File name: Pandora192s1_Tokyo-Sophia_20250415_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T144229.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250415_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250414T223456.1Z 9235.940927 281 1 51.34 2 61.32 98.92 109.96 258.12 0.00 1 0.00 1 0 25 4.438e-02 1.152e-02 1.353e-03 2.126e-04 3.393339e-01 1.154277e-04 4.123247e-03 -6.000000e+00 2.777322e-02 229.13 -2.00 3.41 -2.00 318.60 0.00e+00 2.249063e-03 2.445411e-05 1.546881e-03 -6.000000e+00 1.234921e-03 283.62 -2.00 20.00 -2.00 317.85 0.00e+00 2.073 0.000 302.00 328.00 3 9.4156e-02 3.1536e-04 2.7241e-02 -6.0000e+00 6.9053e-02 1.0551e-02 3.5979e-04 1.7844e-02 -6.0000e+00 7.4775e-02 -1.4395e-02 2.3406e-04 9.0173e-03 -6.0000e+00 4.4574e-02 -1.6483e-03 1.1774e-04 2.7113e-03 -6.0000e+00 1.8269e-02 3.9047e-02 7.4895e-04 7.4304e-06 3.8272e-05 -6.0000e+00 1.5174e-03 4.2528e-03 0.0000e+00 12 8 8 10 0 0 99.89 17.65 0.46 0.00425 0.00988 2767 607 1 5 0 17.760 21.88 15.00 17.65 19.95 27.0 1026.27 -10356 -9076 -8690 -11840 -14483 -16851 -16280 -14832 -13540 -13863 -14148 -12649 -8985 -5404 -2352 -742 710 1570 1827 2062 1478 1210 248 1 -864 -1815 -2854 -4655 -5159 -4788 -3333 -2331 -1973 -3716 -5722 -6233 -4937 -2271 -22 978 1252 1659 1780 1829 2037 1752 1266 600 193 332 971 1521 1897 1598 1393 1276 698 270 6 452 1596 2558 3316 2889 1793 360 -582 -758 423 1224 1317 1168 634 -14 -1112 -2738 -3980 -4514 -3829 -2874 -2422 -2061 -1867 -1174 -306 753 1361 1614 1536 1019 221 -974 -1871 -2122 -1353 -560 317 692 473 -110 -1094 -1785 -1748 -1378 -1207 -888 -446 389 1143 1782 1824 1341 699 -41 -672 -794 -325 232 631 932 1027 1150 803 432 -93 -659 -935 -849 -565 -448 -621 -756 -619 -193 -35 408 527 534 492 137 -250 -643 -491 -449 -431 -426 -583 -690 -795 -870 -851 -836 -909 -967 -911 -706 -477 -233 -81 83 192 234 273 202 168 36 0 -137 -299 -474 -765 -830 -777 -568 -430 -390 -771 -1201 -1328 -1124 -580 -7 326 459 643 715 748 838 725 524 248 81 142 435 725 960 854 775 728 406 158 4 263 951 1615 2036 1878 1186 233 -401 -523 279 880 1022 944 514 -11 -820 -1877 -2824 -3157 -2810 -2111 -1983 -1852 -1803 -1198 -330 853 1606 1783 1688 1183 242 -1001 -1830 -2072 -1392 -630 392 852 611 -142 -1348 -2261 -2136 -1713 -1450 -1124 -592 540 1675 2761 2957 2207 1126 -62 -972 -1104 -451 332 949 1458 1628 1795 1222 634 -131 -894 -1244 -1154 -814 -689 -1009 -1277 -1081 -352 -61 748 992 1019 933 255 -450 -1126 -855 SS 20250414T223927.0Z 9235.944063 284 1 51.65 2 60.41 99.66 110.83 258.68 0.00 1 0.00 1 0 25 4.104e-02 1.157e-02 1.125e-03 1.911e-04 3.300597e-01 1.035693e-04 3.987375e-03 -6.000000e+00 2.568504e-02 229.13 -2.00 3.41 -2.00 318.50 0.00e+00 2.170633e-03 2.123920e-05 1.454214e-03 -6.000000e+00 1.142027e-03 283.62 -2.00 20.00 -2.00 317.73 0.00e+00 2.016 0.000 302.00 328.00 3 -3.3814e-02 2.8262e-04 2.6443e-02 -6.0000e+00 6.3861e-02 8.4238e-03 3.2168e-04 1.7235e-02 -6.0000e+00 6.9152e-02 -1.2916e-02 2.0633e-04 8.6820e-03 -6.0000e+00 4.1222e-02 -2.2013e-03 1.0323e-04 2.6011e-03 -6.0000e+00 1.6896e-02 4.7607e-02 8.0183e-04 6.6959e-06 3.7542e-05 -6.0000e+00 1.4032e-03 3.9733e-03 0.0000e+00 12 8 8 10 0 0 68.38 17.66 0.46 0.00397 0.01000 