File name: Pandora192s1_Tokyo-Sophia_20250412_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T144041.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250412_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250411T215548.7Z 9232.913758 261 1 49.23 2 69.99 93.67 118.03 284.19 0.00 1 0.00 1 0 33 1.526e-01 1.222e-02 1.102e-02 7.609e-04 4.526950e-01 4.162313e-04 5.946568e-03 -6.000000e+00 9.538405e-02 228.89 -2.00 3.41 -2.00 320.01 0.00e+00 3.019441e-03 1.377122e-04 4.197249e-03 -6.000000e+00 4.241589e-03 283.35 -2.00 20.00 -2.00 319.31 0.00e+00 2.892 0.000 302.00 328.00 3 1.4304e+00 1.2309e-03 4.0528e-02 -6.0000e+00 2.3704e-01 5.5156e-03 1.4701e-03 3.1711e-02 -6.0000e+00 2.5677e-01 -5.5344e-02 1.1425e-03 1.5341e-02 -6.0000e+00 1.5306e-01 1.4041e-02 5.7397e-04 3.9137e-03 -6.0000e+00 6.2717e-02 4.1049e-03 1.0995e-03 2.6607e-05 1.0488e-04 -6.0000e+00 5.2175e-03 6.8602e-03 0.0000e+00 12 8 8 10 0 0 32.98 17.45 0.39 0.00686 0.01512 548 120 1 5 0 89.820 21.69 15.00 17.45 19.29 26.8 1027.55 -53750 -45134 -48290 -48131 -56421 -53671 -53016 -52176 -44818 -48894 -40503 -38025 -27596 -20391 -17193 -7768 -10031 -3272 -4158 -6 -4765 -6146 -4929 -7858 -4972 -7241 -7182 -9882 -12458 -9735 -9658 -2790 -3739 -5729 -7101 -9962 -5427 -3879 2279 2575 3447 3155 2347 3783 3086 3375 2534 1864 1009 500 2036 2633 3299 2944 2555 2258 692 1012 -63 719 1752 3210 4152 3531 2854 865 -123 -368 629 1970 1606 1638 990 72 -1536 -3688 -5103 -5788 -4221 -3200 -2341 -2014 -1861 -892 -105 1140 1695 1961 1914 1053 130 -1390 -2285 -2614 -1537 -680 395 840 348 -206 -1413 -2199 -2063 -1683 -1295 -1034 -418 546 1310 1972 1859 1375 633 -281 -938 -1098 -439 127 723 923 1171 1285 835 493 -288 -835 -1110 -845 -563 -478 -591 -853 -579 -225 31 480 556 663 510 166 -301 -581 -386 -1066 -929 -1078 -1055 -1279 -1159 -1191 -1274 -1116 -1356 -1096 -1108 -851 -704 -684 -323 -472 -171 -233 0 -289 -384 -314 -543 -352 -544 -541 -753 -968 -768 -839 -254 -378 -616 -775 -1139 -648 -530 346 451 664 652 510 831 693 764 583 437 244 127 548 765 1026 977 890 814 257 375 -24 267 670 1308 1830 1673 1389 421 -59 -181 330 1127 996 1054 637 45 -899 -2022 -2667 -3050 -2365 -2007 -1650 -1572 -1571 -796 -90 1026 1588 1874 1817 971 125 -1269 -2018 -2354 -1482 -661 427 994 434 -257 -1686 -2465 -2217 -1834 -1482 -1249 -530 730 1872 3023 3022 2294 1045 -445 -1419 -1608 -643 193 1145 1512 1923 2066 1308 745 -421 -1182 -1554 -1225 -877 -808 -1065 -1617 -1144 -427 62 995 1183 1424 1090 345 -603 -1127 -813 SS 20250411T220637.8Z 9232.921271 264 1 49.16 2 67.80 95.32 120.11 285.98 0.00 1 0.00 1 0 25 1.037e-01 1.194e-02 6.608e-03 5.594e-04 4.146806e-01 3.041894e-04 5.257092e-03 -6.000000e+00 6.480617e-02 228.89 -2.00 3.41 -2.00 319.65 0.00e+00 2.752110e-03 8.953127e-05 3.163653e-03 -6.000000e+00 2.881745e-03 283.35 -2.00 20.00 -2.00 318.94 0.00e+00 2.624 0.000 302.00 328.00 3 1.2088e+00 8.7499e-04 3.5564e-02 -6.0000e+00 1.6105e-01 -3.9193e-03 1.0286e-03 2.5939e-02 -6.0000e+00 1.7445e-01 -3.5259e-02 7.6380e-04 1.2899e-02 -6.0000e+00 1.0399e-01 6.5887e-03 3.8644e-04 3.5430e-03 -6.0000e+00 4.2613e-02 6.9256e-03 9.3036e-04 1.9506e-05 7.8714e-05 -6.0000e+00 3.5448e-03 6.6037e-03 0.0000e+00 