e+00 -9.722768e-02 2.066777e-02 1.856441e-02 -6.000000e+00 8.937021e-02 228.12 -2.00 3.41 -2.00 502.07 0.00e+00 1.166 0.000 489.00 513.00 1 7.8726e+00 1.5840e-03 2.3480e-03 -6.0000e+00 6.8665e-03 9.6590e-03 4.0427e-04 4.1686e-04 -6.0000e+00 1.7569e-03 6.3146e-04 -4.0475e-04 1.0812e-04 1.6090e-05 -6.0000e+00 4.7761e-04 7.9501e-03 -1.2154e-04 11 8 0 10 0 0 99.69 17.07 0.66 0.00795 0.00514 16 4 1 4 0 3004.580 21.38 15.01 17.07 15.80 26.2 1025.32 -1090 -974 -689 -97 -15 174 634 479 763 355 411 -88 -395 -440 -837 -400 -645 -158 338 38 -23 430 417 461 637 802 488 314 -200 -828 -488 -808 -537 328 370 -1 18 276 67 -158 261 33 188 690 594 650 804 329 -29 253 -542 -878 -943 -837 -327 -369 2 124 -166 210 259 521 455 496 230 171 238 2 -184 -594 -48 -236 -225 243 21 -125 -351 -202 -329 -456 -592 -554 -576 -121 57 -256 -393 -112 -277 -97 159 747 859 269 466 495 -124 -129 -419 -582 -784 -636 -199 103 -279 -364 -350 -492 -278 98 -80 15 344 290 281 585 873 747 544 223 352 216 535 403 183 229 196 179 244 281 -183 -374 -591 -602 -325 -12 -465 -449 3 105 58 464 111 354 137 -35 -295 -727 -403 -403 -1049 -941 -680 -99 -16 177 654 501 796 369 421 -89 -395 -457 -864 -411 -672 -160 348 40 -24 452 438 485 672 846 514 327 -206 -831 -500 -790 -532 332 386 -1 19 287 69 -162 265 33 194 716 622 682 839 340 -30 251 -527 -879 -932 -831 -314 -366 2 126 -170 215 265 532 466 507 234 172 235 2 -178 -570 -46 -224 -216 235 20 -122 -336 -190 -308 -426 -556 -524 -549 -116 55 -250 -387 -110 -272 -95 158 746 865 273 467 487 -120 -122 -390 -534 -720 -594 -191 101 -281 -367 -350 -486 -273 96 -80 16 352 299 292 607 905 774 559 227 351 214 527 399 182 227 195 177 241 276 -179 -360 -562 -569 -308 -11 -456 -447 3 107 59 473 109 346 133 -35 -294 -712 -389 -389 SQ 20250402T023022.8Z 9223.104430 253 1 48.77 2 30.88 173.04 46.60 87.40 0.00 1 0.00 1 0 15 4.506e-03 4.495e-03 1.202e-03 1.197e-03 2.207609e+03 7.392613e+01 1.544246e+02 -6.000000e+00 2.567358e+02 282.46 -2.00 20.00 -2.00 505.24 0.00e+00 4.728217e-04 3.312170e-05 2.691517e-05 -6.000000e+00 1.275817e-04 282.46 -2.00 20.00 -2.00 500.27 0.00e+00 -1.194351e-01 2.414625e-02 1.773067e-02 -6.000000e+00 9.022618e-02 228.12 -2.00 3.41 -2.00 501.89 0.00e+00 1.165 0.000 489.00 513.00 1 7.8616e+00 1.8572e-03 2.3167e-03 -6.0000e+00 6.9322e-03 1.1346e-02 4.7330e-04 4.1548e-04 -6.0000e+00 1.7738e-03 6.3950e-04 -1.5634e-04 1.2446e-04 1.7154e-05 -6.0000e+00 4.8213e-04 7.6090e-03 -1.2502e-04 11 8 0 10 0 0 99.93 17.08 0.76 0.00761 0.00652 48 11 1 4 0 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