3242 712 1 5 0 15.150 21.88 15.01 17.66 20.59 27.3 1030.40 -10153 -7411 -7604 -9941 -13567 -15581 -15070 -13449 -12199 -12774 -12874 -11922 -8367 -4758 -2160 -285 858 1538 1982 2012 1512 919 370 -192 -603 -1446 -2969 -4457 -4985 -4433 -3058 -2022 -1835 -3791 -5673 -6185 -4680 -2060 203 1048 1160 1646 1712 1925 2025 1644 1206 509 102 327 975 1459 1810 1512 1313 1174 706 306 65 476 1548 2570 3268 2816 1742 331 -643 -793 380 1254 1282 1135 658 -10 -1134 -2709 -3954 -4493 -3767 -2896 -2483 -2057 -1906 -1115 -289 752 1330 1590 1526 991 221 -960 -1845 -2122 -1348 -521 331 714 489 -154 -1113 -1847 -1713 -1406 -1194 -899 -472 382 1136 1783 1818 1352 703 -70 -683 -810 -298 231 640 937 1031 1160 800 487 -88 -638 -949 -820 -545 -413 -620 -767 -623 -212 -40 389 514 541 478 132 -271 -650 -492 -483 -379 -404 -525 -699 -871 -868 -830 -810 -902 -945 -925 -707 -450 -229 -33 107 201 271 285 220 136 56 -31 -101 -252 -524 -776 -848 -758 -548 -391 -381 -826 -1248 -1380 -1113 -550 62 365 444 666 718 820 869 709 519 219 44 145 451 719 946 834 753 691 423 184 39 285 950 1670 2064 1882 1182 219 -412 -509 256 920 1015 935 543 -8 -854 -1895 -2860 -3200 -2810 -2162 -2064 -1874 -1866 -1152 -315 863 1458 1780 1700 1166 245 -998 -1825 -2093 -1398 -590 378 885 635 -199 -1378 -2159 -2107 -1762 -1445 -1147 -631 534 1674 2776 2957 2230 1133 -107 -989 -1125 -413 331 964 1468 1636 1815 1220 715 -125 -867 -1264 -1114 -784 -634 -1005 -1291 -1085 -355 -70 710 964 1027 905 244 -487 -1135 -855 SS 20250414T224451.9Z 9235.947823 287 1 51.46 2 59.33 100.56 111.88 259.36 0.00 1 0.00 1 0 25 3.741e-02 1.153e-02 1.032e-03 1.880e-04 3.206237e-01 1.017503e-04 3.858484e-03 -6.000000e+00 2.341698e-02 229.13 -2.00 3.41 -2.00 318.38 0.00e+00 2.121783e-03 2.012318e-05 1.345969e-03 -6.000000e+00 1.041167e-03 283.62 -2.00 20.00 -2.00 317.61 0.00e+00 1.952 0.000 302.00 328.00 3 1.1849e-02 2.7632e-04 2.5564e-02 -6.0000e+00 5.8222e-02 6.4880e-03 3.1389e-04 1.6561e-02 -6.0000e+00 6.3045e-02 -1.1184e-02 1.9948e-04 8.3246e-03 -6.0000e+00 3.7582e-02 -2.9188e-03 9.9380e-05 2.4977e-03 -6.0000e+00 1.5404e-02 4.9099e-02 8.0138e-04 6.5881e-06 3.4855e-05 -6.0000e+00 1.2793e-03 3.8611e-03 0.0000e+00 12 8 8 10 0 0 83.20 17.67 0.46 0.00386 0.00988 3264 716 1 5 0 15.050 21.98 15.01 17.67 21.49 27.2 1034.01 -7811 -6357 -6957 -9744 -12021 -13797 -12922 -11991 -10900 -11766 -12240 -10901 -7710 -4099 -1532 -4 712 1664 2018 2093 1770 1029 539 136 -559 -1281 -2581 -4063 -4709 -4467 -3133 -1973 -1868 -3677 -5551 -6175 -4639 -2176 63 1000 1156 1624 1620 1825 1945 1571 1238 474 151 288 876 1415 1828 1500 1314 1218 664 287 58 481 1624 2552 3273 2745 1695 285 -635 -722 364 1166 1240 1144 684 37 -1095 -2665 -3838 -4398 -3717 -2818 -2404 -2040 -1868 -1161 -310 737 1356 1593 1527 981 194 -946 -1831 -2089 -1342 -499 310 714 486 -118 -1086 -1815 -1701 -1382 -1172 -860 -436 401 1146 1773 1823 1362 730 -24 -654 -792 -281 251 642 969 1013 1182 806 456 -60 -601 -933 -824 -554 -411 -624 -750 -644 -232 -43 383 510 529 500 122 -258 -667 -499 -399 -353 -402 -562 -667 -828 -795 -795 -778 -895 -970 -907 -699 -415 -174 -1 95 232 294 316 274 162 87 23 -100 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