12 8 8 10 0 0 17.15 17.47 0.42 0.00660 0.01359 781 171 1 5 0 62.940 21.79 15.00 17.47 20.56 26.7 1032.53 -34179 -31617 -25609 -30477 -38364 -38169 -40106 -33206 -33779 -30509 -29893 -26572 -20233 -14662 -8742 -4572 -3154 -1496 -1468 -656 -2310 -1601 -2476 -2808 -3107 -5086 -5564 -9079 -8988 -7664 -5541 -3370 -3345 -4488 -6703 -7175 -5445 -2626 235 1254 2287 2471 2876 3138 2743 2323 2019 979 916 623 1446 1953 2588 2099 2007 1666 1149 550 65 591 1703 2897 3787 3619 2104 499 -335 -678 651 1414 1658 1587 741 -7 -1427 -3184 -4579 -5193 -4239 -3326 -2458 -1996 -1770 -1065 -172 1003 1607 1951 1816 1168 269 -1302 -2267 -2500 -1522 -578 408 783 498 -128 -1312 -1967 -1940 -1593 -1225 -938 -423 470 1283 1915 1898 1412 566 -179 -866 -910 -432 159 574 921 1056 1179 933 434 -190 -838 -1099 -943 -655 -514 -725 -835 -606 -228 -47 407 608 652 545 199 -293 -599 -442 -797 -807 -645 -790 -1022 -990 -1108 -937 -1050 -979 -1106 -1039 -862 -704 -466 -266 -199 -100 -104 -48 -176 -123 -198 -237 -277 -478 -527 -874 -853 -742 -573 -380 -411 -580 -884 -966 -785 -427 44 267 534 615 742 827 735 630 552 272 259 184 452 656 927 801 800 687 483 233 27 249 740 1339 1887 1922 1153 270 -178 -366 373 887 1122 1116 523 -5 -915 -1904 -2600 -2951 -2558 -2238 -1850 -1658 -1586 -919 -157 959 1600 1982 1835 1144 250 -1257 -2109 -2353 -1526 -581 455 952 638 -164 -1605 -2263 -2146 -1789 -1446 -1168 -553 647 1879 2994 3132 2184 943 -285 -1312 -1330 -632 241 911 1511 1745 1912 1471 661 -278 -1191 -1540 -1362 -1013 -857 -1287 -1422 -1073 -423 -91 824 1261 1369 1137 404 -576 -1142 -839 SS 20250411T221643.2Z 9232.928278 267 1 49.16 2 65.76 96.88 122.03 287.72 0.00 1 0.00 1 0 25 7.653e-02 1.177e-02 4.561e-03 4.732e-04 3.855212e-01 2.549364e-04 4.753914e-03 -6.000000e+00 4.784330e-02 228.90 -2.00 3.41 -2.00 319.35 0.00e+00 2.718823e-03 6.807510e-05 2.448575e-03 -6.000000e+00 2.127386e-03 283.35 -2.00 20.00 -2.00 318.61 0.00e+00 2.419 0.000 302.00 328.00 3 1.1735e+00 7.1899e-04 3.2051e-02 -6.0000e+00 1.1890e-01 -6.0099e-03 8.3601e-04 2.2047e-02 -6.0000e+00 1.2879e-01 -2.6970e-02 5.9664e-04 1.1270e-02 -6.0000e+00 7.6773e-02 3.8400e-03 3.0269e-04 3.3447e-03 -6.0000e+00 3.1460e-02 9.0561e-03 8.7497e-04 1.6600e-05 5.6252e-05 -6.0000e+00 2.6168e-03 6.3452e-03 0.0000e+00 12 8 8 10 0 0 23.18 17.51 0.40 0.00635 0.01292 885 194 1 5 0 55.540 21.79 15.00 17.51 21.83 26.6 1037.88 -23945 -19288 -20381 -22117 -26207 -31097 -27195 -27747 -23720 -22610 -22177 -19257 -15890 -8730 -6451 -2965 -1832 -999 1676 165 803 -705 -308 -1116 -1641 -2735 -5204 -5800 -7614 -6664 -4354 -3123 -2503 -4910 -6391 -7148 -5500 -2498 74 1430 1491 2400 2373 2613 2697 1946 1808 750 489 620 1339 1809 2099 1966 1526 1487 776 246 -22 203 1606 2597 3698 3285 2094 467 -634 -632 325 1505 1551 1466 800 -127 -1315 -3127 -4402 -4994 -4304 -3107 -2613 -2124 -1883 -1095 -185 881 1523 1674 1724 1087 205 -1046 -2096 -2288 -1596 -614 304 835 535 -171 -1203 -1996 -1913 -1475 -1270 -805 -544 461 1277 1903 1857 1336 688 -173 -794 -933 -322 252 679 989 1022 1234 886 484 -42 -816 -1001 -947 -553 -489 -641 -757 -703 -273 -56 438 596 617 536 146 -246 -663 -458 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